公开(公告)号：EP2693534A4

公开(公告)日：2015-01-14

申请号：EP11862158

申请日：2011-12-26

申请人： TODA KOGYO CORP

发明人： WATANABE HIROYASU ,  MORITA DAISUKE ,  YAMAMOTO MANABU ,  KOGA KAZUMICHI ,  KAJIYAMA AKIHISA ,  MASUKUNI HIROAKI ,  SADAMURA HIDEAKI ,  MASAKI RYUTA ,  MATSUMOTO KAZUTOSHI

IPC分类号： H01M4/505 ,  C01G53/00 ,  H01M4/525

CPC分类号： C30B1/10 ,  C01G45/1242 ,  C01G51/54 ,  C01G53/54 ,  C01P2002/54 ,  C01P2002/72 ,  C01P2004/61 ,  C01P2006/12 ,  C01P2006/80 ,  C30B1/02 ,  H01M4/505 ,  H01M4/525 ,  Y10T428/2982

公开(公告)号：EP3113253A4

公开(公告)日：2017-08-02

申请号：EP15754705

申请日：2015-02-24

申请人： TODA KOGYO CORP ,  DENKA COMPANY LTD

发明人： KAJIYAMA AKIHISA ,  SANTOKI TERUAKI ,  MORITA DAISUKE ,  MASAKI RYUTA ,  SUGIHARA TAKAHIKO ,  WAKIYAMA TSUYOSHI ,  MATSUMOTO KAZUTOSHI ,  YODA AKIRA ,  INADA TARO ,  YOKOTA HIROSHI ,  KAWASAKI TAKASHI

IPC分类号： H01M4/13 ,  H01M4/131 ,  H01M4/136 ,  H01M4/505 ,  H01M4/525 ,  H01M4/58 ,  H01M4/62 ,  H01M10/052

CPC分类号： H01M4/364 ,  H01M4/131 ,  H01M4/136 ,  H01M4/505 ,  H01M4/525 ,  H01M4/5825 ,  H01M4/625 ,  H01M10/052 ,  H01M10/0525 ,  H01M2004/028

摘要： An object of the present invention is to provide a positive electrode mixture capable of conducting stable charging and discharging with a less amount of gasses generated which has an operating voltage or an initial crystal phase transition voltage of not less than 4.5 V on the basis of lithium. The present invention relates to a positive electrode mixture comprising carbon black having a bulk density of not more than 0.1 g/cm 3 , a crystallite size of 10 to 40 Å, an iodine adsorption of 1 to 150 mg/g, a volatile content of not more than 0.1% and a metal impurity content of not more than 20 ppm, and a positive electrode active substance having an operating voltage or an initial crystal phase transition voltage of not less than 4.5 V on the basis of lithium.

摘要翻译： 本发明的一个目的是提供一种正极混合物，该正极混合物能够以较少量的产生的气体进行稳定的充放电，其具有基于锂的操作电压或初始晶相转变电压不小于4.5V 。 本发明涉及一种正极混合物，其包含体积密度不大于0.1g / cm 3，微晶尺寸为10至40埃，碘吸附值为1至150毫克/克，挥发物含量为 不超过0.1％，金属杂质含量不超过20ppm，并且具有以锂为基础的工作电压或初始晶相转变电压不小于4.5V的正极活性物质。

公开(公告)号：EP2314545A4

公开(公告)日：2014-09-17

申请号：EP09725552

申请日：2009-03-26

申请人： TODA KOGYO CORP

发明人： KOBINO MASASHI ,  FUJITA KATSUHIRO ,  OKAZAKI SEIJI ,  HONDA TOMOHIRO ,  NISHIO TAKAHISA ,  FUJIMOTO RYOTA ,  HIRAMOTO TOSHIAKI ,  SATO KOUTA ,  ITO AKINO ,  OKINAKA KENJI ,  FUJINO SHOICHI ,  NISHIMOTO KAZUSHI ,  UEGAMI MASAYUKI ,  MORITA DAISUKE ,  KAJIYAMA AKIHISA

IPC分类号： C01G51/04 ,  H01M4/48 ,  H01M4/52 ,  H01M10/36

CPC分类号： C01G51/04 ,  C01G51/42 ,  C01P2002/52 ,  C01P2002/60 ,  C01P2002/72 ,  C01P2002/88 ,  C01P2004/03 ,  C01P2004/51 ,  C01P2004/61 ,  C01P2004/62 ,  C01P2006/10 ,  C01P2006/11 ,  C01P2006/12 ,  C01P2006/40 ,  H01M4/131 ,  H01M4/1391 ,  H01M4/485 ,  H01M4/525 ,  H01M10/052

摘要： The present invention relates to cobalt oxyhydroxide particles and lithium cobaltate particles which have a high density and a uniformly grown crystal structure. These objects of the present invention can be achieved by cobalt oxyhydroxide particles having an average secondary particle diameter (D50) of 3.0 to 25.0 µm, a BET specific surface area (BET) of 0.1 to 20.0 m 2 /g, a tap density (TD) of 1.0 to 3.5 g/cm 3 in which the average secondary particle diameter (D50) and the BET specific surface area (BET) of the cobalt oxyhydroxide particles satisfy the relational formula; and by lithium cobaltate particles having an average secondary particle diameter (D50) of 15.0 to 25.0 µm, a specific surface area (BET) of 0.10 to 0.30 m 2 /g, a compressed density (CD; as measured by applying a pressure of 2.5 t/cm 2 thereto) of 3.65 to 4.00 g/cm 3 . The cobalt oxyhydroxide particles are useful as a precursor of a positive electrode active substance (lithium cobaltate particles) used in a non-aqueous electrolyte secondary battery, and the lithium cobaltate particles are useful as a the positive electrode active substance used in a non-aqueous electrolyte secondary battery.

公开(公告)号：EP2492243A4

公开(公告)日：2015-01-21

申请号：EP10825034

申请日：2010-10-21

申请人： TODA KOGYO CORP

发明人： KOBINO MASASHI ,  FUJITA KATSUHIRO ,  FUJINO SHOICHI ,  KAJIYAMA AKIHISA ,  MASAKI RYUTA ,  MORITA DAISUKE ,  YAMAMURA TAKAYUKI ,  KODAIRA TETSUYA ,  YAMASAKI MINORU ,  OKAZAKI SEIJI ,  HIRAMOTO TOSHIAKI ,  ITO AKINO ,  ODA WATARU ,  OKINAKA KENJI

IPC分类号： C01G53/00 ,  H01M4/505 ,  H01M4/525

CPC分类号： C01G45/006 ,  C01G45/1221 ,  C01G51/006 ,  C01G51/44 ,  C01G53/006 ,  C01G53/42 ,  C01G53/44 ,  C01P2002/52 ,  C01P2002/60 ,  C01P2002/72 ,  C01P2004/03 ,  C01P2004/51 ,  C01P2004/61 ,  C01P2006/11 ,  C01P2006/12 ,  C01P2006/40 ,  H01M4/505 ,  H01M4/525 ,  H01M10/052 ,  Y10T428/2982

摘要： The present invention relates to nickel-cobalt-manganese-based compound particles which have a volume-based average secondary particle diameter (D50) of 3.0 to 25.0 µm, wherein the volume-based average secondary particle diameter (D50) and a half value width (W) of the peak in volume-based particle size distribution of secondary particles thereof satisfy the relational formula: W ‰¤ 0.4 x D50, and can be produced by dropping a metal salt-containing solution and an alkali solution to an alkali solution at the same time, followed by subjecting the obtained reaction solution to neutralization and precipitation reaction. The nickel-cobalt-manganese-based compound particles according to the present invention have a uniform particle size, a less content of very fine particles, a high crystallinity and a large primary particle diameter, and therefore are useful as a precursor of a positive electrode active substance used in a non-aqueous electrolyte secondary battery.

摘要翻译： 本发明涉及一种具有3.0至25.0微米的基于体积的平均二次粒径（D50）的镍 - 钴 - 锰类化合物颗粒，worin体积基准的平均二次粒径（D50）和半值宽度 在二次粒子的体积基准的粒径分布中的峰的（W）满足关系式：W‰¤0.4×D50，并且可以通过在在碱性溶液中滴下含金属盐的溶液和在碱性溶液中要生产 在Sametime，接着进行将所得到的反应溶液中以中和和沉淀反应。 所述基于镍 - 钴 - 锰化合物颗粒雅丁到本发明具有均匀的颗粒尺寸，非常细的颗粒的含量少，高结晶度和大的一次粒径，并且因此作为正极的前体是有用 在非水电解质二次电池中使用的活性物质。