Invention Grant
- Patent Title: Metal complex and supported metal complex having disiloxane as ligand, method for production therefor, and supported metal catalyst prepared by using the same
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Application No.: US14774481Application Date: 2014-03-13
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Publication No.: US09616418B2Publication Date: 2017-04-11
- Inventor: Jun-Chul Choi , Norihisa Fukaya , Hiroyuki Yasuda
- Applicant: NATIONAL INSTITUTE OF ADVANCED INDUSTRIAL SCIENCE AND TECHNOLOGY
- Applicant Address: JP Tokyo
- Assignee: National Institute of Advanced Industrial Science and Technology
- Current Assignee: National Institute of Advanced Industrial Science and Technology
- Current Assignee Address: JP Tokyo
- Agency: Myers Bigel, P.A.
- Priority: JP2013-051526 20130314
- International Application: PCT/JP2014/056716 WO 20140313
- International Announcement: WO2014/142252 WO 20140918
- Main IPC: B01J29/74
- IPC: B01J29/74 ; C01B39/46 ; C01B33/20 ; B01J23/42 ; B01J37/08 ; C07F15/00 ; B01J31/16 ; B01J35/00 ; B01J29/03 ; B01J31/18 ; B01J31/20 ; B01J31/22 ; B01J31/24 ; C07C5/03

Abstract:
A metal complex represented by the following Formula (1): (wherein M represents palladium or platinum; L represents a ligand selected from carbon monoxide, an olefin compound, an amine compound, a phosphine compound, an N-heterocyclic carbene compound, a nitrile compound and an isocyanide compound; n represents an integer of 0 to 2 showing the number of the ligand; and each of R1 to R4 represents an organic group). The metal complex described above can be fixed on an inorganic oxide while maintaining a skeletal structure thereof to obtain a supported metal complex, which makes it possible to allow the supported metal complex to maintain the same catalytic activity as that of the original metal complex. Also, calcining the supported metal complex obtained in the manner described above makes it possible to obtain a supported metal catalyst improved in catalytic activity to a greater extent than conventional supported metal catalysts.
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