发明授权
US09212247B2 Method for controlling size distribution of polymer particles during preparation of aqueous polymer dispersion and aqueous polymer dispersion
有权
在制备聚合物水分散体和聚合物水分散体的过程中控制聚合物颗粒尺寸分布的方法
- 专利标题: Method for controlling size distribution of polymer particles during preparation of aqueous polymer dispersion and aqueous polymer dispersion
- 专利标题(中): 在制备聚合物水分散体和聚合物水分散体的过程中控制聚合物颗粒尺寸分布的方法
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申请号: US14510200申请日: 2014-10-09
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公开(公告)号: US09212247B2公开(公告)日: 2015-12-15
- 发明人: Helena Peuranen , Perttu Heiska , Kimmo Huhtala , Nina Bruun
- 申请人: Kemira Oyj
- 申请人地址: FI Helsinki
- 专利权人: Kemira Oyj
- 当前专利权人: Kemira Oyj
- 当前专利权人地址: FI Helsinki
- 代理机构: Thomas Horstemeyer, LLP
- 优先权: FI20125036 20120112
- 主分类号: C08L1/00
- IPC分类号: C08L1/00 ; C08L31/00 ; C08F251/00 ; C08F2/16 ; C08F212/08 ; D21H21/16 ; C08F2/20 ; D21H17/24 ; D21H17/36 ; D21H17/37 ; C08F220/18 ; C08K3/20
摘要:
The present disclosure relates to a method for controlling size distribution of formed polymer particles during preparation of aqueous polymer dispersion. The method comprises obtaining an aqueous polysaccharide solution, which comprises about 10 to 40 weight-% polysaccharide containing a free hydroxyl group, such as starch, and polymerising in the polysaccharide solution in the presence of a graft-linking, water-soluble redox system about 30 to 60 weight-% of at least one optionally substituted styrene, about 60 to 30 weight-% of at least one C1-C4-alkyl(meth)acrylate, and 0 to about 10 weight-% of other ethylenically unsaturated copolymerizable monomers. The size distribution of the formed polymer particles is controlled by adjusting viscosity of the polysaccharide solution before the polymerisation to a level less than about 20 mPas.
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