摘要:
The present invention provides: a catalyst which has high activity and enables the production of an olefin polymer that has a polar group; and a method for producing the polymer. A catalyst for olefin polymerization, which contains a metal complex represented by general formula (C1); and a method for producing an ethylene (co)polymer, wherein (1) ethylene is polymerized, (2) ethylene and an olefin having a polar group represented by general formula (1) are copolymerized, or (3) ethylene, an olefin having a polar group represented by general formula (1) and another monomer are copolymerized, with use of the above-described catalyst. (In the formulae, the symbols are as defined in the description; and at least one of R 6 and R 7 represents a 9-fluorenyl analogous group represented by general formula (2).)
摘要:
To provide a resin composition, a pellet, a composite molded article, a method for manufacturing a composite molded article and a tank, all capable of enabling tight joining and integration of the polyacetal resin molded article and the polyethylene resin molded article, and of suppressing formaldehyde emission and occurrence of mold deposit. The resin composition contains a resin ingredient and melamine, the resin ingredient containing a polyacetal resin and a maleic anhydride-modified polyethylene resin, the polyacetal resin and the maleic anhydride-modified polyethylene resin following a mass proportion of (20 to 49):(80 to 51), and molar concentration of the maleic anhydride group capable of reacting with amino group of melamine contained in the resin composition being 5 to 25 µmol/g.
摘要:
The present invention pertains to a method for producing a copolymer of ethylene and an allyl monomer having a polar group represented by general formula (1), or a copolymer of ethylene, an allyl monomer having a polar group represented by general formula (1), and other monomers, wherein the copolymer is produced in the presence of a boron compound having a boron-hydrogen bond or a boron-carbon bond (for example, a compound represented by general formula (2)) by using a metal complex represented by general formula (C1) as a polymerization catalyst (the symbols in the formulas are as described in the description). According to the present invention, a copolymer of ethylene and an allyl monomer can be efficiently produced with high catalytic activity, wherein the copolymer has a polar group and can be used in various applications.
摘要:
Provided is a multi-component, polar group-containing olefin copolymer balanced between transparency, rigidity and toughness. The multi-component, polar group-containing olefin copolymer is a multi-component, polar group-containing olefin copolymer comprising: at least one structural unit (A) selected from the group consisting of a structural unit derived from ethylene and a structural unit derived from an α-olefin which contains 3 to 20 carbon atoms, at least one structural unit (B) composed of a polar group-containing olefin monomer, and a structural unit (C) derived from a non-polar cyclic olefin.
摘要:
A polar-group-containing olefin copolymer which comprises 99.999 to 80 mol% of structural units derived from at least one of ethylene and ±-olefin having 3 to 20 carbon atoms and 20 to 0.001 mol% of structural units derived from at least one polar-group-containing monomer which contains an epoxy group and is represented by the following structural formula (I) or following structural formula (II), the polar-group-containing olefin copolymer being a random copolymer obtained by copolymerization in the presence of a transition metal catalyst and having a linear molecular structure.
摘要:
The invention provides a metallocene compound for use for a catalyst for producing an olefin polymer having a sufficiently high molecular weight while maintaining excellent copolymerizability at a polymerization temperature and under polymerization conditions industrially advantageous in polymerization of an olefin such as ethylene or the like. The metallocene compound of the present invention is represented by the following general formula [I]:
摘要:
A compound represented by the following general formula (1): [In the formula, X represents a nitrogen atom, Y represents a nitrogen atom or a phosphorus atom, R 5 and R 6 each independently are a hydrogen atom or a hydrocarbon group which has 1-30 carbon atoms and may contain one or more heteroatoms, at least one of R 5 and R 6 being a hydrocarbon group which contains two or more heteroatom-containing groups, and R 1 to R 4 each independently represent a hydrogen atom, a hydrocarbon group which has 1-20 carbon atoms and may contain one or more heteroatoms, or a halogen atom, and two or more groups selected from among R 1 to R 4 may be linked to each other to form an alicyclic ring, an aromatic ring, or a heterocyclic ring which contains one or more heteroatoms selected from among oxygen, nitrogen, and sulfur atoms, in which each of the rings is a 5- to 8-membered ring which may have one or more substituents thereon.]
摘要:
The present invention provides a process for producing an ethylene/α-olefin copolymer having an excellent balance between the density and the molecular weight, at an industrially advantageous polymerization temperature of 100-300°C using an olefin polymerization catalyst having excellent α-olefin copolymerization properties. The process for producing an olefin polymer of the present invention comprises copolymerizing ethylene with a α-olefin at a polymerization temperature of 110°C or higher using a catalyst for olefin polymerization which comprises components (A) and (B) and optionally comprises a component (C): Component (A): a metallocene compound represented by the following general formula [I], Component (B): a compound which reacts with component (A) to form an ion pair, or an ion-exchanging layered silicate, and Component (C): an organoaluminum compound,