摘要:
A process to prepare propylene showing desirably increased selectivity comprises contacting, at an elevated temperature, ethanol and a rhenium oxide-modified ZSM-5 zeolite catalyst, under conditions suitable to form propylene. The rhenium oxide-modified ZSM-5 zeolite catalyst may be prepared by impregnating, in an aqueous or organic medium, a ZSM-5 zeolite with a rhenium source, under conditions suitable to form a catalyst precursor, and calcining the catalyst precursor under conditions suitable to form a rhenium oxide-modified ZSM-5 zeolite catalyst.
摘要:
The invention relates to a method for producing a particulate, Si-bound fluidized-bed catalyst having improved abrasion strength, which comprises the steps I. providing an aqueous suspension containing zeolite particles, II. adding a silicone resin mixture containing one or more hydrolysable silicone resin precondensates and mixing the aqueous suspension and the silicone resin mixture, III. spray drying the mixture obtained from step II, wherein the mixture is homogenized before the spray drying, and IV. calcining the spray-dried fluidized-bed catalyst obtained from step III, and an Si-bound fluidized-bed catalyst producible by this method, and also use thereof for non-oxidative dehydroaromatization of C 1 -C 4 -aliphatics.
摘要:
Provided is a process for producing an aromatic hydrocarbon using a molybdenum-containing solid catalyst, more specifically a process for producing an aromatic hydrocarbon efficiently from a lower hydrocarbon gas essentially containing methane by activating the molybdenum-containing solid catalyst with maintaining a high yield for a long period of time. The process comprises a pre-contacting step of allowing a molybdenum-containing solid catalyst to contact with a pre-contacting gas comprising at least one selected from a lower hydrocarbon and a hydrogen gas; and a reaction step of allowing the pre-contacted catalyst to contact with a raw material gas essentially containing methane, to generate an aromatic hydrocarbon, wherein the starting temperature in the pre-contacting step is lower than the reaction temperature, and the temperature during the pre-contacting step from the beginning to the end is not over the reaction temperature.
摘要:
A catalyst for aromatizing a lower hydrocarbon, in order to increase the amount of production of useful aromatic compounds, such as benzene and toluene, by improving the methane conversion rate, the benzene formation rate, the naphthalene formation rate and the BTX formation rate (or a total formation rate of benzene, toluene and xylene) is such that molybdenum and silver are loaded on a metallosilicate as a substrate. It is more preferable to obtain the aromatizing catalyst by loading molybdenum and silver after modifying a zeolite formed of the metallosilicate with a silane compound that has a molecular diameter larger than a pore diameter of the zeolite and that has an amino group, which selectively reacts at a Bronsted acid point of the zeolite, and a straight-chain hydrocarbon group. When producing a process for producing aromatic compounds, these aromatizing catalysts are reacted with a reaction gas containing lower hydrocarbons and carbonic acid gas.
摘要:
It is intended to provide a method for producing an LPG fraction, a gasoline fraction, a kerosene fraction, a gas oil fraction, monocyclic aromatic hydrocarbon and a non-aromatic naphtha fraction from hydrocracked oil obtained by hydrocracking hydrocarbon oil containing polycyclic aromatic hydrocarbon to convert into a light hydrocarbon fraction, and at the same time efficiently and selectively to produce monocyclic aromatic hydrocarbon which is higher valuable alkylbenzenes. The method for producing hydrocarbon fraction of the present invention comprises a hydrocracking step of subjecting a hydrocarbon feedstock which contains polycyclic aromatic hydrocarbon and in which the ratio of carbons constituting an aromatic ring to the total carbons in the hydrocarbon oil (the aromatic ring-constituting carbon ratio) is 35 mole % or more to catalytic cracking in the presence of hydrogen, and is characterized in that 40% or more of a fraction with a boiling point of 215°C or higher in the hydrocarbon feedstock is converted into a fraction with a boiling point lower than 215°C and an hydrocracked oil containing 30 vol % or more of monocyclic aromatic hydrocarbon is produced.
摘要:
On décrit un catalyseur comportant au moins une zéolithe présentant des canaux dont l'ouverture est définie par un anneau à 10 atomes d'oxygène (10 MR), au moins une zéolithe présentant au moins des canaux ou des poches latérales dont l'ouverture est définie par un anneau à 12 atomes d'oxygène (12 MR), au moins un métal choisi dans le groupe constitué par les métaux des groupes IIIA et VIIB et au moins une matrice minérale poreuse. Ledit catalyseur contient éventuellement en outre au moins un métal choisi dans le groupe constitué par les métaux des groupes IVA et VIB. Le catalyseur selon l'invention est utilisé dans un procédé de transalkylation d'hydrocarbures alkylaromatiques tels que le toluène ou le benzène et les alkylaromatiques à au moins 9 atomes de carbone.