摘要:
According to the present invention, there are provided lithium titanate particles which exhibit an excellent initial discharge capacity and an enhanced high-efficiency discharge capacity retention rate as an active substance for non-aqueous electrolyte secondary batteries and a process for producing the lithium titanate particles, and Mg-containing lithium titanate particles. The present invention relates to lithium titanate particles with a spinel structure comprising TiO 2 in an amount of not more than 1.5%, Li 2 TiO 3 in an amount of not less than 1% and not more than 6%, and Li 4 Ti 5 O 12 in an amount of not less than 94% and not more than 99% as determined according to Rietveld analysis when indexed with Fd-3m by XRD, and having a specific surface area of 7 to 15 m 2 /g as measured by BET method, a process for producing lithium titanate particles comprising the steps of adding and mixing a water-soluble lithium solution into a water suspension of an oxide of titanium having a BET specific surface area of 40 to 400 m 2 /g and a primary particle diameter of 5 to 50 nm and subjecting the resulting mixed suspension to aging reaction at a temperature of 50 to 100°C; subjecting the resulting reaction product to filtration, drying and pulverization; and subjecting the obtained dry particles to heat-calcination treatment at a temperature of 550 to 800°C, and Mg-containing lithium titanate particles having a composition represented by the formula: Li x Mg y Ti z O 4 wherein x, z > 0; 0.01 ‰¤ y ‰¤ 0.20; 0.01 ‰¤ y/z ‰¤ 0.10; and 0.5 ‰¤ (x + y)/z ‰¤ 1.0, the Mg-containing lithium titanate particles having a BET specific surface area of 5 to 50 m 2 /g, a spinel single phase as a crystal structure, and a lattice constant (a) represented by a value of 0.050y + 8.3595
摘要:
The present invention relates to Li-Ni composite oxide particles that exhibit a high initial discharge capacity and are excellent in thermal stability when used as a positive electrode active substance for non-aqueous electrolyte secondary batteries, and a process for producing the Li-Ni composite oxide particles. The Li-Ni composite oxide particles of the present invention have a composition of Li x Ni 1-y-a-b Co y M1 a M2 b O 2 wherein x, y, a and b represent 1.00 ‰¤ x ‰¤ 1.10; 0
摘要:
The present invention relates to an electromagnetic interference suppression sheet comprising a conductive layer comprising a conductive metal filler and having a surface electrical resistance of 100 to 5000 Ω/□, and a magnetic layer comprising a magnetic material mixed therein and having a real part µ ' of a magnetic permeability of 3 to 45 as measured at 100 MHz which is laminated on the conductive layer. The electromagnetic interference suppression sheet of the present invention is suitable for high-density packaging of electronic devices, and has an excellent low-pass filter characteristic in a near electromagnetic field in a wide frequency band ranging from a low frequency to a high frequency.
摘要:
The present invention relates to an Ni-Zn-Cu-Co ferrite sintered plate having a composition comprising 45 to 50 mol% of Fe 2 O 3 , 10 to 25 mol% of NiO, 15 to 36 mol% of ZnO, 2 to 14 mol% of CuO and 0.1 to 3.5 mol% of CoO, all of the molar amounts being calculated in terms of the respective oxides, and a ferrite sintered sheet that is provided on a surface thereof with a groove and further with an adhesive layer and/or a protective layer. The ferrite sintered sheet is capable of exhibiting an increased µ ' value of a magnetic permeability while maintaining a small µ " value of the magnetic permeability.
摘要翻译:本发明涉及一种Ni-Zn-Cu-Co系铁氧体烧结体,其特征在于,其组成为:Fe 2 O 3为45〜50摩尔%,NiO为10〜25摩尔%,ZnO为15〜36摩尔%,2〜14 氧化铝的摩尔%,CoO的0.1〜3.5摩尔%,所有的摩尔量均以各氧化物计算,铁素体烧结片的表面设置有槽,并且还具有粘合层和/ 或保护层。 铁氧体烧结片能够在保持磁导率的小μ“的情况下表现出增加的磁导率μ'值。
摘要:
The present invention relates to a process for producing lithium iron phosphate particles having an olivine type structure, comprising a first step of mixing an iron oxide or an iron oxide hydroxide as an iron raw material which comprises at least one element selected from the group consisting of Na, Mg, Al, Si, Cr, Mn and Ni in an amount of 0.1 to 2 mol% for each element based on Fe, and a carbon element C in an amount of 5 to 10 mol% based on Fe, and has a content of Fe 2+ of not more than 40 mol% based on an amount of Fe and an average primary particle diameter of 5 to 300 nm, with a lithium raw material and a phosphorus raw material; a second step of controlling agglomerates diameter in the resulting mixture is 0.3 to 5.0 µm; and a third step of sintering the mixture obtained in the second step in an inert gas or reducing gas atmosphere having an oxygen concentration of not more than 0.1% at a temperature of 250 to 750°C.
摘要:
The present invention provides lithium composite compound particles having good high-temperature storage property and excellent cycle characteristics as an active substance for a non-aqueous electrolyte secondary battery, and a secondary battery using the lithium composite compound particles. The Li-Ni composite oxide particles for a non-aqueous electrolyte secondary battery according to the present invention have a BET specific surface area of 0.05 to 0.8 m 2 /g; an atomic ratio (Ma/Ni) of a concentration of an amphoteric metal to a concentration of Ni on an outermost surface of the respective Li-Ni composite oxide particles is 2 to 6; and the concentration of the amphoteric metal on the outermost surface of the respective Li-Ni composite oxide particles is higher than a concentration of the amphoteric metal at a position spaced by 50 nm from the outermost surface toward a center of the respective Li-Ni composite oxide particles.