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    Diene polymers and copolymers terminated by reaction with N-alkyl and N-aryl imines
    2.
    发明授权
    Diene polymers and copolymers terminated by reaction with N-alkyl and N-aryl imines 失效
    通过与N-烷基和N-亚氨基反应终止的二烯聚合物和共聚物

    公开(公告)号：US5066729A

    公开(公告)日：1991-11-19

    申请号：US506306

    申请日：1990-04-09

    申请人： Mark L. Stayer, Jr. ,  Thomas A. Antkowiak ,  David F. Lawson ,  Russell W. Koch

    发明人： Mark L. Stayer, Jr. ,  Thomas A. Antkowiak ,  David F. Lawson ,  Russell W. Koch

    IPC分类号： C08C19/22 ,  B60C1/00 ,  C08C19/44 ,  C08F8/30 ,  C08F36/00 ,  C08F36/04 ,  C08F136/04 ,  C08F236/10 ,  C08L47/00

    CPC分类号： C08C19/44 ,  B60C1/0016

    摘要： A process is provided for preparing a terminally functionalized polymer from a living polymer obtained by anionic polymerization of a diene monomer or mixture of a diene monomer and a vinyl aromatic hydrocarbon monomer which comprises reacting the living polymer with a compound having the formula: ##STR1## wherein R.sub.1 and R.sub.2 are selected from the group consisting of H, alkyl, cycloalkyl, aryl, dialkylaminoaryl, aralkyl, and aprotic O, N and S- containing alkyl, cycloalkyl, aryl and aralkyl groups; wherein R.sub.3 is selected from the group consisting of alkyl, cycloalkyl, aryl, dialkylaminoaryl, aralkyl, and aprotic O, N and S- containing alkyl, cycloalkyl, aryl and aralkyl groups; with the proviso that at least one of the R.sub.1, R.sub.2 and R.sub.3 groups must be a dialkylaminoaryl group and that not all of the R.sub.1, R.sub.2 and R.sub.3 groups can be aryl groups.The resultant terminally functionalized polymer has reduced hysteresis properties and may be utilized to prepare elastomer compositions and tire treads having reduced rolling resistance.

    摘要翻译： 提供了一种通过二烯单体或二烯单体和乙烯基芳族烃单体的混合物的阴离子聚合获得的活性聚合物制备末端官能化聚合物的方法，其包括使活性聚合物与具有下式的化合物反应： 其中R 1和R 2选自H，烷基，环烷基，芳基，二烷基氨基芳基，芳烷基和非质子O，N和S-含烷基，环烷基，芳基和芳烷基; 其中R 3选自烷基，环烷基，芳基，二烷基氨基芳基，芳烷基和非质子O，N和S-含烷基，环烷基，芳基和芳烷基; 条件是R1，R2和R3基团中的至少一个必须是二烷基氨基芳基，并且不是所有的R 1，R 2和R 3基团都可以是芳基。 所得的末端官能化聚合物具有降低的滞后性能，并且可用于制备具有降低的滚动阻力的弹性体组合物和轮胎胎面。

    Elastomers and products having reduced hysteresis
    3.
    发明授权
    Elastomers and products having reduced hysteresis 失效
    弹性体和滞后性降低的产品

    公开(公告)号：US5268413A

    公开(公告)日：1993-12-07

    申请号：US791910

    申请日：1991-11-13

    申请人： Thomas A. Antkowiak ,  David F. Lawson ,  Russell W. Koch ,  Mark L. Stayer, Jr.

    发明人： Thomas A. Antkowiak ,  David F. Lawson ,  Russell W. Koch ,  Mark L. Stayer, Jr.

    IPC分类号： C08C19/44 ,  C08F4/48 ,  C08F36/04 ,  C08K3/04

    CPC分类号： C08F4/48 ,  C08C19/44 ,  C08F36/04

    摘要： An anionic polymerization initiator comprising the reaction product of a functionalizing agent selected from the group consisting of substituted aldimines, ketimines and secondary amines and, an organolithium compound. Elastomeric polymers prepared with these initiators have functional sites incorporated at the initiator end of the polymer chain and provide vulcanizable rubber compounds exhibiting reduced hysteresis. Articles such as tires, produced with low hysteresis elastomeric polymers have lower rolling resistance. Methods are also provided for preparing the initiators, functionalized polymers and vulcanizable elastomeric compounds having reduced hysteresis.

    摘要翻译： 一种阴离子聚合引发剂，其包含选自取代的醛亚胺，酮亚胺和仲胺的官能化试剂的反应产物和有机锂化合物。 用这些引发剂制备的弹性体聚合物具有并入聚合物链的引发剂末端的功能性位点，并提供具有降低的滞后性的可硫化橡胶化合物。 用低滞后弹性体聚合物制成的轮胎等制品具有较低的滚动阻力。 还提供了用于制备具有降低的滞后的引发剂，官能化聚合物和可硫化弹性体化合物的方法。

    Diene polymers and copolymers terminated by reaction with N-alkyl and N-aryl imines
    4.
    发明授权
    Diene polymers and copolymers terminated by reaction with N-alkyl and N-aryl imines 失效
    通过与N-烷基和N-芳基亚胺反应终止二烯聚合物和共聚物

    公开(公告)号：US5109907A

    公开(公告)日：1992-05-05

    申请号：US732851

    申请日：1991-07-19

    申请人： Mark L. Stayer, Jr. ,  Thomas A. Antkowiak ,  David F. Lawson ,  Russell W. Koch

    发明人： Mark L. Stayer, Jr. ,  Thomas A. Antkowiak ,  David F. Lawson ,  Russell W. Koch

    IPC分类号： B60C1/00 ,  C08C19/44

    CPC分类号： C08C19/44 ,  B60C1/0016

    摘要： A process is provided for preparing a terminally functionalized polymer from a living polymer obtained by anionic polymerization of a diene monomer or mixture of a diene monomer and a vinyl aromatic hydrocarbon monomer which comprises reacting the living polymer with a compound having the formula: ##STR1## wherein R.sub.1 and R.sub.2 are selected from the group consisting of H, alkyl, cycloalkyl, aryl, dialkylaminoaryl, aralkyl, and aprotic O, N and S- containing alkyl, cycloalkyl, aryl and aralkyl groups; wherein R.sub.3 is selected from the group consisting of alkyl, cycloalkyl, aryl, dialkylaminoaryl, aralkyl, and aprotic O, N and S- containing alkyl, cycloalkyl, aryl and aralkyl groups; with the proviso that at least one of the R.sub.1, R.sub.2 and R.sub.3 groups must be a dialkylaminoaryl group and that not all of the R.sub.1, R.sub.2 and R.sub.3 groups can be aryl groups.The resultant terminally functionalized polymer has reduced hysteresis properties and may be utilized to prepare elastomer compositions and tire treads having reduced rolling resistance.

    摘要翻译： 提供了一种通过二烯单体或二烯单体和乙烯基芳族烃单体的混合物的阴离子聚合获得的活性聚合物制备末端官能化聚合物的方法，其包括使活性聚合物与具有下式的化合物反应： 其中R 1和R 2选自H，烷基，环烷基，芳基，二烷基氨基芳基，芳烷基和非质子O，N和S-含烷基，环烷基，芳基和芳烷基; 其中R 3选自烷基，环烷基，芳基，二烷基氨基芳基，芳烷基和非质子O，N和S-含烷基，环烷基，芳基和芳烷基; 条件是R1，R2和R3基团中的至少一个必须是二烷基氨基芳基，并且不是所有的R 1，R 2和R 3基团都可以是芳基。 所得的末端官能化聚合物具有降低的滞后性能，并且可用于制备具有降低的滚动阻力的弹性体组合物和轮胎胎面。

    Anionic polymerization initiators containing adducts of cyclic secondary amines and conjugated dienes, and products therefrom
    9.
    发明授权
    Anionic polymerization initiators containing adducts of cyclic secondary amines and conjugated dienes, and products therefrom 失效
    含有环状仲胺和共轭二烯的加合物的阴离子聚合引发剂及其产物

    公开(公告)号：US5491230A

    公开(公告)日：1996-02-13

    申请号：US175294

    申请日：1993-12-29

    申请人： David F. Lawson ,  Thomas A. Antkowiak ,  James E. Hall ,  Mark L. Stayer, Jr.

    发明人： David F. Lawson ,  Thomas A. Antkowiak ,  James E. Hall ,  Mark L. Stayer, Jr.

    IPC分类号： C08F4/08 ,  C07F1/02 ,  C08F4/42 ,  C08F4/46 ,  C08F4/48 ,  C08F236/04 ,  C08F236/10 ,  C07D225/00

    CPC分类号： C07F1/02

    摘要： An anionic polymerization initiator includes a carbon-lithio salt of the adduct of a cyclic secondary amine with a conjugated diene. A method of preparing an anionic polymerization initiator includes reacting an excess of a cyclic secondary amine with a conjugated diene to form an adduct; and, reacting the adduct with an organolithium compound. A method of preparing a polymer includes forming a solution of one or more anionically polymerizable monomers in a hydrocarbon solvent; and, polymerizing the monomer with an anionic polymerization initiator comprising a carbon-lithio salt of the adduct of a cyclic secondary amine with a conjugated diene. A functionalized polymer includes the termination product of a living polymer having the general formula AYLi, wherein A is a functional group derived from an anionic polymerization initiator; and, Y is a divalent polymer radical; wherein the anionic polymerization initiator is a carbon-lithio salt of the adduct of a cyclic secondary amine with a conjugated diene.

    摘要翻译： 阴离子聚合引发剂包括环状仲胺与共轭二烯的加合物的碳 - 硫酸盐。 制备阴离子聚合引发剂的方法包括使过量的环状仲胺与共轭二烯反应形成加合物; 并使加合物与有机锂化合物反应。 制备聚合物的方法包括在烃溶剂中形成一种或多种阴离子聚合单体的溶液; 并且用包含环状仲胺加成物的碳 - 硫醇盐与共轭二烯的阴离子聚合引发剂聚合单体。 官能化聚合物包括具有通式AYLi的活性聚合物的终止产物，其中A是衍生自阴离子聚合引发剂的官能团; Y为二价聚合物基团; 其中所述阴离子聚合引发剂是环状仲胺与共轭二烯的加合物的碳 - 锂盐。