Invention Grant
- Patent Title: Double-component modified molecular sieve with improved hydrothermal stability and production method thereof
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Application No.: US13505219Application Date: 2009-12-01
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Publication No.: US09895686B2Publication Date: 2018-02-20
- Inventor: Xionghou Gao , Dong Ji , Haitao Zhang , Hongchang Duan , Di Li , ZhengGuo Tan , Yi Su , Zhicheng Tang , Yi Wang , Yanqing Ma , Yanbo Sun
- Applicant: Xionghou Gao , Dong Ji , Haitao Zhang , Hongchang Duan , Di Li , ZhengGuo Tan , Yi Su , Zhicheng Tang , Yi Wang , Yanqing Ma , Yanbo Sun
- Applicant Address: CN Beijing Dongcheng District
- Assignee: PetroChina Company Limited
- Current Assignee: PetroChina Company Limited
- Current Assignee Address: CN Beijing Dongcheng District
- Agency: Schwegman Lundberg & Woessner, P.A.
- Priority: CN200910237007 20091030
- International Application: PCT/CN2009/001353 WO 20091201
- International Announcement: WO2011/050505 WO 20110505
- Main IPC: B01J29/06
- IPC: B01J29/06 ; B01J37/28 ; B01J29/04 ; B01J29/12 ; B01J29/068 ; B01J29/44 ; B01J29/74 ; C01B39/02 ; C07C4/06 ; C10G11/18 ; B01J37/02 ; B01J37/08

Abstract:
A method for producing double-component modified molecular sieve comprises adding molecular sieve to an aqueous solution containing phosphorus to form a mixture, allowing the mixture to react at pH of 1-10, temperature of 70-200° C. and pressure of 0.2-1.2 MPa for 10-200 min, and then filtering, drying and baking the resultant to obtain phosphorus-modified molecular sieve, and then adding the phosphorus-modified molecular sieve to an aqueous solution containing silver ions, allowing the phosphorus-modified molecular sieve to react with silver ions at 0-100° C. in dark condition for 30-150 min, and then filtering, drying and baking. The obtained double-component modified molecular sieve contains 88-99 wt % molecular sieve with a ratio of silica to alumina between 15 and 60, 0.5-10 wt % phosphorus (based on oxides) and 0.01-2 wt % silver (based on oxides), all based on dry matter. A catalyst produced from the double-component modified molecular sieve has improved hydrothermal stability and microactivity.
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