发明授权
- 专利标题: Method for the production of branched polymerizates
- 专利标题(中): 生产支化聚合物的方法
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申请号: US877640申请日: 1997-06-17
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公开(公告)号: US5859140A公开(公告)日: 1999-01-12
- 发明人: Martina Pfirmann , Werner Siol , Klaus Koralewski , Michael Wicker
- 申请人: Martina Pfirmann , Werner Siol , Klaus Koralewski , Michael Wicker
- 申请人地址: DEX Darmstadt
- 专利权人: Roehm GmbH Chemische Fabrik
- 当前专利权人: Roehm GmbH Chemische Fabrik
- 当前专利权人地址: DEX Darmstadt
- 优先权: DEX19524053.7 19950701
- 主分类号: C08F2/06
- IPC分类号: C08F2/06 ; C08F2/38 ; C08F265/06 ; C09D7/12 ; C09J11/08 ; C10M145/14 ; C10M149/06 ; C08F273/00
摘要:
A method for producing branched polymerizates by radical polymerization of monomers in two stages comprisingin a first stage, adding 10 to 500 parts by weight of at least one monomer M.sub.1 and 0.1 to 20 parts by weight of a mercaptan with an olefinic, radically polymerizable double bond RM as a molecular weight regulator, and polymerizing said at least one monomer M.sub.1 and mercaptan RM to form a copolymer MM.sub.1 in the presence of at least one polymerization initiator and 0 to 100 parts by weight of an inert, non-aqueous solvent, which completely dissolves the monomer M.sub.1, the mercaptan RM and the copolymer MM.sub.1, where the polymerizable double bonds and M.sub.1 and RM have a reactivity, expressed by a copolymerization parameter r, between 0.1 and 10, andin a second stage, adding 10 to 2000 parts by weight of a monomer M.sub.2 and 0.01 to 10 parts by weight of a saturated molecular weight regulator, and optionally, an inert, non-aqueous solvent, to the reaction mixture formed in the first stage, and polymerizing in the presence of at least one polymerization initiator to form a branched polymerizate. Branched polymerzates made by the method.
公开/授权文献
- US5185034A Ink-jet inks with improved colors and plain paper capacity 公开/授权日:1993-02-09
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