发明授权
- 专利标题: Disproportionation/transalkylation of aromatic hydrocarbons
- 专利标题(中): 芳烃的歧化/烷基转移
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申请号: US10268649申请日: 2002-10-10
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公开(公告)号: US06867340B2公开(公告)日: 2005-03-15
- 发明人: Seung-Hoon Oh , Sang-Il Lee , Kyoung-Hak Seong , Sang-Hoon Park
- 申请人: Seung-Hoon Oh , Sang-Il Lee , Kyoung-Hak Seong , Sang-Hoon Park
- 申请人地址: KR Seoul
- 专利权人: SK Corporation
- 当前专利权人: SK Corporation
- 当前专利权人地址: KR Seoul
- 代理机构: Drinker Biddle & Reath LLP
- 优先权: KR98-58628 19981224; KR99-9649 19990322
- 主分类号: B01J29/18
- IPC分类号: B01J29/18 ; B01J29/22 ; B01J29/40 ; B01J29/44 ; B01J29/70 ; B01J29/80 ; B01J37/00 ; C07C6/12 ; C07C15/02 ; C07C15/08
摘要:
A catalyst for the disproportionation/transalkylation of various hydrocarbons consists of a carrier and a metal component supported on the carrier. The carrier comprises 10 to 80 wt % of mordenite and/or beta type zeolite with a mole ratio of silica/alumina ranging from 10 to 200; 0 to 70 wt % of ZSM-5 type zeolite with a mole ratio of silica/alumina ranging from 30 to 500; and 5 to 90 wt % of at least one inorganic binder selected from the group consisting of gamma-alumina, silica, silica alumina, bentonite, kaolin, clinoptilolite, and montmorillonite. The metal component comprises platinum and either tin or lead. The catalyst enables mixed xylenes to be produced at remarkably high yields from benzene, toluene and C9 or higher aromatic compounds through disproportionation/transalkylation with a great reduction in aromatic loss. In addition, the catalyst can maintain its catalytic activity for a long period of time without deactivation.
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