POLYOLEFIN MICROPOROUS MEMBRANE, MANUFACTURING SYSTEM THEREFOR, BATTERY SEPARATOR, AND ELECTROCHEMICAL DEVICE

    公开(公告)号:EP4265670A1

    公开(公告)日:2023-10-25

    申请号:EP21905156.2

    申请日:2021-09-14

    摘要: The present invention relates to the field of battery separators. Specifically, disclosed is a polyolefin microporous membrane of which the membrane thickness is 2-30 µm, the puncture strength is 1000-2000 gf, the tensile strength in direction MD is 3200-5000 kgf/cm 2 , the tensile strength in direction TD is 2800-4800 kgf/cm 2 , the porosity is 40% to 57%, the maximum pore diameter is 33-48 nm, the gas permeation rate is 10-400 s/100 mL, the impedance is 0.3-0.9 Ω/cm 2 , a manufacturing system therefor, a coated separator using the base membrane, and an electrochemical apparatus. The polyolefin microporous membrane of the present invention is provided with excellent properties and, with the thickness, tensile strength, puncture strength, air permeability, porosity, and thermal shrinkage thereof satisfying applications having high requirements on the thickness and mechanical strength of the microporous membrane, is very suitable for use in the field of power lithium-ion battery separators.

    NICKEL-METAL HYDRIDE BATTERY
    130.
    发明公开

    公开(公告)号:EP4250396A1

    公开(公告)日:2023-09-27

    申请号:EP23163338.9

    申请日:2023-03-22

    摘要: The invention relates to a Ni-MH battery. The positive electrode active material of the Ni-MH battery is made of spherical nickel hydroxide coated with β-CoOOH; the positive electrode additive used in the positive electrode of the nickel-hydrogen battery comprises tungsten and zinc, and the positive electrode additive further comprises at least one of yttrium and ytterbium. The separator of the battery is made of grafted or fluorinated or sulfonated polypropylene separator. The electrolyte of the Ni-MH battery is an alkaline aqueous solution composed of alkali metal hydroxide, and the concentration of alkali metal hydroxide is 5.5 - 8.0 mol /L. The negative electrode additive used in the negative electrode of the Ni-MH battery comprises yttrium. The Ni-MH battery can effectively reduce the increase in internal resistance of the Ni-MH battery during long-term overcharging in a high-temperature environment, and prolong the service life of the Ni-MH battery.