摘要:
An object is to provide a novel method for producing a binaphthyl, the method achieving good reaction efficiency and allowing an inorganic salt to be easily removed. As a solution, a method for producing a 2,2'-bis(alkoxycarbonylmethoxy)-1,1'-binaphthyl represented by formula (2), the method including reacting 1,1'-binaphthalene-2,2'-diol and a chloroacetic acid ester represented by formula (1) with each other in a C5 to C8 aliphatic ketone solvent in the presence of an alkali metal iodide, is provided.
摘要:
The purpose of the present invention is to provide an aromatic polycarbonate oligomer solid with substantially reduced low-molecular-weight components, no or a substantially reduced amount of chlorine-containing compounds, high loose bulk density, and ease of handling. The aromatic polycarbonate oligomer solid contains a repeating unit represented by formula (1), has a weight average molecular weight of 500 to 10,000, low-molecular-weight components less than or equal to 5.0 area% measured with high-speed liquid chromatography, and a loose bulk density of greater than or equal to 0.30 g/cm 3 .
摘要:
The purpose of the present invention is to provide an aromatic polycarbonate oligomer solid with substantially reduced low-molecular-weight components, no or a substantially reduced amount of chlorine-containing compounds, high loose bulk density, and ease of handling. The aromatic polycarbonate oligomer solid contains a repeating unit represented by formula (1), has a weight average molecular weight of 500 to10,000, low-molecular-weight components less than or equal to 5.0 area% measured with high-speed liquid chromatography, and a loose bulk density of greater than or equal to 0.22 g/cm 3 .
摘要:
A process for production of 1,1-bis(4-hydroxyphenyl)-3,3,5-trimethylcyclohexane which comprises reacting phenol with 3,3,5-trimethylcyclohexanone in the presence of an acid catalyst, separating the resulting phenol adduct crystals of 1,1-bis(4-hydroxyphenyl)-3,3,5-trimethylcyclohexane from the resulting reaction mixture, and removing the phenol from the phenol adduct crystals, wherein the phenol adduct crystals are dissolved in a crystallization solvent comprising an aromatic hydrocarbon solvent and water, crystallizing the crystals of 1,1-bis(4-hydroxyphenyl)-3,3,5-trimethylcyclohexane out of the crystallization solvent, and collecting the crystals by filtration at a temperature of 40-60°C.