- 专利标题: Support for fischer-tropsch catalyst having improved activity
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申请号: US14961998申请日: 2015-12-08
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公开(公告)号: US09687826B2公开(公告)日: 2017-06-27
- 发明人: Kandaswamy Jothimurugesan , Howard Steven Lacheen
- 申请人: Chevron U.S.A. Inc.
- 申请人地址: US CA San Ramon
- 专利权人: Chevron U.S.A. Inc.
- 当前专利权人: Chevron U.S.A. Inc.
- 当前专利权人地址: US CA San Ramon
- 代理商 Susan M. Abernathy
- 主分类号: B01J27/198
- IPC分类号: B01J27/198 ; B01J35/02 ; B01J37/02 ; B01J37/08 ; B01J37/18 ; C10G2/00
摘要:
Provided is a Fischer Tropsch catalyst prepared according to a process comprising: a. preparing a catalyst precursor by: i. impregnating an alumina catalyst support material with a first solution comprising ammonium metavanadate and phosphoric acid, to obtain a treated catalyst support material; ii. calcining the treated catalyst support material at a temperature of at least 500° C. to obtain a modified catalyst support having a modified support surface area and a pore volume of at least 0.4 cc/g; wherein the modified catalyst support loses no more than 8% of the pore volume when exposed to a water vapor; and iii. contacting the modified catalyst support with a second solution comprising a precursor compound of an active cobalt catalyst component and glutaric acid to obtain the catalyst precursor; and b. reducing the catalyst precursor to activate the catalyst precursor to obtain the Fischer Tropsch catalyst.
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