公开(公告)号：US09822052B2

公开(公告)日：2017-11-21

申请号：US15279837

申请日：2016-09-29

申请人： AdvanSix Resins & Chemicals LLC ,  University of Southampton

发明人： Alan B. Levy ,  Scott R. Keenan ,  Robert Raja ,  Arran M. Gill ,  Matthew E. Potter ,  Sivan A. Van Aswegen

IPC分类号： C07C45/35 ,  B01J27/00 ,  B01J37/00 ,  C07C45/39 ,  B01J27/13 ,  B01J27/185 ,  B01J37/04 ,  B01J37/08

CPC分类号： C07C45/39 ,  B01J23/42 ,  B01J23/44 ,  B01J23/52 ,  B01J23/8926 ,  B01J27/13 ,  B01J27/1856 ,  B01J35/0013 ,  B01J35/002 ,  B01J37/04 ,  B01J37/08 ,  B01J37/088 ,  B01J37/18 ,  B01J37/343 ,  C07C2601/14 ,  C07C49/403

摘要： Methods for converting an alcohol, such as cyclohexanol to a ketone, such as cyclohexanone, include reacting the alcohol in the presence of a catalyst and oxygen to produce the ketone. In one exemplary embodiment, the catalyst comprises a microporous copper chloropyrophosphate framework including a plurality of noble metal nanoparticles. In one exemplary embodiment, the noble metal nanoparticles include at least one metal selected from the group consisting of platinum, palladium, and gold.

公开(公告)号：US09662643B2

公开(公告)日：2017-05-30

申请号：US14263156

申请日：2014-04-28

申请人： AdvanSix Resins & Chemicals LLC ,  University of Southampton

发明人： Alan B. Levy ,  Robert Raja ,  Matthew E. Potter

IPC分类号： C01B39/54 ,  B01J29/85 ,  C07D201/04 ,  B01J35/00 ,  C07D223/10 ,  C07D225/02 ,  C01B37/08

CPC分类号： B01J29/85 ,  B01J35/002 ,  C01B37/08 ,  C01B39/54 ,  C07D201/04 ,  C07D223/10 ,  C07D225/02 ,  Y02P20/52

摘要： Methods for producing lactams from oximes by performing a Beckmann rearrangement using a silicoaluminophosphate catalyst are provided. These catalysts may be used in gas phase or liquid phase reactions to convert oximes into lactams. High conversion of oxime and high selectivity for the desired lactams are produced using the disclosed methods, including high conversion and selectivity for ε-caprolactam produced from cyclohexanone oxime and high conversion and selectivity for ω-laurolactam produced from cyclododecanone oxime.

公开(公告)号：US10537884B2

公开(公告)日：2020-01-21

申请号：US16161662

申请日：2018-10-16

申请人： AdvanSix Resins & Chemicals LLC

发明人： Alan B. Levy ,  Robert Raja ,  Stephanie H. Newland ,  Scott R. Keenan ,  Simon R. Bare

IPC分类号： B01J29/06 ,  B01J29/84 ,  C07D225/02 ,  C07D223/10 ,  B01J29/85 ,  B01J29/89 ,  B01J35/10 ,  C01B37/08 ,  C01B39/54 ,  B01J29/04 ,  B01J37/03 ,  B01J29/83

摘要： Methods for producing lactams from oximes by performing a Beckmann rearrangement using a hierarchical porous aluminophosphate catalyst having interconnected microporous and mesoporous networks are provided. Exemplary catalysts include a plurality of weak Brønsted acid active sites, including silicon-containing aluminophosphates having the IZA framework code AFI, such as SAPO-5, CHA, such as SAPO-34, and FAU, such as SAPO-37.

公开(公告)号：US20190046963A1

公开(公告)日：2019-02-14

申请号：US16161662

申请日：2018-10-16

申请人： AdvanSix Resins & Chemicals LLC

发明人： Alan B. Levy ,  Robert Raja ,  Stephanie H. Newland ,  Scott R. Keenan ,  Simon R. Bare

IPC分类号： B01J29/84 ,  C01B39/54 ,  C01B37/08 ,  B01J35/10 ,  B01J29/85 ,  C07D223/10 ,  C07D225/02 ,  B01J29/89

摘要： Methods for producing lactams from oximes by performing a Beckmann rearrangement using a hierarchical porous aluminophosphate catalyst having interconnected microporous and mesoporous networks are provided. Exemplary catalysts include a plurality of weak Brønsted acid active sites, including silicon-containing aluminophosphates having the IZA framework code AFI, such as SAPO-5, CHA, such as SAPO-34, and FAU, such as SAPO-37.

公开(公告)号：US20130245323A1

公开(公告)日：2013-09-19

申请号：US13889411

申请日：2013-05-08

申请人： UNIVERSITY OF SOUTHAMPTON

发明人： Robert Raja ,  John Meuring THOMAS

IPC分类号： C07C249/04 ,  B01J27/187 ,  B01J27/185

CPC分类号： C07C249/04 ,  B01J27/1853 ,  B01J27/187 ,  B01J29/84 ,  B01J29/85 ,  B01J2229/18 ,  C07C2601/14 ,  C07C251/44

摘要： A redox ammoximation process in which a ketone or aldehyde is reacted with ammonia and oxygen in the presence of a catalyst; wherein the catalyst is an aluminophosphate based redox catalyst having at least two different redox catalytic sites comprising different transition metal atoms.

摘要翻译： 一种氧化还原氨肟化方法，其中酮或醛在催化剂存在下与氨和氧反应; 其中所述催化剂是具有包含不同过渡金属原子的至少两种不同氧化还原催化位点的磷酸铝基氧化还原催化剂。

公开(公告)号：US09221762B2

公开(公告)日：2015-12-29

申请号：US14273688

申请日：2014-05-09

申请人： Honeywell International Inc. ,  University of Southampton

发明人： Alan B. Levy ,  Robert Raja ,  Matthew E. Potter

IPC分类号： C07D201/04 ,  C07D223/10 ,  B01J29/85 ,  B01J35/00 ,  C07D225/02

CPC分类号： B01J29/85 ,  B01J35/002 ,  C01B37/08 ,  C01B39/54 ,  C07D201/04 ,  C07D223/10 ,  C07D225/02 ,  Y02P20/52

摘要： Methods for producing lactams from oximes by performing a Beckmann rearrangement using a silicoaluminophosphate catalyst are provided. These catalysts may be used in gas phase or liquid phase reactions to convert oximes into lactams. High conversion of oxime and high selectivity for the desired lactams are produced using the disclosed methods, including high conversion and selectivity for ε-caprolactam produced from cyclohexanone oxime and high conversion and selectivity for ω-laurolactam produced from cyclododecanone oxime.

摘要翻译： 提供了通过使用硅铝磷酸盐催化剂进行贝克曼重排来从肟产生内酰胺的方法。 这些催化剂可用于气相或液相反应以将肟转化成内酰胺。 使用所公开的方法制备肟的高转化率和高选择性，包​​括由环己酮肟产生的ε-己内酰胺的高转化率和选择性，以及由环十二酮肟产生的ω-月桂内酰胺的高转化率和选择性。

公开(公告)号：US08779124B2

公开(公告)日：2014-07-15

申请号：US13889404

申请日：2013-05-08

申请人： University of Southampton

发明人： Robert Raja ,  Alexander James Patterson

IPC分类号： C07C249/04 ,  C07C251/32 ,  C07D201/04

CPC分类号： C07C249/04 ,  B01J27/1853 ,  B01J27/187 ,  B01J29/84 ,  B01J35/002 ,  C01B37/065 ,  C07C249/08 ,  C07C2601/14 ,  C07C251/44

摘要： A redox ammoximation process in which a ketone or aldehyde is reacted with ammonia and oxygen in the presence of a catalyst, wherein: the catalyst is an aluminophosphate based redox catalyst having the qualitative general formula (I) M1M2AlPO-5 (I) in which M1 is at least one transition metal atom having redox catalytic capability; M2 is at least one metal atom in the (IV) oxidation state; M1 and M2 are different from each other; and a proportion of the phosphorous atoms in the M1M2AlPO-5 type structure are replaced by M2 atoms.

摘要翻译： 一种氧化还原氨肟化方法，其中酮或醛在催化剂存在下与氨和氧反应，其中：该催化剂是具有定性通式（I）M1M2AlPO-5（I）的磷酸铝基氧化还原催化剂，其中M1 是至少一种具有氧化还原催化能力的过渡金属原子; M2是（IV）氧化态中的至少一个金属原子; M1和M2彼此不同; M1M2AlPO-5型结构中的一部分磷原子被M2原子取代。

公开(公告)号：US08772476B2

公开(公告)日：2014-07-08

申请号：US13658495

申请日：2012-10-23

申请人： Honeywell International Inc. ,  University of Southampton

发明人： Alan B. Levy ,  Robert Raja ,  Matthew E. Potter

IPC分类号： C07D201/04 ,  C07D223/10

CPC分类号： B01J29/85 ,  B01J35/002 ,  C01B37/08 ,  C01B39/54 ,  C07D201/04 ,  C07D223/10 ,  C07D225/02 ,  Y02P20/52

摘要： Methods for producing lactams from oximes by performing a Beckmann rearrangement using a silicoaluminophosphate catalyst are provided. These catalysts may be used in gas phase or liquid phase reactions to convert oximes into lactams. High conversion of oxime and high selectivity for the desired lactams are produced using the disclosed methods, including high conversion and selectivity for ε-caprolactam produced from cyclohexanone oxime and high conversion and selectivity for ω-laurolactam produced from cyclododecanone oxime.

摘要翻译： 提供了通过使用硅铝磷酸盐催化剂进行贝克曼重排来从肟产生内酰胺的方法。 这些催化剂可用于气相或液相反应以将肟转化成内酰胺。 使用所公开的方法制备肟的高转化率和高选择性，包​​括由环己酮肟产生的ε-己内酰胺的高转化率和选择性，以及由环十二酮肟产生的ω-月桂内酰胺的高转化率和选择性。

公开(公告)号：US20180065910A1

公开(公告)日：2018-03-08

申请号：US15790235

申请日：2017-10-23

申请人： AdvanSixResins & Chemicals LLC ,  University of Southampton

发明人： Alan B. Levy ,  Scott R. Keenan ,  Robert Raja ,  Arran M. Gill ,  Matthew E. Potter ,  Sivan A. Van Aswegen

IPC分类号： C07C45/39 ,  B01J37/08 ,  B01J37/04 ,  B01J27/13 ,  B01J27/185 ,  C07C49/403

CPC分类号： C07C45/39 ,  B01J23/42 ,  B01J23/44 ,  B01J23/52 ,  B01J23/8926 ,  B01J27/13 ,  B01J27/1856 ,  B01J35/0013 ,  B01J35/002 ,  B01J37/04 ,  B01J37/08 ,  B01J37/088 ,  B01J37/18 ,  B01J37/343 ,  C07C2601/14 ,  C07C49/403

摘要： Methods for converting an alcohol, such as cyclohexanol to a ketone, such as cyclohexanone, include reacting the alcohol in the presence of a catalyst and oxygen to produce the ketone. In one exemplary embodiment, the catalyst comprises a microporous copper chloropyrophosphate framework including a plurality of noble metal nanoparticles. In one exemplary embodiment, the noble metal nanoparticles include at least one metal selected from the group consisting of platinum, palladium, and gold.

公开(公告)号：US20160279622A9

公开(公告)日：2016-09-29

申请号：US14263156

申请日：2014-04-28

申请人： Honeywell International Inc. ,  University of Southampton

发明人： Alan B. Levy ,  Robert Raja ,  Matthew E. Potter

IPC分类号： B01J29/85

CPC分类号： B01J29/85 ,  B01J35/002 ,  C01B37/08 ,  C01B39/54 ,  C07D201/04 ,  C07D223/10 ,  C07D225/02 ,  Y02P20/52

摘要： Methods for producing lactams from oximes by performing a Beckmann rearrangement using a silicoaluminophosphate catalyst are provided. These catalysts may be used in gas phase or liquid phase reactions to convert oximes into lactams. High conversion of oxime and high selectivity for the desired lactams are produced using the disclosed methods, including high conversion and selectivity for ε-caprolactam produced from cyclohexanone oxime and high conversion and selectivity for ω-laurolactam produced from cyclododecanone oxime.

摘要翻译： 提供了通过使用硅铝磷酸盐催化剂进行贝克曼重排来从肟产生内酰胺的方法。 这些催化剂可用于气相或液相反应以将肟转化成内酰胺。 使用所公开的方法制备肟的高转化率和对选择性内酰胺的高选择性，包​​括由环己酮肟产生的ε-己内酰胺的高转化率和选择性以及由环十二酮肟产生的ω-月桂内酰胺的高转化率和选择性。