发明授权
US5741845A Process for production of azo macroinitiators for the synthesis of block copolymers and of aqueous block copolymer dispersions and emulsions and the use thereof 失效
制备用于合成嵌段共聚物和水性嵌段共聚物分散体和乳液的偶氮大分子引发剂的方法及其用途

Process for production of azo macroinitiators for the synthesis of block
copolymers and of aqueous block copolymer dispersions and emulsions and
the use thereof
摘要:
The invention concerns a process for the production of block copolymers or aqueous dispersions and emulsions thereof, whereby azo macroinitiators are reacted with radical-polymerizable monomers or a mixture of several radical-polymerizable monomers. The azo macroinitiators are obtained by reacting simple reactive azo compounds with prepolymers with a molecular weight between 400 and 20000, which possess at least 2 functional groups, e.g. polyurethanes or polyesters. The aqueous block copolymer dispersions and emulsions produced according to the invention are suitable for use for the production of paints, adhesives etc.
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