Abstract:
Procédé de récupération de valeurs de catalyseur de rhodium à partir de ''goudrons'' formés pendant la préparation d'anhydride acétique par la carbonylation catalysée au rhodium d'un mélange d'iodure de méthyle, d'acétate de méthyle et/ou d'éther de diméthyle. Le procédé décrit constitue un moyen de récupération des valeurs de rhodium, lesquelles normalement ne sont pas extraites des goudrons par traitement d'une solution d'iodure de méthyle desdits goudrons, à l'aide de certains oxydants.
Abstract:
A process for converting liquid triglycerides into solid triglycerides by means of random transesterification achieved through the use of catalytically active combinations comprising the reaction product of mixtures of dihydroxy and trihydroxy alcohols with mixtures of alkali metal hydroxides, and with ketones. The catalytically active materials can be employed in directed transesterifications in which the transesterification reaction mixture is subjected to a series of heating and cooling cycles during which higher melting fats are formed and precipitated from solution, causing an equilibrium shift that results in the formation and precipitation of still additional higher melting fats. An especially desirable catalytically active combination comprises the reaction product of 1, 2 propanediol, 1, 3 propanediol and glycerol, with sodium hydroxide and potassium hydroxide, and in a preferred embodiment, the reaction product is combined with acetone to form the catalytically active combination.
Abstract:
In the process of recovering molybdenum from a spent catalyst solution obtained from a crude reaction product of a molybdenum catalyzed epoxidation of an olefin with an organic hydroperoxide from which crude reaction product epoxide and an alcohol corresponding to the hydroperoxide is removed, the improvement comprises removing and recovering dissolved molybdenum as a high molybdenum content solid by subjecting the spent catalyst solution to a liquid-to-liquid extraction with an aqueous extract to form a two phase system, separating the molybdenum-rich aqueous extract and precipitating therefrom a high molybdenum content solid by heating the aqueous extract in the presence of hydrogen sulfide or a water soluble sulfide salt.
Abstract:
A catalyst system for alphaolefin type polymerizations, includes at least one hindered alkyl metal amide compound having the formula R' 2 YNR 2 in combination with a Group IVA-VIII transition metal compound on a support and at least one Lewis base wherein R is C 3 to C 20 bulky alkyl, cycloalkyl, aralkyl, aryl or substituted aryl groups or R 2 N is a hindered cyclic amide group; R' is C, to C 20 primary alkyl, secondary alkyl, tertiary alkyl, neopentyl alkyl, branched alkyl, cycloalkyl or aralkyl groups, and Y is aluminium, gallium or indium. The catalyst system provides polymers having increased isotactic stereoregularity as well as lower catalyst residue.
Abstract translation:用于α-烯烃型聚合的催化剂体系包括至少一种具有式R min 2 YNR2的受阻烷基金属酰胺化合物与载体上的IVA-VIII族过渡金属化合物和至少一种路易斯碱,其中R为C 3至C 20大体积 烷基,环烷基,芳烷基,芳基或取代的芳基或R2N是受阻环酰胺基; R min为C 1至C 20伯烷基,仲烷基,叔烷基,新戊基烷基,支链烷基,环烷基或芳烷基,Y为铝,镓或铟。 催化剂体系提供具有增加的全同立构规整性以及较低催化剂残余物的聚合物。
Abstract:
A functionalised solid product containing sulphonate or sulphonic acid groups is prepared from an inorganic oxide containing surface hydroxyl groups, e.g. silica by reacting the latter in a first stage with a haloalkyl alkoxy- or arylox- ysilane. The first stage product is then reacted with an aqueous solution of an inorganic sulphite to give a product containing sulphonate groups. These can be converted to sulphonic acid groups by an optional third stage treatment with dilute mineral acid. The final products are suitable for use as adsorbent materials or catalyst supports.
Abstract:
The present invention provides a novel transesterification catalyst having the general formula: Zn3M2(CN)n(ROH).xZnCl2.yH2O wherein R is tertiary-butyl and M is a transition metal ion selected from Fe, Co and Cr, x varies from 0 to 0.5, y varies from 3-5 and n is 10 or 12. The above said catalyst is useful for an efficient transesterification of glycerides, fatty acid esters and cyclic carbonates on reactions with alcohols.