发明授权
- 专利标题: Stable support for Fischer-Tropsch catalyst
- 专利标题(中): 稳定支持费 - 托催化剂
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申请号: US14873676申请日: 2015-10-02
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公开(公告)号: US09370768B2公开(公告)日: 2016-06-21
- 发明人: Kandaswamy Jothimurugesan
- 申请人: Chevron U.S.A. Inc.
- 申请人地址: US CA San Ramon
- 专利权人: Chevron U.S.A. Inc.
- 当前专利权人: Chevron U.S.A. Inc.
- 当前专利权人地址: US CA San Ramon
- 代理商 Karen R. DiDomenicis
- 主分类号: B01J27/198
- IPC分类号: B01J27/198 ; C10G2/00 ; B01J23/89 ; B01J37/02 ; B01J37/08 ; B01J37/18 ; B01J37/16 ; B01J35/02 ; B01J37/14 ; B01J35/00 ; B01J35/10
摘要:
A process has been developed for preparing a Fischer-Tropsch catalyst precursor and a Fischer-Tropsch catalyst made from the precursor. The process includes contacting a gamma alumina catalyst support material with a first solution containing a vanadium compound and a phosphorus compound, to obtain a modified catalyst support material. The modified catalyst support material is calcined at a temperature of at least 500° C. The modified catalyst support is less soluble in acid solutions than an equivalent unmodified catalyst support. The modified catalyst support loses no more than 6% of its pore volume when exposed to water vapor. The modified catalyst support is contacted with a second solution which includes a precursor compound of an active cobalt catalyst component to obtain a catalyst precursor. The Fischer-Tropsch catalyst has enhanced hydrothermal stability as measured by losing no more than 10% of its pore volume when exposed to water vapor.
公开/授权文献
- US20160067688A1 STABLE SUPPORT FOR FISCHER-TROPSCH CATALYST 公开/授权日:2016-03-10