摘要:
Disclosed is a process for starting up fluidized reaction apparatus which are used for producing lower olefins from methanol or/and dimethyl ether. Said process includes after heating the catalyst bed of circulating fluidized catalytic reaction apparatus to above 200 °C or 300°C by using a starting-up auxiliary heat source, feeding methanol or dimethyl ether raw materials to a reactor, whereby heat released by the reaction makes the temperature of the reaction system apparatus increase quickly to a designed temperature, consequently making the system reach the normal operation state rapidly. Said process is suitable for starting up an exothermic fluidized catalytic reaction apparatus and can simplify the apparatus and operation, accordingly lowering the cost.
摘要:
This invention relates to a class of microporous metal-silicoaluminophosphate molecular sieves(MeAPSOs) and the method of their fast preparation. These molecular sieves can be represented by the empirical formula on an anhydrous basis: mR· (M q Si x AI y P z )O 2 , wherein "R" represents the templating agent presented in the intracrystalline pore system; " m " is the molar amount of "R" per mole of (M q Si x Al y P z O 2 and has a value from 0.01 to 8.00; "M" represents at least one metal element; " q ", " x ", " y " and " z " represent the molar fractions of metal, silicon, aluminum and phosphorus respectively, whose variations are q=0∼0.98, x=0∼0.98, y=0.01∼0.60, z=0.01∼0.60 and q+x+y+z=1. The crystallization time of the synthesis is 0.5-12 hours, which is defined as the method of fast preparation. This molecular sieve can be used as adsorbents and catalysts of many hydrocarbon conversion processes.
摘要翻译:本发明涉及一类微孔金属硅铝磷酸盐分子筛(MeAPSO)及其快速制备方法。 这些分子筛可以用无水的经验公式表示:mR。 (MqSixAyPz)O 2,其中“R”表示呈现在晶体内孔系统中的模板剂; “m”是每摩尔(MqSixAlyPzO2)的摩尔量“R”,其值为0.01至8.00;“M”表示至少一种金属元素;“q”,“x”,“y”和“z” 分别表示金属,硅,铝和磷的摩尔分数,其变化为q = 0,0.98,x = 0,0.98,y = 0.01,0.60,z = 0.01,0.60,q + x + y + z = 1 合成结晶时间为0.5-12小时,定义为快速制备方法,该分子筛可用作许多烃转化工艺的吸附剂和催化剂。
摘要:
A rare earth-containing zeolite with a cocrystalline structure of ZSM-5 and ZSM-11, wherein the weight ratio of the moiety having the crystalline structure of ZSM-5 to the moiety having the crystalline structure of ZSM-11 is 0.1 to 10, which has, in the sodium form, the X-ray diffraction pattern set forth in Table 1, and in its originally synthesized anhydrous state, a chemical formula in terms of mole ratios of oxides as follows: 0.1-1.0 Na 2 O · 0.01-1.0 RE 2 O 3 · Al 2 O 3 · 20-300 SiO 2 . Said zeolite has good acid hydrothermal stability and resistance against impurity contamination, and is useful as catalyst in various hydrocarbon conversions.
摘要翻译:一种具有ZSM-5和ZSM-11的共晶体结构的含稀土沸石,其中具有ZSM-5晶体结构的部分与具有ZSM-11晶体结构的部分的重量比为0.1至10, 其以钠形式具有表1所列的X射线衍射图,并且在其最初合成的无水状态下具有如下氧化物摩尔比的化学式:0.1-1.0 Na 2 O 0.01-1.0 RE 2 O 3 ·Al2O3·20-300SiO2。 所述沸石具有良好的酸水热稳定性和抗杂质污染性,并且可用作各种烃转化中的催化剂。
摘要:
The present invention discloses an amine-bromine two electron electrolyte of flow battery and the use thereof, and a flow battery, which belong to the field of flow battery. In the electrolyte, an amino compound with an electron-withdrawing group at the ortho-position of an amino group is used to react with bromine charged to a positive valence so as to form an amine-bromine compound, such that positive-valence bromine is stabilized, and a reversible two-electron transfer reaction from bromine ions to amino compounds is achieved. The amine compounds have different solubilities and produce different voltages depending on their substituent groups, and thus have extensive adjustability and applicability for use in acidic, neutral, and weak alkaline flow battery systems. Flow batteries assembled with the electrolyte prepared using this reaction has the advantages of low cost and high energy density, and can achieve a longer cycle life and higher battery efficiency.
摘要:
The present invention relates to direct preparation of low-carbon olefins by using synthesis gas, and in particular to a catalyst and a method for directly converting synthesis gas into low-carbon olefins. In the method, synthesis gas is used as a reaction raw material and is subjected to a conversion reaction on a fixed bed or a moving bed. The catalyst is a composite catalyst, and is formed by compounding component I and component II in a mechanical mixing manner. The active ingredient of the component I is a metal oxide, and the component II is a molecular sieve having a CHA and AEI structure or one or more of metal modified CHA and/or AEI molecular sieves. The weight ratio between the active ingredient in the component I and component II is in the range of 0.1-20. The reaction process has a very high product yield and selectivity. The sum of selectivity of propylene and butylene reaches 40-75%, the sum of selectivity of low-carbon olefins including ethylene, propylene and butylene can reach 50-90%, and at the same time the selectivity of the byproduct methane is less below 15%, and thus the reaction process has good application prospects.