摘要:
A method for the removal of NOX and N2O from the residual gas in nitric acid production is disclosed. The method comprises passing the residual gases leaving the absorption tower, through a two-stage combination before introduction into the residual gas turbine. In the first stage the NOx content of the gas is reduced and in the second stage the N2O content is reduced. The NOx/N2O ratio, before entry into the second stage, is in the range from 0,001 to 0,5 and said gas is brought into contact with a catalyst in the second stage. Said catalyst comprises essentially one or several iron-loaded zeolites.
摘要:
The invention provides a process for removing NOx which is free of impairment in denitration efficiency at a reaction temperature of up to 300° C even when the component molar ratio of NOx in the gas to be treated is NO 2 > NO. For use in removing NOx from the gas to be treated and containing NO 2 in a larger amount than NO, that is, having a (NO 2 )/NOx ratio in excess of 0.5, by selective reduction with use of ammonia serving as a main reducing agent in the presence of a denitration catalyst, the process of the invention for removing NOx comprises adding to the denitration reaction system a substance for removing an excess of oxygen accumulating on catalyst active sites by selectively reducing the oxygen at not higher than 300° C, for example, at 300 to 150° C, in other words, a substance which reacts with the excess of oxygen on the catalyst active sites and becomes oxidized at not higher than 300° C.
摘要:
A pollutant removing stack device includes a stack body (10) having a lower reactor section (20) that is divided by a partition (30) into an upper chamber (25) and a lower chamber (24). A first set of spraying units (22) is disposed in the lower chamber (24). A second set of spraying units (29) is disposed the upper chamber (25). A stack gas inlet is connected to the lower chamber (24) of the lower reactor section (20) for entrance of a stack gas. An oxidant supplying unit is connected to the first set of spraying units (22) in order to produce an oxidant mist in the lower chamber (24) for oxidizing a nitrogen compound contained in the stack gas into nitrogen dioxide. An alkaline solution supplying unit is connected to the second set of spraying units (29) in order to produce an alkaline mist in the upper chamber (25) for removing nitrogen dioxide and sulfur dioxide from the stack gas.
摘要:
The present invention provides a nitrogen dioxide absorbent for the exhaust gas purifying facility designed to remove by absorption or adsorption of NO 2 from a gas (such as ventilation gas from road tunnels) containing NO x in low concentrations. The absorbent is composed of a porous carrier and a basic amino acid and/or organic amine compound supported thereon. The absorbent is produced by impregnating a porous carrier sequentially with two aqueous solutions each containing in an amount of, for example, 0.5-3.0 mol/l (preferably 1.0-2.0 mol/l) of basic amino acid and 0.5-3.0 mol/l (preferably 1.0-2.0 mol/l) of organic amine compound, or impregnating a porous carrier with a solution containing 0.5-3.0 mol/l (preferably 1.0-2.0 mol/l) of basic amino acid and/or 0.5-3.0 mol/l (preferably 1.0-2.0 mol/l) of organic amine compound.
摘要:
The present invention provides a nitrogen dioxide absorbent for the exhaust gas purifying facility designed to remove by absorption or adsorption of NO 2 from a gas (such as ventilation gas from road tunnels) containing NO x in low concentrations. The absorbent is composed of a porous carrier and a basic amino acid and/or organic amine compound supported thereon. The absorbent is produced by impregnating a porous carrier sequentially with two aqueous solutions each containing in an amount of, for example, 0.5-3.0 mol/l (preferably 1.0-2.0 mol/l) of basic amino acid and 0.5-3.0 mol/l (preferably 1.0-2.0 mol/l) of organic amine compound, or impregnating a porous carrier with a solution containing 0.5-3.0 mol/l (preferably 1.0-2.0 mol/l) of basic amino acid and/or 0.5-3.0 mol/l (preferably 1.0-2.0 mol/l) of organic amine compound.
摘要:
A system and method for the reduction of NOx in a flue gas are disclosed. A P4 in water liquid/liquid emulsion is injected into a flue gas having a temperature of about 180 DEG C. to about 280 DEG C. to induce phosphorus-accelerated oxidation of the NO in the flue gas. NO2 and phosphorus oxides are subsequently removed from the flue gas stream at a location sufficiently downstream of the injection site that the oxidation of NO in the flue gas is substantially complete prior to the removal of NO2. This significantly improves the NOx recovery rate of the present system and method over those of the prior art. The system can be retrofitted to the waste gas stream of any stationary combustion source regardless of the fuel burned. The system is advantageously used in connection with a wet scrubber for the removal of NO2 and other water soluble flue gas components. Injection of the emulsion results in the creation of ozone by means of the controlled oxidation of white phosphorus. The ozone reacts with nitrogen oxide (NO), which generally accounts for 90% of flue gas NOx, to produce nitrogen dioxide (NO2). The reaction products (NO2 and the P4O10,) can be removed from the flue gas together with SO2 and particulates in the wet scrubber wherein they are efficiently transferred from the gaseous phase to the buffered scrubbing liquid. In the scrubber, the temperature gradient is preferably set through the dew point, so that it recovers both latent as well as sensible heat energy from the flue gas which energy can be sold to commercial or residential consumers to recover at least a part of the capital costs (purchase and operation) associated with the system.
摘要:
A system for exhaust gas purification disposed in the exhaust pipe of internal combustion engine, includes the followings (C) and (D): (C) a catalyst giving an excellent light-off performance at low temperatures, comprising a carrier and a catalyst layer supported thereon, the catalyst layer comprising a precious metal and a substance having an electron donatability and/or a nitrogen dioxide absorbability and releasability, and (D) an adsorbent comprising a carrier and an adsorbent layer having a hydrocarbon adsorbability, supported on the carrier. This system for exhaust gas purification can effectively purify the harmful substances contained in the exhaust gases discharged from internal combustion engines of automobiles, etc., particularly the hydrocarbons discharged in a large amount from gasoline engines during their cold start.
摘要:
An adsorbing material comprising a porous body having larger pores of a mean pore diameter of 200 to 2000 A and smaller pores of a mean pore diameter of 40 to 200 A on the surfaces of the larger pores, said porous body being impregnated with a metal such as silver, copper, etc., or a salt thereof such as silver nitrate, etc., has excellent adsorbing performance for iodine and/or organic iodine compounds under any degree of humidity.
摘要:
Die Erfindung betrifft ein Verfahren zur Abscheidung. von Stickstoffoxiden aus bereits weitgehend entschwefelten Rauchgasen. Der NO-Anteil der Stickstoffoxide wird unter Einsatz von Ozon oder anderen Oxidantien zur Verbesserung der Wasserlöslichkeit in NO 2 übergeführt und der gesamte entschwefelte und aufoxidierte Gasstrom anschließend einem Waschprozeß unterworfen. In dem nachgeschalteten Waschprozeß wird der Waschlösung als reduzierend wirkende Substanzen Alkali-bzw. Erdalkalisulfite zugesetzt, die das in der Waschlösung absorbierte NO 2 zu N 2 reduzieren, wobei die reduzierend wirkenden Substanzen zu den entsprechenden Sulfaten oxidiert werden.