公开(公告)号：US08663816B2

公开(公告)日：2014-03-04

申请号：US13504755

申请日：2010-10-28

Applicant: Hiroki Nakamaru ,  Seiji Nakajima ,  Tatsuya Miyoshi ,  Hiroyuki Masuoka ,  Shinji Ootsuka

Inventor： Hiroki Nakamaru ,  Seiji Nakajima ,  Tatsuya Miyoshi ,  Hiroyuki Masuoka ,  Shinji Ootsuka

IPC: B32B15/04 ,  B32B15/18

Abstract: A hot-pressed member includes a steel sheet, a Ni-diffusion region present in a surface layer of the steel sheet, and an intermetallic compound layer and a ZnO layer which are provided in order on the Ni-diffusion region, the intermetallic compound layer corresponding to a γ phase present in a phase equilibrium diagram of a Zn—Ni alloy, wherein a spontaneous immersion potential indicated in a 0.5 M NaCl aqueous air-saturated solution at 25° C.±5° C. is −600 to −360 mV based on a standard hydrogen electrode.

公开(公告)号：US07588836B2

公开(公告)日：2009-09-15

申请号：US11597117

申请日：2005-08-17

Applicant: Hiroki Nakamaru ,  Chiyoko Tada ,  Kazumi Yamashita ,  Hideo Sasaoka ,  Chiaki Kato

Inventor： Hiroki Nakamaru ,  Chiyoko Tada ,  Kazumi Yamashita ,  Hideo Sasaoka ,  Chiaki Kato

IPC: B32B15/00 ,  C25D7/04 ,  C25D5/10

CPC classification number: C23C2/06 ,  C23C2/26 ,  C23C22/22 ,  C23C28/321 ,  C23C28/3225 ,  C23C28/345 ,  C25D3/22 ,  C25D11/36 ,  Y10T428/12438 ,  Y10T428/12493 ,  Y10T428/12535 ,  Y10T428/12611 ,  Y10T428/12618 ,  Y10T428/1266 ,  Y10T428/12729 ,  Y10T428/12792 ,  Y10T428/12799 ,  Y10T428/12951 ,  Y10T428/12972 ,  Y10T428/12979

Abstract: Disclosed is a phosphated galvanized steel sheet comprising a steel sheet, a zinc-plating layer of η single phase which is formed on at least one side of the steel sheet and contains Ni in an amount of not less than 10 ppm by mass and not more than the solubility limit thereof, and a phosphate layer which is formed on the zinc-plating layer and contains Mg in an amount of not less than 0.1 % by mass and less than 2.0 % by mass. Although this steel sheet is not subjected to sealing, it has corrosion resistance equivalent to or higher than those of conventional steel sheets which have been subjected to sealing, while having excellent blackening resistance.

Abstract translation: 公开了一种磷化镀锌钢板，其包括钢板，等离子体镀锌层，其形成在钢板的至少一侧，并且含有不小于10质量ppm的量，而不是更多 以及在镀锌层上形成的Mg含量不低于0.1质量％且小于2.0质量％的磷酸盐层。 虽然该钢板不进行密封，但是其耐腐蚀性等于或高于已经进行密封的常规钢板，同时具有优异的耐黑变性。

公开(公告)号：US09498810B2

公开(公告)日：2016-11-22

申请号：US13991055

申请日：2011-11-30

Applicant: Seiji Nakajima ,  Tatsuya Miyoshi ,  Hiroki Nakamaru

Inventor： Seiji Nakajima ,  Tatsuya Miyoshi ,  Hiroki Nakamaru

IPC: B21D22/02 ,  B32B15/01 ,  C21D9/46 ,  C22C18/00 ,  C23C2/06 ,  C23C2/28 ,  C25D5/50 ,  C22C38/12 ,  C22C38/00 ,  C22C38/02 ,  C22C38/04 ,  C22C38/06 ,  C22C38/14 ,  C21D1/673 ,  G01N19/02

CPC classification number: B21D22/022 ,  B32B15/013 ,  B32B15/015 ,  C21D1/673 ,  C21D9/46 ,  C22C18/00 ,  C22C38/001 ,  C22C38/02 ,  C22C38/04 ,  C22C38/06 ,  C22C38/12 ,  C22C38/14 ,  C23C2/06 ,  C23C2/28 ,  C25D3/12 ,  C25D3/565 ,  C25D5/12 ,  C25D5/14 ,  C25D5/50 ,  C25D7/0614 ,  G01N19/02

Abstract: The invention provides methods for manufacturing warm press-formed members which can ensure post-coating corrosion resistance. A method for manufacturing warm press-formed members includes heating a steel sheet to a temperature in the range from 200 to 800° C. and warm press-forming the steel sheet at a temperature in the above range of temperatures, the steel sheet having a Zn—Ni alloy coating layer on its surface, the coating layer including 10 to 25 mass % Ni and the balance being Zn and inevitable impurities and having a coating weight of 10 to 90 g/m2.

Abstract translation: 本发明提供了制造能够确保涂层后耐腐蚀性的热压成型件的方法。 一种制造暖压成形构件的方法包括将钢板加热到200-800℃的温度，并在上述温度范围内的温度下对钢板进行热压成形，该钢板具有 Zn-Ni合金涂层表面，涂层含有10〜25质量％的Ni，余量为Zn和不可避免的杂质，涂层重量为10〜90g / m2。

公开(公告)号：US09040166B2

公开(公告)日：2015-05-26

申请号：US13504755

申请日：2010-10-28

Applicant: Hiroki Nakamaru ,  Seiji Nakajima ,  Tatsuya Miyoshi ,  Hiroyuki Masuoka ,  Shinji Ootsuka

Inventor： Hiroki Nakamaru ,  Seiji Nakajima ,  Tatsuya Miyoshi ,  Hiroyuki Masuoka ,  Shinji Ootsuka

IPC: B32B15/04 ,  B32B15/18 ,  C21D8/02 ,  C23C2/28 ,  B32B15/01 ,  C22C18/00 ,  C22C38/02 ,  C22C38/04 ,  C22C38/06 ,  C22C38/18 ,  C22C38/32 ,  C22C38/60 ,  C23C10/28 ,  C25D5/48 ,  C25D5/50 ,  C21D1/673 ,  C23C2/26 ,  C23C10/60 ,  C23C26/00 ,  C23C28/00 ,  B21D31/00 ,  C25D3/56 ,  C21D8/04

CPC classification number: C21D8/0247 ,  B32B15/01 ,  B32B15/013 ,  B32B15/015 ,  B32B15/04 ,  B32B15/043 ,  B32B15/18 ,  C21D1/673 ,  C21D8/0457 ,  C21D2251/02 ,  C22C18/00 ,  C22C38/001 ,  C22C38/002 ,  C22C38/02 ,  C22C38/04 ,  C22C38/06 ,  C22C38/14 ,  C22C38/18 ,  C22C38/28 ,  C22C38/32 ,  C22C38/34 ,  C22C38/38 ,  C22C38/60 ,  C23C2/06 ,  C23C2/26 ,  C23C2/28 ,  C23C10/28 ,  C23C10/60 ,  C23C26/00 ,  C23C28/321 ,  C23C28/322 ,  C23C28/325 ,  C23C28/345 ,  C23C30/005 ,  C25D3/565 ,  C25D5/48 ,  C25D5/50 ,  Y10T428/12486 ,  Y10T428/1259 ,  Y10T428/12611 ,  Y10T428/12618 ,  Y10T428/1266 ,  Y10T428/12674 ,  Y10T428/12757 ,  Y10T428/12792 ,  Y10T428/12799 ,  Y10T428/12806 ,  Y10T428/12931 ,  Y10T428/12937 ,  Y10T428/12944 ,  Y10T428/12972 ,  Y10T428/12979 ,  Y10T428/2495 ,  Y10T428/24967 ,  Y10T428/264 ,  Y10T428/265

Abstract: A hot-pressed member includes a steel sheet, a Ni-diffusion region present in a surface layer of the steel sheet, and an intermetallic compound layer and a ZnO layer which are provided in order on the Ni-diffusion region, the intermetallic compound layer corresponding to a γ phase present in a phase equilibrium diagram of a Zn—Ni alloy, wherein a spontaneous immersion potential indicated in a 0.5 M NaCl aqueous air-saturated solution at 25° C.±5° C. is −600 to −360 mV based on a standard hydrogen electrode.

Abstract translation: 热压部件包括钢板，存在于钢板的表层中的Ni扩散区域和在Ni扩散区域上依次设置的金属间化合物层和ZnO层，金属间化合物层 对应于存在于Zn-Ni合金的相平衡图中的γ相，其中在25℃±5℃下在0.5M NaCl饱和空气饱和溶液中指示的自发浸渍电位为-600至-360 基于标准氢电极的mV。

公开(公告)号：US09034480B2

公开(公告)日：2015-05-19

申请号：US13989287

申请日：2011-11-25

Applicant: Masahiro Yoshida ,  Hiroki Nakamaru

Inventor： Masahiro Yoshida ,  Hiroki Nakamaru

IPC: C23C2/06 ,  C23C2/12 ,  B32B15/04 ,  B32B15/18 ,  B32B15/20 ,  C23C30/00 ,  C23C28/00 ,  C23C8/14 ,  C23C8/18

CPC classification number: C23C2/06 ,  B32B15/04 ,  B32B15/18 ,  B32B15/20 ,  C23C2/12 ,  C23C8/14 ,  C23C8/18 ,  C23C28/321 ,  C23C28/322 ,  C23C28/3225 ,  C23C28/345 ,  C23C30/005 ,  Y10T428/12757 ,  Y10T428/12799

Abstract: There is provided a hot-dip Al—Zn coated steel sheet that has a steel sheet containing Si and Mn as a base steel sheet and has excellent coating appearance and corrosion resistance. The Al—Zn coating layer has an Al content in the range of 20% to 95% by mass. The Al—Zn coating layer has a Ca content in the range of 0.01% to 10% by mass. Alternatively, the Ca and Mg content is in the range of 0.01% to 10% by mass. A steel sheet surface layer within 100 μm from a surface of the base steel sheet directly under the Al—Zn coating layer contains 0.06 to 1.0 g/m2 per surface of an oxide of at least one selected from Fe, Si, Mn, Al, P, B, Nb, Ti, Cr, Mo, Cu, and Ni in total.

Abstract translation: 提供了一种热浸镀铝锌钢板，其具有含有Si和Mn作为基础钢板的钢板，并且具有优异的涂层外观和耐腐蚀性。 Al-Zn涂层的Al含量在20质量％至95质量％的范围内。 Al-Zn系涂层的Ca含量为0.01质量％〜10质量％。 或者，Ca和Mg含量在0.01质量％至10质量％的范围内。 在从Al-Zn被覆层的正下方的基材钢板的表面100μm以下的钢板表面层，含有选自Fe，Si，Mn，Al中的至少一种以上的氧化物的表面0.06〜1.0g / m 2， P，B，Nb，Ti，Cr，Mo，Cu和Ni。

公开(公告)号：US09023488B2

公开(公告)日：2015-05-05

申请号：US13813328

申请日：2011-08-02

Applicant: Seiji Nakajima ,  Tatsuya Miyoshi ,  Hiroki Nakamaru

Inventor： Seiji Nakajima ,  Tatsuya Miyoshi ,  Hiroki Nakamaru

IPC: B32B15/04 ,  B32B15/18 ,  B21D31/00 ,  C22C38/00 ,  C23C30/00 ,  B21D22/20 ,  B32B15/01 ,  C22C18/00 ,  C22C19/03 ,  C22C38/02 ,  C22C38/04 ,  C22C38/06 ,  C22C38/28 ,  C22C38/32 ,  C22C38/60 ,  C23C28/02 ,  C25D5/14 ,  C21D8/02 ,  C25D3/56 ,  C25D5/50 ,  C22C38/38 ,  C21D1/673

CPC classification number: C22C38/00 ,  B21D22/20 ,  B21D22/208 ,  B32B15/015 ,  B32B15/043 ,  B32B15/18 ,  C21D1/673 ,  C21D8/0278 ,  C22C18/00 ,  C22C19/03 ,  C22C38/001 ,  C22C38/02 ,  C22C38/04 ,  C22C38/06 ,  C22C38/28 ,  C22C38/32 ,  C22C38/38 ,  C22C38/60 ,  C23C28/02 ,  C23C28/025 ,  C23C30/00 ,  C23C30/005 ,  C25D3/562 ,  C25D3/565 ,  C25D5/14 ,  C25D5/50 ,  Y10T428/12299 ,  Y10T428/12611 ,  Y10T428/12799 ,  Y10T428/12944 ,  Y10T428/12972 ,  Y10T428/2495

Abstract: In order to provide a steel sheet for hot pressing from which a hot-pressed part excellent in perforation corrosion resistance is obtainable and a method of manufacturing a hot-pressed part using the steel sheet for hot pressing, provided is a steel sheet for hot pressing having, sequentially on a surface of a base steel sheet: a plating layer I containing 60% by mass or more of Ni and the remainder consisting of Zn and inevitable impurities, a coating mass thereof being 0.01 to 5 g/m2; and a plating layer II containing 10 to 25% by mass of Ni and the remainder consisting of Zn and inevitable impurities, a coating mass thereof being 10 to 90 g/m2.

Abstract translation: 为了提供可获得耐穿孔性优异的热压部分的热压钢板和使用热压钢板制造热压部件的方法，提供一种用于热压的钢板 在基体钢板的表面上依次形成：含有60质量％以上的Ni的镀层I，其余由Zn和不可避免的杂质构成，其涂布质量为0.01〜5g / m 2; 和含有10〜25质量％的Ni，其余由Zn和不可避免的杂质构成的镀层II，其涂布质量为10〜90g / m 2。

公开(公告)号：US20130236739A1

公开(公告)日：2013-09-12

申请号：US13989515

申请日：2011-11-25

Applicant: Masahiro Yoshida ,  Hiroki Nakamaru

Inventor： Masahiro Yoshida ,  Hiroki Nakamaru

IPC: C23C2/02 ,  C23C2/12 ,  B32B15/01 ,  C23C2/06

CPC classification number: C23C2/02 ,  B32B15/012 ,  C23C2/06 ,  C23C2/12 ,  Y10T428/12583 ,  Y10T428/1259 ,  Y10T428/12611 ,  Y10T428/12618 ,  Y10T428/1266 ,  Y10T428/12667 ,  Y10T428/12736 ,  Y10T428/1275 ,  Y10T428/12757 ,  Y10T428/12799 ,  Y10T428/12972 ,  Y10T428/12979 ,  Y10T428/27

Abstract: There is provided a hot-dip Al—Zn coated steel sheet that has a steel sheet containing Si and Mn as a base steel sheet and has excellent coating appearance and corrosion resistance. The Al—Zn coating layer has an Al content in the range of 20% to 95% by mass. The Al—Zn coating layer has a Ca content in the range of 0.01% to 10% by mass. Alternatively, the Ca and Mg content is in the range of 0.01% to 10% by mass. A steel sheet surface layer within 100 μm from a surface of the base steel sheet directly under the Al—Zn coating layer contains less than 0.060 g/m2 per surface of an oxide of at least one selected from Fe, Si, Mn, Al, P, B, Nb, Ti, Cr, Mo, Cu, and Ni in total.

Abstract translation: 提供了一种热浸镀铝锌钢板，其具有含有Si和Mn作为基础钢板的钢板，并且具有优异的涂层外观和耐腐蚀性。 Al-Zn涂层的Al含量在20质量％至95质量％的范围内。 Al-Zn系涂层的Ca含量为0.01质量％〜10质量％。 或者，Ca和Mg含量在0.01质量％至10质量％的范围内。 从Al-Zn被覆层的正下方的基材钢板的表面100μm以内的钢板表面层，含有选自Fe，Si，Mn，Al中的至少一种以上的氧化物表面的0.060g / m 2以下， P，B，Nb，Ti，Cr，Mo，Cu和Ni。

公开(公告)号：US20080063891A1

公开(公告)日：2008-03-13

申请号：US11597117

申请日：2005-08-17

Applicant: Hiroki Nakamaru ,  Chiyoko Tada ,  Kazumi Yamashita ,  Hideo Sasaoka ,  Chiaki Kato

Inventor： Hiroki Nakamaru ,  Chiyoko Tada ,  Kazumi Yamashita ,  Hideo Sasaoka ,  Chiaki Kato

IPC: B21D39/00

CPC classification number: C23C2/06 ,  C23C2/26 ,  C23C22/22 ,  C23C28/321 ,  C23C28/3225 ,  C23C28/345 ,  C25D3/22 ,  C25D11/36 ,  Y10T428/12438 ,  Y10T428/12493 ,  Y10T428/12535 ,  Y10T428/12611 ,  Y10T428/12618 ,  Y10T428/1266 ,  Y10T428/12729 ,  Y10T428/12792 ,  Y10T428/12799 ,  Y10T428/12951 ,  Y10T428/12972 ,  Y10T428/12979

Abstract: The phosphate-treated zinc-coated steel sheet has: a steel sheet; a zinc-coating layer of a single η-phase containing Ni in a range from 10 ppm by mass to solid solution limit, being formed on at least one side of the steel sheet; and a phosphate-treated layer containing Mg in a range from not less than 0.1% by mass to less than 2.0% by mass, being formed on the zinc-coating layer. The steel sheet without treated by sealing has corrosion resistance equivalent to or higher than that of conventional products treated by sealing, and also has excellent blackening resistance.

Abstract translation: 磷酸盐处理的镀锌钢板具有：钢板; 在钢板的至少一面上形成含有10质量ppm〜固溶极限的Ni的单一η相的锌被膜层; 在锌被覆层上形成含有0.1质量％以上且小于2.0质量％的Mg的磷酸盐处理层。 未经密封处理的钢板的耐腐蚀性等于或高于通过密封处理的常规产品的耐腐蚀性，并且还具有优异的耐黑变性。

公开(公告)号：US07166759B2

公开(公告)日：2007-01-23

申请号：US10045316

申请日：2001-11-07

Applicant: Hiroki Nakamaru ,  Haruhiko Miyazawa ,  Yoshiei Kato

Inventor： Hiroki Nakamaru ,  Haruhiko Miyazawa ,  Yoshiei Kato

IPC: A62D3/00 ,  C02F1/68 ,  C02F1/70 ,  B09C1/08 ,  B09C1/10

CPC classification number: A62D3/34 ,  A62D3/37 ,  A62D2101/22 ,  B09C1/00 ,  B09C1/002 ,  B09C1/08 ,  C02F1/70 ,  C02F2101/32 ,  C02F2101/36 ,  Y10S588/901

Abstract: The invention provides a remediation method of soil, water and/or gases by prompt dehalogenation of halogenated hydrocarbons by allowing the halogenated hydrocarbons contained at least in one of the soil, water and/or gases to contact an iron powder containing about 0.03 to about 2% by mass of sulfur preferably on the surface, and an iron powder for use in the remediation method.

Abstract translation: 本发明通过使含有至少一种土壤，水和/或气体中的至少一种的卤代烃与含有约0.03至约2的铁粉接触来迅速脱卤卤代烃来提供土壤，水和/或气体的补救方法 质量％硫优选在表面上，以及用于补救方法的铁粉。

公开(公告)号：US09234267B2

公开(公告)日：2016-01-12

申请号：US13989515

申请日：2011-11-25

Applicant: Masahiro Yoshida ,  Hiroki Nakamaru

Inventor： Masahiro Yoshida ,  Hiroki Nakamaru

IPC: C23C2/02 ,  C23C2/06 ,  C23C2/12 ,  B32B15/01

CPC classification number: C23C2/02 ,  B32B15/012 ,  C23C2/06 ,  C23C2/12 ,  Y10T428/12583 ,  Y10T428/1259 ,  Y10T428/12611 ,  Y10T428/12618 ,  Y10T428/1266 ,  Y10T428/12667 ,  Y10T428/12736 ,  Y10T428/1275 ,  Y10T428/12757 ,  Y10T428/12799 ,  Y10T428/12972 ,  Y10T428/12979 ,  Y10T428/27

Abstract: There is provided a hot-dip Al—Zn coated steel sheet that has a steel sheet containing Si and Mn as a base steel sheet and has excellent coating appearance and corrosion resistance. The Al—Zn coating layer has an Al content in the range of 20% to 95% by mass. The Al—Zn coating layer has a Ca content in the range of 0.01% to 10% by mass. Alternatively, the Ca and Mg content is in the range of 0.01% to 10% by mass. A steel sheet surface layer within 100 μm from a surface of the base steel sheet directly under the Al—Zn coating layer contains less than 0.060 g/m2 per surface of an oxide of at least one selected from Fe, Si, Mn, Al, P, B, Nb, Ti, Cr, Mo, Cu, and Ni in total.

Abstract translation: 提供了一种热浸镀铝锌钢板，其具有含有Si和Mn作为基础钢板的钢板，并且具有优异的涂层外观和耐腐蚀性。 Al-Zn涂层的Al含量在20质量％至95质量％的范围内。 Al-Zn系涂层的Ca含量为0.01质量％〜10质量％。 或者，Ca和Mg含量在0.01质量％至10质量％的范围内。 在Al-Zn被覆层的正下方的基材钢板的表面100μm以下的钢板表面层，含有选自Fe，Si，Mn，Al， P，B，Nb，Ti，Cr，Mo，Cu和Ni。