HOLLOW FIBER MEMBRANE AND HOLLOW FIBER MEMBRANE MODULE
    92.
    发明公开
    HOLLOW FIBER MEMBRANE AND HOLLOW FIBER MEMBRANE MODULE 审中-公开
    中空纤维膜和空心纤维膜组件

    公开(公告)号:EP3187249A1

    公开(公告)日:2017-07-05

    申请号:EP15836260.8

    申请日:2015-08-21

    摘要: The invention provides a hollow fiber membrane exhibits favorable gas permeation performance and excellent heat resistance and in which the generation of pinholes are suppressed, and a hollow fiber membrane module using the same. The hollow fiber membrane having a gas permeable nonporous layer; and a porous supporting layer to support the nonporous layer formed of a thermoplastic elastomer having a DSC melting peak temperature of 130°C or higher and a rupture elongation prescribed in ISO 37 (2010) of 300% or more. The nonporous layer is formed of a composition containing a styrene-based thermoplastic elastomer (I) containing at least either of an ABA type styrene-based thermoplastic elastomer (α) having a polystyrene portion (A) and a poly-conjugated diene portion (B) or a hydrogenated product (αh) of the ABA type styrene-based thermoplastic elastomer (α) and a polyolefin (II), wherein the poly-conjugated diene portion (B) contains at least either of a 1,2-bonding unit or a 3,4-bonding unit, wherein a total amount of the 1,2-bonding unit and the 3,4-bonding unit is 50% by mole or more with respect to a total amount of the entire units constituting the poly-conjugated diene portion (B).

    摘要翻译: 本发明提供一种中空纤维膜和具有该中空纤维膜膜的中空纤维膜组件,该中空纤维膜呈现良好的气体渗透性能和优异的耐热性,并且其中抑制了针孔的产生。 该中空纤维膜具有气体可渗透的无孔层; 以及多孔性支撑层,用于支撑由DSC熔融峰值温度为130℃以上且ISO37(2010)中规定的断裂伸长率为300%以上的热塑性弹性体形成的无孔层。 无孔层由含有苯乙烯系热塑性弹性体(I)的组合物形成,所述苯乙烯系热塑性弹性体(I)含有具有聚苯乙烯部分(A)和聚共轭二烯部分(B)的ABA型苯乙烯系热塑性弹性体(α) )或ABA型苯乙烯类热塑性弹性体(α)和聚烯烃(II)的氢化物(αh),其中,聚共轭二烯部分(B)含有1,2-键合单元或 3,4-键合单元,其中1,2-键合单元和3,4-键合单元的总量相对于构成聚共轭物的全部单元的总量为50摩尔%以上 二烯部分(B)。