摘要:
The invention provides a hollow fiber membrane exhibits favorable gas permeation performance and excellent heat resistance and in which the generation of pinholes are suppressed, and a hollow fiber membrane module using the same. The hollow fiber membrane having a gas permeable nonporous layer; and a porous supporting layer to support the nonporous layer formed of a thermoplastic elastomer having a DSC melting peak temperature of 130°C or higher and a rupture elongation prescribed in ISO 37 (2010) of 300% or more. The nonporous layer is formed of a composition containing a styrene-based thermoplastic elastomer (I) containing at least either of an ABA type styrene-based thermoplastic elastomer (α) having a polystyrene portion (A) and a poly-conjugated diene portion (B) or a hydrogenated product (αh) of the ABA type styrene-based thermoplastic elastomer (α) and a polyolefin (II), wherein the poly-conjugated diene portion (B) contains at least either of a 1,2-bonding unit or a 3,4-bonding unit, wherein a total amount of the 1,2-bonding unit and the 3,4-bonding unit is 50% by mole or more with respect to a total amount of the entire units constituting the poly-conjugated diene portion (B).
摘要:
The present invention relates to a polyolefin microporous membrane having an air permeability normalized to a thickness of 16 µm of from 100 to 220 sec/100 cc, a pin puncture strength normalized to a thickness of 16 µm of not less than 550 gf, and a crystallization half time t 1/2 of from 10 to 35 minutes when subjected to isothermal crystallization at 117°C; a separator for a battery using the same; and a production method thereof. The polyolefin microporous membrane of the present invention has excellent pin puncture strength and air permeability, suppresses curling, and has an excellent appearance without wrinkles or winding deviation when formed into a roll.
摘要:
To provide a polyolefin multilayer microporous membrane and a battery separator having excellent mechanical strength and heat resistance. The present invention is a polyolefin multilayer microporous membrane having at least three layers, the membrane comprising a first microporous layer composed of a polyethylene resin containing an ultrahigh molecular weight polyethylene (surface layers) and a second microporous layer composed of a polyolefin rein containing a high-density polyethylene and polypropylene (intermediate layer), wherein (I) the pin puncture strength is at least 25 g/µm, (II) the coefficient of static friction with respect to a metal foil is at least 0.40, and (III) the meltdown temperature is at least 180°C.
摘要:
The present invention relates to a membrane distillation system comprising a flat-sheet composite mixed matrix hydrophilic/hydrophobic membrane having at least a hydrophilic layer and a hydrophobic layer. The hydrophilic layer comprises a hydrophilic polymer and inorganic nanoparticles having high thermal conductivity. The hydrophobic layer comprises fluorinated surface-modifying macromolecules (SMM). Also disclosed is a phase inversion method for manufacturing the membrane.
摘要:
To provide a polyolefin multilayer microporous membrane and a battery separator having excellent mechanical strength and heat resistance. The present invention is a polyolefin multilayer microporous membrane having at least three layers, the membrane comprising a first microporous layer composed of a polyethylene resin containing an ultrahigh molecular weight polyethylene (surface layers) and a second microporous layer composed of a polyolefin rein containing a high-density polyethylene and polypropylene (intermediate layer), wherein (I) the pin puncture strength is at least 25 g/µm, (II) the coefficient of static friction with respect to a metal foil is at least 0.40, and (III) the meltdown temperature is at least 180°C.
摘要:
The invention offers a microporous modified-polytetrafluoroethylene membrane that is a microporous membrane having a significantly small pore diameter and narrow pore-diameter distribution and that can remove microscopic foreign particles at high efficiency when used as a filtration membrane. A microporous modified-polytetrafluoroethylene membrane that is a microporous membrane produced by the steps of producing a copolymer of hexafluoropropylene or perfluoroalkyl ether and tetrafluoroethylene having the number of moles not less than 50 times that of the hexafluoropropylene or perfluoroalkyl ether, forming the copolymer into the shape of a membrane, heating the membrane to the melting point of the copolymer or above to bake the copolymer, cooling the obtained baked product, and stretching the baked product and that has a mean flow pore diameter of 30 nm or less; a porous-modified-polytetrafluoroethylene-membrane composite that incorporates the microporous membrane and a production process of the composite; and a separation membrane element incorporating the porous-modified-polytetrafluoroethylene-membrane composite.