公开(公告)号：EP2412694A1

公开(公告)日：2012-02-01

申请号：EP10755703.5

申请日：2010-03-26

申请人： Mitsui Chemicals, Inc. ,  Agency for Science, Technology and Research

发明人： WADAMOTO, Manabu ,  YOSHINAGA, Kazuhiko ,  NAGATA, Takushi ,  ABDUL MAJEED, Seayad ,  BALAMURUGAN, Ramalingam ,  CHRISTINA L.L., Chai

IPC分类号： C07C29/40 ,  C07C33/24 ,  C07C33/34 ,  C07C33/46 ,  C07B61/00

CPC分类号： C07B53/00 ,  C07B2200/07 ,  C07C29/40 ,  C07C41/30 ,  C07C2601/14 ,  C07D213/30 ,  C07D307/42 ,  C07C33/46 ,  C07C33/18 ,  C07C33/24 ,  C07C43/23 ,  C07C33/28 ,  C07C33/34 ,  C07C33/20

摘要： Disclosed is a method for producing an optically active alcohol including reacting a titanium compound, an aromatic magnesium compound and a carbonyl compound in the presence of an optically active biphenol compound having a predetermined structure and an ether compound having a predetermined structure.

摘要翻译： 公开了一种光学活性醇的制备方法，其包括在具有预定结构的光学活性联苯酚化合物和具有预定结构的醚化合物存在下使钛化合物，芳族镁化合物和羰基化合物反应。

公开(公告)号：EP2396289A1

公开(公告)日：2011-12-21

申请号：EP10705933.9

申请日：2010-02-11

申请人： Agency for Science, Technology and Research ,  Mitsui Chemicals, Inc.

发明人： SEAYAD, Abdul Majeed ,  RAMALINGAM, Balamurugan ,  CHAI, Christina ,  NAGATA, Takushi ,  YOSHINAGA, Kazuhiko ,  WADAMOTO, Manabu

IPC分类号： C07B43/08 ,  B01J31/18 ,  B01J31/22

CPC分类号： B01J31/1805 ,  B01J31/2265 ,  B01J2231/341 ,  B01J2531/46 ,  C07B43/08

摘要： The present invention relates to titanium catalysts for synthesis reactions produced by bringing a reaction mixture comprising a titanium alkoxide and a ligand in contact with water, wherein the ligand is represented by the general formula (e): wherein R
1 , R
2 , R
3 , and R
4 are independently a hydrogen atom, an alkyl group, or the like, and (A) represents a group with two or more carbon atoms. The titanium catalysts may be isolated in solid form and may be stored. The invention further relates to a process for cyanation of imines, wherein the process comprises reacting an imine with a cyanating agent in the presence of the titanium catalyst.

公开(公告)号：EP1816146B1

公开(公告)日：2011-04-06

申请号：EP05806700.0

申请日：2005-11-16

申请人： Mitsui Chemicals, Inc.

发明人： MATSUMOTO, Tetsuhiro ,  TSUTSUI, Toshiyuki ,  RO, Kisu ,  KUROIWA, Kourei ,  NAGATA, Takushi ,  SHIBAHARA, Atsushi ,  NAKAMURA, Tatsuya ,  TANAKA, Tooru ,  SHINOZAKI, Tetsunori

IPC分类号： C08F4/654 ,  C08F210/14 ,  C08J5/18

CPC分类号： C08F10/00 ,  C08F210/14 ,  C08F2500/26 ,  C08J5/18 ,  C08J2323/20 ,  C08F4/651 ,  C08F2500/15

摘要： This invention relates to a process for producing an α-olefin polymer that has high catalytic activity and can particularly realize a deliming-free process even in polymerization of a higher olefin. The production process comprises polymerizing or copolymerizing an α-olefin having 3 or more carbon atoms in the presence of a catalyst for olefin polymerization comprising a solid titanium catalyst component (I) comprising a titanium element, a magnesium element, and a halogen element and a compound containing two or more ether bonds having a specific structure, and an organometal compound catalyst component (II). A 4-methyl-1-pentene polymer produced by polymerization in the presence of the catalyst according to the present invention has excellent stereoregularity, transparency, heat resistance, and releasability and is particularly suitable as a release film.

公开(公告)号：EP2190851A1

公开(公告)日：2010-06-02

申请号：EP08834037.7

申请日：2008-09-26

申请人： Agency for Science, Technology and Research ,  Mitsui Chemicals, Inc.

发明人： SEAYAD, Abdul Majeed ,  RAMALINGAM, Balamurugan ,  CHAI, Christina ,  NAGATA, Takushi ,  YOSHINAGA, Kazuhiko

IPC分类号： C07F7/28

CPC分类号： C07C253/30 ,  C07B41/02 ,  C07B43/08 ,  C07B53/00 ,  C07C255/19

摘要： The present invention relates to titanium catalysts for asymmetric synthesis reactions produced by bringing a reaction mixture obtained by contacting water and a titanium alkoxide into contact with an optically active ligand represented by the general formula (a), wherein R1, R2, R3, and R4 are independently a hydrogen atom, an alkyl group, or the like, and A* represents a group with two or more carbon atoms having an asymmetric carbon atom or axial asymmetry. The invention further relates to a process for asymmetric cyanation of imines, wherein the process comprises reacting an imine with a cyanating agent in the presence of the titanium catalyst.

公开(公告)号：EP2137197A1

公开(公告)日：2009-12-30

申请号：EP07808949.7

申请日：2007-09-28

申请人： Agency for Science, Technology And Research ,  Mitsui Chemicals, Inc.

发明人： SEAYAD, Abdul, Majeed ,  CHAI, Christina ,  RAMALINGAM, Balamurugan ,  NAGATA, Takushi ,  YOSHINAGA, Kazuhiko

IPC分类号： C07F7/00

CPC分类号： C07C253/30 ,  C07B41/02 ,  C07B43/08 ,  C07B53/00 ,  C07C255/19

摘要： The present invention relates to titanium catalysts for asymmetric synthesis reactions produced by bringing a reaction mixture obtained by contacting water and a titanium alkoxide into contact with an optically active ligand represented by the general formula (a), wherein R1, R2, R3, and R4 are independently a hydrogen atom, an alkyl group, or the like, and A* represents a group with two or more carbon atoms having an asymmetric carbon atom or axial asymmetry. The invention further relates to a process for asymmetric cyanation of imines, wherein the process comprises reacting an imine with a cyanating agent in the presence of the titanium catalyst.

公开(公告)号：EP2132155A1

公开(公告)日：2009-12-16

申请号：EP07716169.3

申请日：2007-03-29

申请人： Agency for Science, Technology and Research ,  Mitsui Chemicals, Inc.

发明人： YEO, Wee Chuan ,  CHAI, L. L. Christina ,  SELVARATNAM, Selvasothi ,  NAGATA, Takushi ,  YOSHINAGA, Kazuhiko

IPC分类号： C07B53/00 ,  C07B43/08 ,  C07B41/02 ,  C07C253/00

CPC分类号： C07C253/30 ,  C07B41/02 ,  C07B43/08 ,  C07B53/00 ,  C07C255/19

摘要： The present invention relates to a method of producing an optically active cyanohydrin derivative, which comprises reacting an aldehyde or an asymmetrical ketone with a cyanating agent in the presence of a Lewis base and a titanium compound produced from a partial hydrolysate of titanium tetraalkoxide and an optically active ligand represented by formula (II) or a titanium oxoalkoxide compound represented by formula (I) [TixOy](OR1)4x-2y, and an optically active ligand represented by formula (II), wherein R1 is an optionally substituted alkyl group or an optionally substituted aryl group; x is an integer of not less than 2; y is an integer of not less than 1; and y/x satisfies 0.1

公开(公告)号：EP1816146A1

公开(公告)日：2007-08-08

申请号：EP05806700.0

申请日：2005-11-16

申请人： Mitsui Chemicals, Inc.

发明人： MATSUMOTO, Tetsuhiro ,  TSUTSUI, Toshiyuki ,  RO, Kisu ,  KUROIWA, Kourei ,  NAGATA, Takushi ,  SHIBAHARA, Atsushi ,  NAKAMURA, Tatsuya ,  TANAKA, Tooru ,  SHINOZAKI, Tetsunori

IPC分类号： C08F4/654 ,  C08F210/14 ,  C08J5/18

CPC分类号： C08F10/00 ,  C08F210/14 ,  C08F2500/26 ,  C08J5/18 ,  C08J2323/20 ,  C08F4/651 ,  C08F2500/15

摘要： The present invention provides a process for producing an α-olefin polymer comprising polymerizing or copolymerizing (a) C 3 or higher α-olefin(s) in the presence of an olefin polymerization catalyst comprising solid titanium catalyst component (I) containing titanium, magnesium, halogen, and a compound with a specific structure having two or more ether linkages and organometallic catalyst component (II) with high catalytic activity. In this process, particularly even in (co)polymerizing (a) higher olefin(s), demineralization is unnecessary. A 4-methyl-1-pentene-based polymer obtained by polymerization using the catalyst of the present invention is excellent in tacticity, transparency, heat resistance, and releasability, and the polymer is particularly suitable for a release film.

摘要翻译： 本发明提供了一种生产在±烯烃聚合物，其包含聚合或共聚的（a）的C 3或更高±在烯烃聚合催化剂，它包括含钛的固体钛催化剂成分（I）的存在下烯烃（S），镁 ，卤素和具有两个或多个醚键和具有高催化活性有机金属催化剂组分（II）的特定结构的化合物。 在这个过程中，特别是即使是在（共）的（a）更高的聚合烯烃，脱矿质是不必要的。 通过使用本发明的催化剂聚合获得的基于4-甲基-1-戊烯类聚合物具有优异的立构规整度，透明性，耐热性，和脱模性，并且该聚合物是特别适合于释放的电影。