Transesterification of triglycerides
    93.
    发明公开
    Transesterification of triglycerides 失效
    Verfahren zur Transveresterung von Tryglyceriden。

    公开(公告)号:EP0428249A1

    公开(公告)日:1991-05-22

    申请号:EP90309136.1

    申请日:1990-08-21

    Abstract: A process for converting liquid triglycerides into solid triglycerides by means of random transesterification achieved through the use of catalytically active combinations comprising the reaction product of mixtures of dihydroxy and trihydroxy alcohols with mixtures of alkali metal hydroxides, and with ketones. The catalytically active materials can be employed in directed transesterifications in which the transesterification reaction mixture is subjected to a series of heating and cooling cycles during which higher melting fats are formed and precipitated from solution, causing an equilibrium shift that results in the formation and precipitation of still additional higher melting fats. An especially desirable catalytically active combination comprises the reaction product of 1, 2 propanediol, 1, 3 propanediol and glycerol, with sodium hydroxide and potassium hydroxide, and in a preferred embodiment, the reaction product is combined with acetone to form the catalytically active combination.

    Abstract translation: 通过使用包含二羟基和三羟基醇的混合物与碱金属氢氧化物与酮的混合物的反应产物的催化活性组合,通过随机酯交换将液体甘油三酸酯转化为固体甘油三酸酯的方法。 催化活性材料可用于定向酯交换反应,其中酯交换反应混合物经受一系列加热和冷却循环,在此期间,溶液中形成和沉淀出较高熔点的脂肪,引起导致形成和沉淀的平衡变化 还有更高的熔点。 特别理想的催化活性组合包括1,2-丙二醇,1,3-丙二醇和甘油与氢氧化钠和氢氧化钾的反应产物,在优选的实施方案中,将反应产物与丙酮混合以形成催化活性组合。

    Ziegler type catalyst composition
    98.
    发明公开
    Ziegler type catalyst composition 失效
    Katalysatorzusammensetzung des Ziegler-Typs。

    公开(公告)号:EP0016581A1

    公开(公告)日:1980-10-01

    申请号:EP80300670.9

    申请日:1980-03-05

    Abstract: A catalyst system for alphaolefin type polymerizations, includes at least one hindered alkyl metal amide compound having the formula R' 2 YNR 2 in combination with a Group IVA-VIII transition metal compound on a support and at least one Lewis base wherein R is C 3 to C 20 bulky alkyl, cycloalkyl, aralkyl, aryl or substituted aryl groups or R 2 N is a hindered cyclic amide group; R' is C, to C 20 primary alkyl, secondary alkyl, tertiary alkyl, neopentyl alkyl, branched alkyl, cycloalkyl or aralkyl groups, and Y is aluminium, gallium or indium. The catalyst system provides polymers having increased isotactic stereoregularity as well as lower catalyst residue.

    Abstract translation: 用于α-烯烃型聚合的催化剂体系包括至少一种具有式R min 2 YNR2的受阻烷基金属酰胺化合物与载体上的IVA-VIII族过渡金属化合物和至少一种路易斯碱,其中R为C 3至C 20大体积 烷基,环烷基,芳烷基,芳基或取代的芳基或R2N是受阻环酰胺基; R min为C 1至C 20伯烷基,仲烷基,叔烷基,新戊基烷基,支链烷基,环烷基或芳烷基,Y为铝,镓或铟。 催化剂体系提供具有增加的全同立构规整性以及较低催化剂残余物的聚合物。

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