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US5357001A Optically active amino acid sulphoxide and amino acid sulphone derivatives, their preparation, their polymerisation and use as adsorbents for chromatographic resolution of racemates 失效
光活性氨基酸亚砜和氨基酸砜衍生物,它们的制备,它们的聚合和用作吸附剂用于外消旋体的色谱拆分

Optically active amino acid sulphoxide and amino acid sulphone
derivatives, their preparation, their polymerisation and use as
adsorbents for chromatographic resolution of racemates
摘要:
The invention relates to new optically active amino acid derivatives of the general formula (I) ##STR1## in which n, R, R.sub.1, R.sub.2, R.sub.3, X and A have the meaning given in the description, which amino acid derivatives contain sulphoxide or sulphone groups, to two basic synthetic routes for the preparation from sulphur-containing amino acids, to the polymerization of these monomers and to the use of the polymers as optically active adsorbents for chromatographic resolution of racemates to give the enantiomers.
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