发明授权
- 专利标题: Modified molecular sieves by means of solid ion exchange
- 专利标题(中): 通过固体离子交换改性分子筛
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申请号: US388832申请日: 1995-02-15
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公开(公告)号: US5529964A公开(公告)日: 1996-06-25
- 发明人: Jens Weitkamp , Stefan Ernst , Thomas Bock , Thomas Kromminga , Akos Kiss , Peter Kleinschmit
- 申请人: Jens Weitkamp , Stefan Ernst , Thomas Bock , Thomas Kromminga , Akos Kiss , Peter Kleinschmit
- 申请人地址: DEX Frankfurt am Main
- 专利权人: Degussa Aktiengesellschaft
- 当前专利权人: Degussa Aktiengesellschaft
- 当前专利权人地址: DEX Frankfurt am Main
- 优先权: DEX4304821.8 19930217
- 主分类号: B01J20/18
- IPC分类号: B01J20/18 ; B01J29/064 ; B01J29/70 ; B01J29/72 ; B01J29/74 ; B01J37/30 ; C01B39/02 ; C07C5/03 ; B01J29/068
摘要:
Molecular sieves are modified by an ion exchange process where metal cations are introduced into the molecular sieves by means of solid state ion exchange. The solid state ion exchange can be carried out as follows: a weighed amount of calcined and activated zeolite is intimately mixed with a precalculated amount of PtCl.sub.2, PdCl.sub.2, RhCl.sub.3, CuCl.sub.2, V.sub.2 O.sub.5 or another compound of the noble metals (e.g., corresponding halides or oxides), the solids mixture is then heated in a current of inert gas (e.g., a current of helium gas or of nitrogen) to temperatures of 400.degree. to 600.degree. C., then cooled down to room temperature and subsequently reduced in a current of hydrogen for 10 to 14 hours at 280.degree. to 350.degree. C. in order to produce small metal clusters from the cationically introduced metal.
公开/授权文献
- US4911643A High density and high signal integrity connector 公开/授权日:1990-03-27
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