Disclosed is a phosphated galvanized steel sheet comprising a steel sheet, a zinc-plating layer of η single phase which is formed on at least one side of the steel sheet and contains Ni in an amount of not less than 10 ppm by mass and not more than the solubility limit thereof, and a phosphate layer which is formed on the zinc-plating layer and contains Mg in an amount of not less than 0.1 % by mass and less than 2.0 % by mass. Although this steel sheet is not subjected to sealing, it has corrosion resistance equivalent to or higher than those of conventional steel sheets which have been subjected to sealing, while having excellent blackening resistance.