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1.发明公开
公开(公告)号：EP3932955A1
公开(公告)日：2022-01-05
申请号：EP20763295.1
申请日：2020-02-25
发明人： NOZAKI, Kyoko , KURODA, Junichi , HAYASHI, Shinya , OKUMURA, Yoshikuni , UEMATSU, Masahiro , MITSUSHIGE, Yusuke
摘要： The present invention provides: a catalyst which has high activity and enables the production of an olefin polymer that has a polar group; and a method for producing the polymer. A catalyst for olefin polymerization, which contains a metal complex represented by general formula (C1); and a method for producing an ethylene (co)polymer, wherein (1) ethylene is polymerized, (2) ethylene and an olefin having a polar group represented by general formula (1) are copolymerized, or (3) ethylene, an olefin having a polar group represented by general formula (1) and another monomer are copolymerized, with use of the above-described catalyst. (In the formulae, the symbols are as defined in the description; and at least one of R 6 and R 7 represents a 9-fluorenyl analogous group represented by general formula (2).)
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公开(公告)号：EP3786196A1
公开(公告)日：2021-03-03
申请号：EP19793700.6
申请日：2019-03-07
发明人： NOZAKI, Kyoko , ITO, Shingo , KURODA, Junichi , OKUMURA, Yoshikuni , HAYASHI, Shinya , KOBAYASHI, Minoru , YASUKAWA, Yuichiro
IPC分类号： C08F210/02 , C08F4/70 , C08F218/10 , C07F9/50 , C07F15/00
摘要： The present invention pertains to a method for producing a copolymer of ethylene and an allyl monomer having a polar group represented by general formula (1), or a copolymer of ethylene, an allyl monomer having a polar group represented by general formula (1), and other monomers, wherein the copolymer is produced in the presence of a boron compound having a boron-hydrogen bond or a boron-carbon bond (for example, a compound represented by general formula (2)) by using a metal complex represented by general formula (C1) as a polymerization catalyst (the symbols in the formulas are as described in the description). According to the present invention, a copolymer of ethylene and an allyl monomer can be efficiently produced with high catalytic activity, wherein the copolymer has a polar group and can be used in various applications.
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公开(公告)号：EP2848623B1
公开(公告)日：2017-09-27
申请号：EP13787262.8
申请日：2013-04-30
IPC分类号： C07F15/00 , C07F9/53 , C08F4/70 , C08F4/80 , C08F210/00 , C08F214/14 , C08F216/18 , C08F218/08 , C08F218/12 , C08F220/44
CPC分类号： C08F4/80 , C07F9/5312 , C07F9/5325 , C07F15/006 , C08F4/619 , C08F110/02 , C08F210/02 , C08F218/08 , C08F214/14 , C08F218/12 , C08F220/44 , C08F4/7014 , C08F2500/10 , C08F2500/03 , C08F220/14 , C08F216/18 , C08F2500/02 , C08F4/7019
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公开(公告)号：EP2948483A1
公开(公告)日：2015-12-02
申请号：EP14704180.0
申请日：2014-01-22
发明人： ITO, Shingo , NOZAKI, Kyoko , OTA, Yusuke , OKUMURA, Yoshikuni , KURODA, Junichi
IPC分类号： C08F210/02 , C08F4/70 , C07F9/50 , C07F15/00
CPC分类号： C08F10/02 , C07F9/5442 , C07F15/006 , C07F15/0066 , C08F4/60031 , C08F4/80 , C08F220/02 , C08F210/02 , C08F4/7031 , C08F218/12 , C08F4/7098 , C08F214/14 , C08F220/44 , C08F220/18 , C08F218/08 , C08F218/10
摘要： The present invention relates to a method for producing a homopolymer of olefin represented by formula (1): CH
2 =CHR
1 (R
1 is a hydrogen atom or hydrocarbon group having 1 to 20 carbon atoms) or a copolymer of two or more thereof or a method for producing a copolymer of olefin represented by formula (1) with olefin containing a polar group represented by formula (2) : CH
2 =CHR
2 R
3 (R
2 is a hydrogen atom or methyl group, R
3 is -COOR
12 , -CN, -OCOR
12 , -OR
12 , -CH
2 -OCOR
12 , -CH
2 OH, -CH
2 -N(R
13 )
2 or -CH
2 -Hal (R
12 , R
13 and Hal have the same meanings as stated in the description), using as a catalyst a metal complex of group 10 elements in the periodic system typified by the structure represented by formula 1 ("Men" represents a menthyl group and "Me" represents a methyl group). The present invention enables the production of high molecular weight polymers of the polar group-containing monomers such as polar group-containing allyl compounds.-
公开(公告)号：EP3660105A1
公开(公告)日：2020-06-03
申请号：EP18839085.0
申请日：2018-07-17
发明人： KURODA, Junichi , OKUMURA, Yoshikuni , HAYASHI, Shinya , UEMATSU, Masahiro , HATTORI, Takaaki , YASUKAWA, Yuichiro
IPC分类号： C08L101/12 , B32B27/00 , C08F8/12 , C08L23/08 , C08L29/04
摘要： The present invention relates to a gas-barrier resin composition, including: a gas-barrier resin (A) having an oxygen permeability coefficient of 1.0×10 -14 (cm 3 ·cm/cm 2 ·s·Pa) or less; and a copolymer (B) containing monomer structural units represented by the formula (1), the formula (2), and the formula (3):
where: R 1 represents a hydrogen atom or a methyl group; R 2 represents a hydrocarbon group having 1 to 20 carbon atoms that may be substituted with a halogen atom, a hydroxy group, an alkoxy group, or an amino group; l, m, and n represent numerical values representing molar proportions of the respective monomer structural units, and n may represent 0; and p represents an integer of from 1 to 4, wherein a ratio of a mass of the copolymer (B) to a total mass of the gas-barrier resin (A) and the copolymer (B) is from 1 mass% to 40 mass%. Preferred as the gas-barrier resin (A) are a vinyl alcohol-based resin (A1), a polyamide-based resin (A2), and a polyester-based resin (A3). The present invention can provide a resin composition ameliorated in low flexibility and low impact resistance, which are drawbacks of a gas-barrier resin, without impairing excellent gas barrier properties of the gas-barrier resin.-
公开(公告)号：EP2848623A1
公开(公告)日：2015-03-18
申请号：EP13787262.8
申请日：2013-04-30
CPC分类号： C08F4/80 , C07F9/5312 , C07F9/5325 , C07F15/006 , C08F4/619 , C08F110/02 , C08F210/02 , C08F218/08 , C08F214/14 , C08F218/12 , C08F220/44 , C08F4/7014 , C08F2500/10 , C08F2500/03 , C08F220/14 , C08F216/18 , C08F2500/02 , C08F4/7019
摘要： The present invention relates to a method for producing a high-molecular-weight copolymer of polar group-containing allyl monomers comprising monomer units represented by formulae (3) and (4) (in the formulae, R 1 represents a hydrogen atom (H) or hydrocarbon group having 1 to 6 carbon atoms; R 2 represents -OH, -OCOR 3 (R 3 represents hydrocarbon group having 1 to 5 carbon atoms), -N(R 4 ) 2 (R 4 represents a hydrogen atom or hydrocarbon group having 1 to 5 carbon atoms); and n and m are a value representing the molar ratio of each of the monomer units), which has few branches and unsaturated group at the molecular end, by copolymerizing olefin and an allyl compound using a metal complex of group 10 elements in the periodic system represented by formula (I) as a catalyst.
The present invention enables providing a high-molecular-weight copolymer of polar group-containing allyl monomers, which copolymer has a novel structure, is available for various applications and has been considered to be difficult to synthesize by other polymerization methods such as radical polymerization; and a method for producing the same.-
公开(公告)号：EP4442714A1
公开(公告)日：2024-10-09
申请号：EP22901126.7
申请日：2022-11-18
发明人： NOZAKI, Kyoko , SEIDEL, Falk William , AKITA, Shumpei , KIMURA, Kento , KURODA, Junichi , UEMATSU, Masahiro , SAKURAGI, Tsutomu
摘要： Provided are a catalyst and a method that enable the production of an olefin-based polymer, which has a polar group and is usable for various applications, at high catalytic activity. A metal complex shown in general formula (C1) (in the formula, M represents a palladium atom or a nickel atom, X represents a phosphorus atom (P), R5-R9 are as set forth in the claims, L represents an electron donating ligand, and q is 0, 1/2, 1, or 2) is used as a catalyst for polymerization of an olefin having a polar group.
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公开(公告)号：EP4400520A1
公开(公告)日：2024-07-17
申请号：EP22867171.5
申请日：2022-08-19
发明人： NOZAKI, Kyoko , KIMURA, Kento , KURODA, Junichi , HAYASHI, Shinya , NANJO, Shun , UEMATSU, Masahiro , SAKURAGI, Tsutomu
摘要： Provided are a catalyst, which enables the production of a high molecular weight olefin polymer having a polar group and being usable for various applications at a high catalytic activity, and a method for producing such an olefin polymer. Use is made of, as a polymerization catalyst for an olefin having a polar group, a metal complex represented by general formula (C1) [wherein: M represents an element in group 10 of the periodic table; X represents a phosphorus atom (P) or arsenic atom (As); R5 to R11 are as described in claims; at least one of R6 and R7 is an aralkyl group represented by general formula (2) (wherein R12 to R21 are as described in claims); L represents an electron-donating ligand; and q is 0, 1/2, 1 or 2].
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