Invention Grant
- Patent Title: Gas and liquid phase catalytic Beckmann rearrangement of oximes to produce lactams
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Application No.: US14263156Application Date: 2014-04-28
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Publication No.: US09662643B2Publication Date: 2017-05-30
- Inventor: Alan B. Levy , Robert Raja , Matthew E. Potter
- Applicant: AdvanSix Resins & Chemicals LLC , University of Southampton
- Applicant Address: US NJ Parsippany GB Southampton
- Assignee: AdvanSix Resins & Chemical LLC,University of Southampton
- Current Assignee: AdvanSix Resins & Chemical LLC,University of Southampton
- Current Assignee Address: US NJ Parsippany GB Southampton
- Agency: Faegre Baker Daniels LLP
- Main IPC: C01B39/54
- IPC: C01B39/54 ; B01J29/85 ; C07D201/04 ; B01J35/00 ; C07D223/10 ; C07D225/02 ; C01B37/08

Abstract:
Methods for producing lactams from oximes by performing a Beckmann rearrangement using a silicoaluminophosphate catalyst are provided. These catalysts may be used in gas phase or liquid phase reactions to convert oximes into lactams. High conversion of oxime and high selectivity for the desired lactams are produced using the disclosed methods, including high conversion and selectivity for ε-caprolactam produced from cyclohexanone oxime and high conversion and selectivity for ω-laurolactam produced from cyclododecanone oxime.
Public/Granted literature
- US20160279622A9 GAS AND LIQUID PHASE CATALYTIC BECKMANN REARRANGEMENT OF OXIMES TO PRODUCE LACTAMS Public/Granted day:2016-09-29
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