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公开(公告)号：US20190308182A1
公开(公告)日：2019-10-10
申请号：US16466436
申请日：2017-12-06
Applicant: NATIONAL INSTITUTE OF ADVANCED INDUSTRIAL SCIENCE AND TECHNOLOGY , N.E. CHEMCAT CORPORATION
Inventor： Junchul Choi , Norihisa Fukaya , Shunya Onozawa , Kazuhiko Sato , Hiroyuki Yasuda , Tomoteru Mizusaki , Yukio Takagi
IPC: B01J31/22
Abstract: An organometallic complex catalyst is disclosed for use in a cross-coupling reaction. In formula (1), M is the coordination center and represents a metal atom such as Pd or an ion thereof. R1, R2, and R3 may be the same or different and are a substituent such as a hydrogen atom. R4, R5, R6, and R7 may be the same or different and are a substituent such as a hydrogen atom. X represents a halogen atom. R8 represents a substituent that has a π bond and 3-20 carbon atoms. With regard to the electron-donating properties of R1-R7 with respect to the coordination center M of the ligand containing R1-R7 that is indicated in formula (2), R1-R7 are arranged in combination such that the TEP value obtained from infrared spectroscopy shifts toward the high frequency side compared to the TEP value of the ligand of formula (2-1).
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2.发明申请METAL COMPLEX AND SUPPORTED METAL COMPLEX HAVING DISILOXANE AS LIGAND, METHOD FOR PRODUCTION THEREFOF, AND SUPPORTED METAL CATALYST PREPARED BY USING THE SAME 有权金属复合物和具有作为配体的甲硅烷酸的支持金属络合物，其制备方法和使用其制备的支持的金属催化剂公开(公告)号：US20160030932A1
公开(公告)日：2016-02-04
申请号：US14774481
申请日：2014-03-13
Inventor： Jun-Chul Choi , Norihisa Fukaya , Hiroyuki Yasuda
CPC classification number: B01J31/1608 , B01J23/42 , B01J23/44 , B01J29/0325 , B01J29/74 , B01J31/1633 , B01J31/1805 , B01J31/20 , B01J31/223 , B01J31/2273 , B01J31/2295 , B01J31/24 , B01J35/002 , B01J35/006 , B01J37/08 , B01J37/086 , B01J2231/323 , B01J2231/645 , B01J2531/824 , B01J2531/828 , C01B33/20 , C01B39/46 , C07C5/03 , C07C2531/22 , C07C2601/18 , C07F15/006 , C07F15/0066 , C07F15/0086 , C07F15/0093 , Y02P20/588 , C07C13/26
Abstract: A metal complex represented by the following Formula (1): (wherein M represents palladium or platinum; L represents a ligand selected from carbon monoxide, an olefin compound, an amine compound, a phosphine compound, an N-heterocyclic carbene compound, a nitrile compound and an isocyanide compound; n represents an integer of 0 to 2 showing the number of the ligand; and each of R1 to R4 represents an organic group). The metal complex described above can be fixed on an inorganic oxide while maintaining a skeletal structure thereof to obtain a supported metal complex, which makes it possible to allow the supported metal complex to maintain the same catalytic activity as that of the original metal complex. Also, calcining the supported metal complex obtained in the manner described above makes it possible to obtain a supported metal catalyst improved in catalytic activity to a greater extent than conventional supported metal catalysts.
Abstract translation: 由下式（1）表示的金属络合物：其中M表示钯或铂; L表示选自一氧化碳，烯烃化合物，胺化合物，膦化合物，N-杂环卡宾化合物，腈 化合物和异氰化物化合物; n表示0〜2的整数，表示配体数; R 1〜R 4分别表示有机基）。 上述金属络合物可以固定在无机氧化物上，同时保持其骨架结构以获得负载的金属络合物，这使得可以使负载的金属络合物保持与原始金属络合物相同的催化活性。 此外，通过以上述方式煅烧所得到的负载型金属络合物，可以得到比现有的负载型金属催化剂更大程度地得到催化活性提高的负载型金属催化剂。
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公开(公告)号：US10213777B2
公开(公告)日：2019-02-26
申请号：US15448128
申请日：2017-03-02
Inventor： Jun-Chul Choi , Norihisa Fukaya , Hiroyuki Yasuda
IPC: C07C5/03 , B01J31/16 , B01J37/08 , C07F15/00 , B01J23/42 , B01J35/00 , B01J29/74 , C01B33/20 , C01B39/46 , B01J29/03 , B01J31/18 , B01J31/20 , B01J31/22 , B01J31/24 , B01J23/44
Abstract: A metal complex represented by the following Formula (1): (wherein M represents palladium or platinum; L represents a ligand selected from carbon monoxide, an olefin compound, an amine compound, a phosphine compound, an N-heterocyclic carbene compound, a nitrile compound and an isocyanide compound; n represents an integer of 0 to 2 showing the number of the ligand; and each of R1 to R4 represents an organic group). The metal complex described above can be fixed on an inorganic oxide while maintaining a skeletal structure thereof to obtain a supported metal complex, and this makes it possible to allow the supported metal complex to maintain the same catalytic activity as that of the original metal complex. Also, calcining the supported metal complex obtained in the manner described above makes it possible to obtain a supported metal catalyst which is improved in catalytic activity to a greater extent than conventional supported metal catalysts.
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公开(公告)号：US09586927B2
公开(公告)日：2017-03-07
申请号：US14903225
申请日：2014-07-18
Applicant: MARUZEN PETROCHEMICAL CO., LTD. , NATIONAL INSTITUTE OF ADVANCED INDUSTRIAL SCIENCE AND TECHNOLOGY
Inventor： Takashi Naniki , Yasunori Hayashi , Goro Sawada , Takuro Furukawa , Takeshi Haruna , Toshikazu Takahashi , Hiroyuki Yasuda , Shouji Yamamoto
IPC: C07D317/08 , C07D317/38 , B01J31/02
CPC classification number: C07D317/38 , B01J27/08 , B01J31/0231 , B01J31/0239 , B01J31/0254 , B01J31/0268 , B01J31/0269 , B01J31/0271 , B01J2231/341 , B01J2531/90
Abstract: Provided is a method for continuously producing a cyclic carbonate, by which generation of a glycol in a reaction for synthesizing a cyclic carbonate is suppressed, and a cyclic carbonate having a high purity can be efficiently obtained even by simple purification.A method for continuously producing a cyclic carbonate, including filling a catalyst in a fixed-bed tube reactor, and continuously feeding carbon dioxide and an epoxide to the fixed-bed tube reactor to thereby bringing the carbon dioxide and the epoxide into contact with the catalyst, while continuously withdrawing the reaction liquid in the fixed-bed tube reactor, wherein the method includes a pre-treatment step in which a pre-treatment liquid containing a cyclic carbonate is brought into contact with the catalyst before feeding the carbon dioxide and the epoxide to the fixed-bed tube reactor, and the generated glycol is removed out of the system.
Abstract translation: 一种连续生产环状碳酸酯的方法，包括在固定床管式反应器中填充催化剂，并将二氧化碳和环氧化物连续供给到固定床管式反应器中，从而使二氧化碳和环氧化物与催化剂接触 同时连续抽出固定床管式反应器中的反应液，其中该方法包括一预处理步骤，其中将含有环状碳酸酯的预处理液体与进料二氧化碳和环氧化物 到固定床管式反应器中，并将生成的二醇从系统中除去。
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公开(公告)号：US11161103B2
公开(公告)日：2021-11-02
申请号：US16466436
申请日：2017-12-06
Applicant: NATIONAL INSTITUTE OF ADVANCED INDUSTRIAL SCIENCE AND TECHNOLOGY , N.E. CHEMCAT CORPORATION
Inventor： Junchul Choi , Norihisa Fukaya , Shunya Onozawa , Kazuhiko Sato , Hiroyuki Yasuda , Tomoteru Mizusaki , Yukio Takagi
IPC: B01J31/22
Abstract: An organometallic complex catalyst is disclosed for use in a cross-coupling reaction. In formula (1), M is the coordination center and represents a metal atom such as Pd or an ion thereof. R1, R2, and R3 may be the same or different and are a substituent such as a hydrogen atom. R4, R5, R6, and R7 may be the same or different and are a substituent such as a hydrogen atom. X represents a halogen atom. R8 represents a substituent that has a π bond and 3-20 carbon atoms. With regard to the electron-donating properties of R1-R7 with respect to the coordination center M of the ligand containing R1-R7 that is indicated in formula (2), R1-R7 are arranged in combination such that the TEP value obtained from infrared spectroscopy shifts toward the high frequency side compared to the TEP value of the ligand of formula (2-1).
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Patent Agency Ranking
公开(公告)号：US10738190B2
公开(公告)日：2020-08-11
申请号：US16086779
申请日：2017-02-28
Applicant: SHIN-ETSU CHEMICAL CO., LTD. , NATIONAL INSTITUTE OF ADVANCED INDUSTRIAL SCIENCE AND TECHNOLOGY
Inventor： Masayuki Ikeno , Takeshi Miyao , Takeharu Toyoshima , Jun-chul Choi , Norihisa Fukaya , Hiroyuki Yasuda
IPC: C08L83/04 , C08K9/06 , C08L101/00 , B01J31/22 , B01J31/16
Abstract: A resin composition includes: (a) a supported platinum catalyst having a structure shown by the following general formula (1) in which a platinum complex is supported on a surface of an inorganic oxide; and (b) a thermoplastic matrix resin. The resin composition is usable as an addition-reaction catalyst capable of imparting sufficient storability and quick curability to an addition-reaction curable composition. In the formula, L represents a ligand selected from carbon monoxide, an olefin compound, an amine compound, a phosphine compound, an N-heterocyclic carbene compound, a nitrile compound, and an isocyanide compound; and n represents the number of Ls and an integer from 0 to 2.
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公开(公告)号：US09856229B2
公开(公告)日：2018-01-02
申请号：US14904488
申请日：2014-07-18
Applicant: NATIONAL INSTITUTE OF ADVANCED INDUSTRIAL SCIENCE AND TECHNOLOGY , MARUZEN PETROCHEMICAL CO., LTD.
Inventor： Toshikazu Takahashi , Hiroyuki Yasuda , Shouji Yamamoto , Takashi Naniki , Yasunori Hayashi , Takeshi Haruna , Takuro Furukawa
IPC: C07D317/38 , C07D317/36 , B01J31/02
CPC classification number: C07D317/38 , B01J31/0239 , B01J31/0254 , B01J31/0268 , B01J31/0269 , B01J2231/341 , C07D317/36 , Y02P20/142
Abstract: Provided is a method for producing a cyclic carbonate obtained by reacting epoxide and carbon dioxide in the presence of a quaternary onium salt as a counter ion or a quaternary phosphonium salt having a halogenated anion as a counter ion, or in the presence of a solid catalyst obtained by immobilizing the quaternary onium salt onto a carrier, wherein an organohalogen compound containing at least one halogen atom in one molecule is added to the reaction system.
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公开(公告)号：US20170267701A1
公开(公告)日：2017-09-21
申请号：US15309900
申请日：2015-04-30
Inventor： Norihisa Fukaya , Seong-Jib Choi , Jun-Chul Choi , Toshio Horikoshi , Kazuhiko Sato , Hiroyuki Yasuda
IPC: C07F7/04
Abstract: An object of the present invention is to provide a method for producing tetraalkoxysilane while saving energy at a high yield. Tetraalkoxysilane can be produced while saving energy at a high yield by the method including a first step of reacting alcohol with carbon dioxide in the presence of a dehydrating agent and/or in a reactor provided with a dehydrating means, and a second step of reacting a reaction mixture obtained in the first step with silicon oxide.
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公开(公告)号：US09616418B2
公开(公告)日：2017-04-11
申请号：US14774481
申请日：2014-03-13
Inventor： Jun-Chul Choi , Norihisa Fukaya , Hiroyuki Yasuda
IPC: B01J29/74 , C01B39/46 , C01B33/20 , B01J23/42 , B01J37/08 , C07F15/00 , B01J31/16 , B01J35/00 , B01J29/03 , B01J31/18 , B01J31/20 , B01J31/22 , B01J31/24 , C07C5/03
CPC classification number: B01J31/1608 , B01J23/42 , B01J23/44 , B01J29/0325 , B01J29/74 , B01J31/1633 , B01J31/1805 , B01J31/20 , B01J31/223 , B01J31/2273 , B01J31/2295 , B01J31/24 , B01J35/002 , B01J35/006 , B01J37/08 , B01J37/086 , B01J2231/323 , B01J2231/645 , B01J2531/824 , B01J2531/828 , C01B33/20 , C01B39/46 , C07C5/03 , C07C2531/22 , C07C2601/18 , C07F15/006 , C07F15/0066 , C07F15/0086 , C07F15/0093 , Y02P20/588 , C07C13/26
Abstract: A metal complex represented by the following Formula (1): (wherein M represents palladium or platinum; L represents a ligand selected from carbon monoxide, an olefin compound, an amine compound, a phosphine compound, an N-heterocyclic carbene compound, a nitrile compound and an isocyanide compound; n represents an integer of 0 to 2 showing the number of the ligand; and each of R1 to R4 represents an organic group). The metal complex described above can be fixed on an inorganic oxide while maintaining a skeletal structure thereof to obtain a supported metal complex, which makes it possible to allow the supported metal complex to maintain the same catalytic activity as that of the original metal complex. Also, calcining the supported metal complex obtained in the manner described above makes it possible to obtain a supported metal catalyst improved in catalytic activity to a greater extent than conventional supported metal catalysts.
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公开(公告)号：US20220032278A1
公开(公告)日：2022-02-03
申请号：US17490143
申请日：2021-09-30
Applicant: NATIONAL INSTITUTE OF ADVANCED INDUSTRIAL SCIENCE AND TECHNOLOGY , N.E. CHEMCAT CORPORATION
Inventor： Junchul Choi , Norihisa Fukaya , Shunya Onozawa , Kazuhiko Sato , Hiroyuki Yasuda , Tomoteru Mizusaki , Yukio Takagi
IPC: B01J31/22
Abstract: An organometallic complex catalyst that makes it possible to obtain a higher yield of a desired product than conventional catalysts in a cross-coupling reaction. The organometallic complex catalyst has a structure represented by formula (1) and is for use in a cross-coupling reaction. In formula (1), M is the coordination center and represents a metal atom such as Pd or an ion thereof. R1, R2, and R3 may be the same or different and are a substituent such as a hydrogen atom. R4, R5, R6, and R7 may be the same or different and are a substituent such as a hydrogen atom. X represents a halogen atom. R8 represents a substituent that has a π bond and 3-20 carbon atoms. With regard to the electron-donating properties of R1-R7 with respect to the coordination center M of the ligand containing R1-R7 that is indicated in formula (2), R1-R7 are arranged in combination such that the TEP value obtained from infrared spectroscopy shifts toward the low frequency side compared to the TEP value of the ligand of formula (2-1).
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