Invention Grant
- Patent Title: Radiation-sensitive compositions comprising oxazole derivatives and imageable elements based thereon
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Application No.: US10544758Application Date: 2004-02-20
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Publication No.: US07442486B2Publication Date: 2008-10-28
- Inventor: Harald Baumann , Udo Dwars , Detlef Pietsch , Michael Flugel
- Applicant: Harald Baumann , Udo Dwars , Detlef Pietsch , Michael Flugel
- Applicant Address: US NY Rochester
- Assignee: Eastman Kodak Company
- Current Assignee: Eastman Kodak Company
- Current Assignee Address: US NY Rochester
- Agent J. Lanny Tucker
- Priority: DE10307453 20030221
- International Application: PCT/EP2004/001706 WO 20040220
- International Announcement: WO2004/074930 WO 20040902
- Main IPC: G03C1/76
- IPC: G03C1/76 ; G03C1/492 ; G03C1/494 ; G03C5/00 ; G03C1/00

Abstract:
Radiation-sensitive element comprising: (a) one or more types of monomers each comprising at least one ethylenically unsaturated group accessible to a free-radical polymerization, (b) at least one sensitizer, (c) at least one coinitiator capable of forming free radicals together with the sensitizer (b) and selected from the following classes of compounds: metallocenes; 1,3,5-triazine derivatives with one to three CX3 groups, wherein X represents chlorine or bromine; peroxides; hexaarylbiimidazoles; oxime ethers; oxime esters; N-aryl glycines and derivatives thereof; thiol compounds; N-aryl, S-aryl and O-aryl polycarboxylic acids with at least 2 carboxyl groups of which at least one is bonded to the N, S or O atom of the aryl unit; alkyltriarylborates; benzoin ethers; benzoin esters; trihalogenomethylarylsulfones; amines; N,N-dialkylaminobenzoic acid esters; aromatic sulfonyl halides; trihalogenomethylsulfones; imides; diazosulfonates; 9,10-dihydroanthracene derivatives; a-hydroxy and a-amino acetophenones; and (d) optionally one or more components selected from alkali-soluble binders, colorants, exposure indicators, plasticizers, chain transfer agents, leuco dyes, surfactants, inorganic fillers and thermopolymerization inhibitors characterized in that the at least one sensitizer is an oxazole derivative of the formula (I), wherein each R1, R2 and R3 is independently selected from a halogen atom, an optionally substituted alkyl group, an optionally substituted aryl group, which may also be fused, an optionally substituted aralkyl group, a group —NR4R5 and a group —OR6, wherein R4 and R5 are independently selected from a hydrogen atom, an alkyl, aryl or ralkyl group, R6 is an alkyl, aryl or aralkyl group or a hydrogen atom and k, m and n are independently 0 or an integer from 1 to 5.
Public/Granted literature
- US20060234155A1 Radiation-sensitive compositions comprising oxazole derivatives and imageable elements based thereon Public/Granted day:2006-10-19
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