摘要:
An object of the present invention is to provide, at a low cost, a porous metal body that can be used in an electrode of a fuel cell and that has better corrosion resistance. The porous metal body has a three-dimensional mesh-like structure and contains nickel (Ni), tin (Sn), and chromium (Cr). A content ratio of the tin is 10% by mass or more and 25% by mass or less, and a content ratio of the chromium is 1% by mass or more and 10% by mass or less. On a cross section of a skeleton of the porous metal body, the porous metal body contains a solid solution phase of chromium, nickel, and tin. The solid solution phase contains a solid solution phase of chromium and trinickel tin (Ni 3 Sn), the solid solution phase having a chromium content ratio of 2% by mass or less, and does not contain a solid solution phase that is other than a solid solution phase of chromium and trinickel tin (Ni 3 Sn) and that has a chromium content ratio of less than 1.5% by mass.
摘要:
Provided is a porous metal body having higher corrosion resistance than existing porous metal bodies composed of nickel-tin binary alloys and existing porous metal bodies composed of nickel-chromium binary alloys. The porous metal body contains at least nickel, tin, and chromium. An example of a method of producing such a porous metal body is a method including a conductive-coating-layer formation step of forming a conductive coating layer containing chromium on a surface of a porous base formed of a resin material; a metal-layer formation step of forming a nickel layer and a tin layer in any order on a surface of the conductive coating layer; a removal step of removing the porous base; and a diffusion step of, by a heat treatment, causing interdiffusion of metal atoms between the nickel layer and the tin layer and diffusing chromium contained in the conductive coating layer into the nickel layer and the tin layer.
摘要:
A capacitor has a positive electrode 10, a negative electrode 20, and a solid electrolyte layer arranged between the electrode layers 10 and 20. At least one 10 (20) of the electrode layers of this capacitor 100 has an Al porous body 11, and an electrode body 12 (13) held in this Al porous body 11 to polarize the electrolyte. The oxygen content in the surface of the Al porous body 11 is 3.1% by mass or less. The matter that the oxygen content in the surface of the Al porous body 11 is 3.1% by mass or less is equal to the matter that a high-resistance oxide film is hardly formed on the surface of the Al porous body 11. Thus, this Al porous body 11 makes it possible to make the current collector area of the electrode layer 10 (20) large so that the capacitor 100 can be improved in capacity.
摘要:
Provided is a porous current collector which is used for a fuel electrode and has a high gas reforming function and high durability. A porous current collector 9 is provided adjacent to a fuel electrode 4 of a fuel cell 101 that includes a solid electrolyte layer 2, the fuel electrode 4 disposed on one side of the solid electrolyte layer, and an air electrode 3 disposed on the other side. The porous current collector includes a porous metal body 1 and a first catalyst 20. The porous metal body has an alloy layer 12a at least on a surface thereof, the alloy layer containing nickel (Ni) and tin (Sn). The first catalyst, which is in the form of particles, is supported on a surface of the alloy layer, the surface facing pores of the porous metal body, and is capable of processing a carbon component contained in a fuel gas that flows inside the pores.
摘要:
An inexpensive porous current collector having high durability is provided by forming a silver layer having high strength on a current collector formed from a nickel porous base material. Porous current collectors 8a and 9a are used in a fuel cell 101 including a solid electrolyte layer 2, a first electrode layer 3 on one side of the solid electrolyte layer, and a second electrode layer 4 on the other side. The porous current collectors each include: an alloy layer 60a, which is formed from a tin (Sn)-containing alloy, at least on the surfaces of continuous pores 52 of a nickel porous base material 60 having the continuous pores 52; and a silver layer 55 stacked on the alloy layer.