Abstract:
The invention relates to a method for purifying a gas mixture containing dinitrogen monoxide and to the use of a purified gas mixture of this type as an oxidant for olefins. In an additional embodiment, the invention also relates to a method for producing ketones, said method comprising the oxidation of an olefin with a gas mixture containing dinitrogen monoxide that has been purified according to the invention.
Abstract:
The present invention relates to a process for purifying a gas mixture containing dinitrogen monoxide at least comprising the at least in part condensation of a gas mixture G-I containing dinitrogen monoxide with a liquid composition Z-1 containing dinitrogen monoxide being obtained, and contacting the composition Z-1 with a gas mixture S-1, with a composition Z-2 and a gas mixture S-2 being obtained.
Abstract:
The invention relates to a base for a mass transfer column, comprising gas through-openings which are distributed over the base (1) and at least one baffle plate (11) for directing the flow of liquid flowing on the base, said base (1) being loadable with a liquid via at least one inlet (3). The base has at least one inlet (3), at least one separating weir (5) which separates the inflowing liquid into two flows, and at least two outlets (12) or at least two inlets (3) and at least one outlet (12) for the liquid. Each flow flows along a flow path (7; 9) to an outlet (12). The invention further relates to a mass transfer column which contains the base and to a use of the base and the mass transfer column.
Abstract:
The present invention relates to a method for purifying a gas mixture G-0 containing nitrous oxide, comprising at least the bringing of the gas mixture G-0 into contact with a solvent mixture (I) containing at least 50% by weight of water with respect to the total solvent mixture (I), wherein the pH of the solvent mixture (I) ranges from 3.5 to 8.0, the desorption of a gas mixture G-1 from a composition (A), the bringing into contact of the gas mixture G-1 with a solvent mixture (II) containing at least 50% by weight of water with respect to the total solvent mixture (II), wherein the pH of the solvent mixture (II) ranges from 2.0 to 8.0, and the desorption of a gas mixture G-2 from a composition (B), wherein the pH in each case relates to a measurement with a glass electrode. The invention also relates to the use of gas mixtures obtained by the method according to the invention, as oxidizing agents for olefins.
Abstract:
The invention relates to a method for purifying a gas mixture G-0 containing dinitrogen monoxide, at least comprising: the absorption of the gas mixture G-0 in an organic solvent, followed by; the desorption of a gas mixture G-1 from the loaded organic solvent; the absorption of the gas mixture G-1 in water and subsequently; the desorption of a gas mixture G-2 from the loaded water, and to the use of a purified gas mixture containing dinitrogen monoxide that can be obtained according to a method of the aforementioned type as oxidizing agents for olefins.
Abstract:
The invention relates to a method for discontinuous purification of crude acrylic acid by means of crystallization, comprising at least one purification step and at least one stripping step. The first stripping step is carried out in a different crystallizer from the first purification step.