公开(公告)号：EP3124228B1

公开(公告)日：2018-12-26

申请号：EP15768508.2

申请日：2015-03-26

申请人： LINTEC Corporation ,  National Institute of Advanced Industrial Science and Technology

发明人： HIRONAGA, Maki ,  ONO, Yoshitomo ,  SUGINO, Takashi ,  MIYATA, Sou ,  ITO, Kazumi ,  HOZUMI, Atsushi ,  URATA, Chihiro

IPC分类号： C08J7/04 ,  C09D183/04 ,  C09D5/16

CPC分类号： C09D5/1675 ,  C08J7/042 ,  C08J2383/04 ,  C08J2383/16 ,  C09D5/1693 ,  C09D183/04 ,  C09D183/16

摘要： Provided is an antifouling sheet having an interlayer (X) containing a (poly)silazane compound and having an antifouling layer (Y) layered on the surface of the interlayer (X), wherein the layer (Y) is formed of an antifouling layer-forming composition containing a specific tetrafunctional silane compound (A) and a specific trifunctional silane compound (B), the content of the component (B) in the antifouling layer-forming composition is 8 to 90 mol% relative to 100 mol% of the component (A). The antifouling sheet is provided with an antifouling layer having good surface state and curability, has a large slip acceleration for water droplets, thereby having excellent water repellency that makes water droplets slip off instantly, and has excellent interlayer adhesiveness.

公开(公告)号：EP3124228A1

公开(公告)日：2017-02-01

申请号：EP15768508.2

申请日：2015-03-26

申请人： LINTEC Corporation ,  National Institute of Advanced Industrial Science and Technology

发明人： HIRONAGA, Maki ,  ONO, Yoshitomo ,  SUGINO, Takashi ,  MIYATA, Sou ,  ITO, Kazumi ,  HOZUMI, Atsushi ,  URATA, Chihiro

IPC分类号： B32B9/00 ,  B32B27/00 ,  C09D5/16 ,  C09D183/02 ,  C09K3/00 ,  C09K3/18

CPC分类号： C09D5/1675 ,  C08J7/042 ,  C08J2383/04 ,  C08J2383/16 ,  C09D5/1693 ,  C09D183/04 ,  C09D183/16

摘要： Provided is an antifouling sheet having an interlayer (X) containing a (poly)silazane compound and having an antifouling layer (Y) layered on the surface of the interlayer (X), wherein the layer (Y) is formed of an antifouling layer-forming composition containing a specific tetrafunctional silane compound (A) and a specific trifunctional silane compound (B), the content of the component (B) in the antifouling layer-forming composition is 8 to 90 mol% relative to 100 mol% of the component (A). The antifouling sheet is provided with an antifouling layer having good surface state and curability, has a large slip acceleration for water droplets, thereby having excellent water repellency that makes water droplets slip off instantly, and has excellent interlayer adhesiveness.

摘要翻译： 本发明提供一种具有含有（聚）硅氮烷化合物的中间层（X）和在中间层（X）的表面上层叠有防污层（Y））的防污层，其中，层（Y）由防污层形成， 含有特定的四官能性硅烷化合物（A）和特定的三官能硅烷化合物（B）的成膜组合物中，防污层形成用组合物中的成分（B）的含量相对于成分的100摩尔％为8〜90摩尔％ （一个）。 防污片具有良好的表面状态和固化性的防污层，水滴的滑移加速度大，具有优异的防水性，使水滴立即脱落，并具有良好的层间粘合性。

公开(公告)号：EP3246371B1

公开(公告)日：2020-03-25

申请号：EP16737329.9

申请日：2016-01-12

申请人： Lintec Corporation

发明人： HIRONAGA, Maki ,  MIYATA, Sou ,  ONO, Yoshitomo ,  NANASHIMA, Yutaka ,  SUGINO, Takashi

IPC分类号： C09D183/04 ,  C09D5/16 ,  B32B27/00 ,  C09K3/18

公开(公告)号：EP3124234B1

公开(公告)日：2018-12-05

申请号：EP15770186.3

申请日：2015-03-26

申请人： LINTEC Corporation

发明人： HIRONAGA, Maki ,  ONO, Yoshitomo ,  SUGINO, Takashi

IPC分类号： B05D3/00 ,  B05D3/04 ,  C09D183/04 ,  B05D5/08

CPC分类号： C09D5/1675 ,  B05D3/046 ,  B05D3/108 ,  B05D5/00 ,  B05D5/08 ,  B05D7/52 ,  C09D5/16 ,  C09D5/1693 ,  C09D183/04

摘要： Provided is an antifouling sheet having an antifouling layer formed of an antifouling layer-forming composition containing a specific tetrafunctional silane compound (A) and a specific trifunctional silane compound (B) wherein the content of the component (B) is 8 to 90 mol% relative to 100 mol% of the component (A), and the antifouling layer is a layer formed by drying and curing a coating film formed of the antifouling layer-forming composition, in an ammonia atmosphere. Also provided is a method for producing the antifouling sheet. The antifouling sheet is provided with an antifouling layer having good surface state and curability, has a large slip acceleration for water droppings, thereby having excellent water repellency that makes water droplets slip off instantly, and has excellent interlayer adhesiveness.

公开(公告)号：EP3124234A1

公开(公告)日：2017-02-01

申请号：EP15770186.3

申请日：2015-03-26

申请人： LINTEC Corporation

发明人： HIRONAGA, Maki ,  ONO, Yoshitomo ,  SUGINO, Takashi

IPC分类号： B32B27/00 ,  B05D3/04 ,  B05D7/24 ,  C09D5/16 ,  C09D183/02 ,  C09K3/00 ,  C09K3/18

CPC分类号： C09D5/1675 ,  B05D3/046 ,  B05D3/108 ,  B05D5/00 ,  B05D5/08 ,  B05D7/52 ,  C09D5/16 ,  C09D5/1693 ,  C09D183/04

摘要： Provided is an antifouling sheet having an antifouling layer formed of an antifouling layer-forming composition containing a specific tetrafunctional silane compound (A) and a specific trifunctional silane compound (B) wherein the content of the component (B) is 8 to 90 mol% relative to 100 mol% of the component (A), and the antifouling layer is a layer formed by drying and curing a coating film formed of the antifouling layer-forming composition, in an ammonia atmosphere. Also provided is a method for producing the antifouling sheet. The antifouling sheet is provided with an antifouling layer having good surface state and curability, has a large slip acceleration for water droppings, thereby having excellent water repellency that makes water droplets slip off instantly, and has excellent interlayer adhesiveness.

摘要翻译： 本发明提供一种防污层，其由含有特定四官能性硅烷化合物（A）和特定三官能硅烷化合物（B）的防污层形成组合物形成的防污层，其中组分（B）的含量为8〜90摩尔％ 相对于成分（A）的100摩尔％，防污层是通过在氨气氛中干燥并固化由防污层形成用组合物形成的涂膜而形成的层。 还提供了一种生产防污纸的方法。 防污片具有表面状态和固化性好的防污层，水滴的滑动加速性大，具有优异的防水性，使水滴立即脱落，并且具有优异的层间粘合性。

公开(公告)号：EP3252120B1

公开(公告)日：2019-08-21

申请号：EP16743148.5

申请日：2016-01-18

申请人： LINTEC Corporation

发明人： HIRONAGA, Maki ,  AMINO, Yumiko ,  MIYATA, Sou ,  ONO, Yoshitomo

IPC分类号： C09D183/14 ,  B32B27/00 ,  C09D5/16 ,  C09K3/18 ,  C09D183/16

公开(公告)号：EP3290487A1

公开(公告)日：2018-03-07

申请号：EP16786485.9

申请日：2016-04-26

申请人： Lintec Corporation

发明人： HIRONAGA, Maki ,  MIYATA, Sou ,  ONO, Yoshitomo

IPC分类号： C09D183/00 ,  B01J27/10 ,  B01J31/22 ,  B01J37/04 ,  B32B9/00 ,  C03C17/30 ,  C03C17/32 ,  C09D7/12 ,  C09K3/18

CPC分类号： C09D183/04 ,  B01J27/10 ,  B01J31/22 ,  B01J37/04 ,  B05D3/0254 ,  B32B9/00 ,  C03C17/30 ,  C03C17/32 ,  C09D7/40 ,  C09D183/00 ,  C09K3/18

摘要： Provided are an antifouling composition including a tetrafunctional silane-based compound (A) having a specified structure, a trifunctional silane-based compound (B) having a specified structure, and a metal catalyst (C) containing one or more metal atoms selected from titanium, aluminum, and zinc, which does not require light irradiation for revealing a catalytic action; an antifouling sheet including an antifouling layer formed of the antifouling composition; and a method for producing the same.

摘要翻译： 本发明提供一种防污组合物，其含有具有特定结构的四官能硅烷系化合物（A），具有特定结构的三官能硅烷系化合物（B）和含有选自钛的1种以上金属原子的金属催化剂（C） ，铝和锌，其不需要光照射以显示催化作用; 包含由防污组合物形成的防污层的防污片; 及其制造方法。

公开(公告)号：EP3594310A1

公开(公告)日：2020-01-15

申请号：EP18764788.8

申请日：2018-03-05

申请人： LINTEC Corporation

发明人： HIRONAGA, Maki ,  MIYATA, Sou

IPC分类号： C09K3/18 ,  B32B27/00 ,  C09D183/06 ,  C09J7/20 ,  C09J201/00

摘要： The present invention relates to a liquid-repellent composition containing a tetrafunctional silane-based compound having a specified structure [component (A)] and a trifunctional silane-based compound having a specified structure [component (B)] as well as a metal catalyst [component (C)] and satisfying a formula (I): 12 ≤ x ≤ 64 [in the formula (I), x represents a ratio of a molar amount of the component (A) to a molar amount of the component (B) [(A)/(B)] (molar ratio), a liquid-repellent sheet including a liquid-repellent layer formed of the foregoing liquid-repellent composition, and production methods of the same.

公开(公告)号：EP3323865A1

公开(公告)日：2018-05-23

申请号：EP16824497.8

申请日：2016-07-13

申请人： Lintec Corporation

发明人： HIRONAGA, Maki ,  MIYATA, Sou ,  ONO, Yoshitomo

IPC分类号： C09D183/00 ,  B32B27/00 ,  C09D5/16 ,  C09D7/12 ,  C09K3/18

摘要： Provided are an antifouling composition including a tetrafunctional silane-based compound having a specified structure as a component (A), trifunctional silane-based compounds having a specified structure different from each other as a component (B) and component (C), and a metal catalyst as a component (D), the antifouling composition satisfying:
Condition (I): a ratio of a molar amount of the component (A) to a molar amount of the component (B) [(A)/(B)] (molar ratio) is 1.4 or more, and
Condition (II): a ratio of a molar amount of the component (B) to a total molar amount of the component (B) and the component (C) [(B)/{(B) + (C)}] (molar ratio) is 0.020 or more,
an antifouling sheet including an antifouling layer formed of the antifouling composition, and a method for producing the same.

公开(公告)号：EP3252120A1

公开(公告)日：2017-12-06

申请号：EP16743148.5

申请日：2016-01-18

申请人： LINTEC Corporation

发明人： HIRONAGA, Maki ,  AMINO, Yumiko ,  MIYATA, Sou ,  ONO, Yoshitomo

IPC分类号： C09D183/14 ,  B32B27/00 ,  C09D5/16 ,  C09K3/18

CPC分类号： C09D183/14 ,  B32B27/00 ,  B32B27/283 ,  B32B2307/73 ,  C08G77/14 ,  C08G77/62 ,  C09D5/16 ,  C09D5/1675 ,  C09D183/04 ,  C09D183/16 ,  C09K3/18 ,  C08L83/00

摘要： Provided is an antifouling composition including a polysilazane-based compound (A) and a both terminal carboxy-modified silicone (B), the content of the component (B) being from 0.01 to 10 parts by mass based on 100 parts by mass of the total amount of the component (A), and the antifouling composition serves as a sheet-like antifouling layer-forming material. The antifouling composition is able to form a sheet-like antifouling layer having favorable surface state and curability and also having excellent water repellency such that even when a tilt angle is small, water droplets can be slipped off.

摘要翻译： 本发明提供一种防污组合物，其含有聚硅氮烷系化合物（A）和两末端羧基改性聚硅氧烷（B），成分（B）的含量相对于100质量份 组分（A）的总量和防污组合物用作片状防污层形成材料。 该防污组合物能够形成具有良好的表面状态和固化性并且还具有优异的防水性的片状防污层，使得即使当倾斜角度小时，也能够将水滴滑落。