Abstract:
The invention relates to a method for the production of a polyamide based on dicarboxylic acids and diamines, wherein a solid mixture is heated in an extruder, the mixture containing a monomer mixture of 50 mol-% of a dicarboxylic acid mixture of 60 to 88 wt.-% of terephthalic acid and 12 to 40 wt.-% isophthalic acid, in which up to 20 wt.-% of the dicarboxylic acid mixture may also be replaced by other dicarboxylic acids, and 50 mol-% of hexamethylene diamine, up to 20 wt.-% of which may be replaced by other C2-30 diamines, using a synchronized twin screw extruder for a dwell time of 10 seconds to 30 minutes to a temperature in the range from 150 to 400°C while removing water vapor, and possibly diamines, through degassing openings.
Abstract:
Thermoplastic molding materials comprising: (A) 20 - 85% by weight of at least one polyamide having a number of amino end groups of 50 mmol/kg, (B) 14.9 - 60% by weight of glass fibers, (C) 0.01 - 2% by weight of at least one heat stabilizer, (D) 0 - 1.5% by weight of at least one demolding assistant and (D) 0 - 30% by weight of further additives, where the sum of the percentages by weight of (A) - (E) is 100.
Abstract:
The invention relates to a method for the production of a polyamide based on dicarboxylic acids and diamines, wherein a solid mixture is heated in an extruder, the mixture containing a monomer mixture of 50 mol-% of a dicarboxylic acid mixture of 60 to 88 wt.-% of terephthalic acid and 12 to 40 wt.-% isophthalic acid, in which up to 20 wt.-% of the dicarboxylic acid mixture may also be replaced by other dicarboxylic acids, and 50 mol-% of hexamethylene diamine, up to 20 wt.-% of which may be replaced by other C2-30 diamines, using a synchronized twin screw extruder for a dwell time of 10 seconds to 30 minutes to a temperature in the range from 150 to 400°C while removing water vapor, and possibly diamines, through degassing openings.
Abstract:
Disclosed are thermoplastic molding materials containing: A) 10 to 99 percent by weight of at least one thermoplastic polyamide; B) 0.1 to 5 percent by weight of at least one polyethyleneimine homopolymer or copolymer; C) 0.05 to 3 percent by weight of a lubricant; D) 0.05 to 3 percent by weight of a copper-containing stabilizer or a sterically hindered phenol or the mixtures thereof; E) 0 to 60 percent by weight of other additives, the total percentage by weight of components (A) to (E) amounting to 100 percent.