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公开(公告)号：EP1994075A2
公开(公告)日：2008-11-26
申请号：EP07712354.5
申请日：2007-02-28
Applicant: BASF SE
Inventor： DESBOIS, Philippe , BLINNE, Gerd , NEUHAUS, Ralf , STAWITZKI, Hagen , WEIS, Hans-Joachim
IPC: C08G69/26
CPC classification number: C08G69/265 , C08K7/02 , C08L23/00 , C08L23/16 , C08L77/06 , C08L2666/06
Abstract: The invention relates to partially aromatic, partially crystalline thermoplastic polyamide moulding compounds containing: A) between 40 and 100 wt. % of a copolyamide consisting of a1) between 30 and 44 mol % of units derived from terephthalic acid, a2) between 6 and 20 mol % of units derived from isophthalic acid, a3) between 42 and 49.5 mol % of units derived from hexamethylene diamine, and a4) between 0.5 and 8 mol % of units derived from aromatic diamines having between 6 and 30 C atoms, the mol percentage of constituents a1) to a4) amounting to 100; B) between 0 and 50 wt % of a fibrous and particulate filler; C) between 0 and 30 wt. % of a rubber-elastic polymer; and D) between 0 and 30 % of other additives and auxiliary products, the weight percentage of constituents A) to D) amounting to 100.
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公开(公告)号：EP2160432B1
公开(公告)日：2012-10-24
申请号：EP08760905.3
申请日：2008-06-12
Applicant: BASF SE
Inventor： DESBOIS, Philippe , STAWITZKI, Hagen , NEUHAUS, Ralf , WEIS, Hans-Joachim , WEICHMANN, Jürgen , FERNANDEZ RODILES, Raquel , VOGEL, Gunter
CPC classification number: C08G69/26 , C08G69/265 , C08G69/28
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公开(公告)号：EP2121843A2
公开(公告)日：2009-11-25
申请号：EP07857359.9
申请日：2007-12-11
Applicant: BASF SE
Inventor： WEBER, Martin , HOPFENSPIRGER, Xaver , FUNKHAUSER, Steffen , HECKMANN, Walter , SCHNORR, Jörg , FERNANDEZ RODILES, Raquel , KLENZ, Rainer , STAWITZKI, Hagen , BRUCHMANN, Bernd
CPC classification number: C08L77/06 , C08L51/06 , C08L67/00 , C08L69/00 , C08L77/00 , C08L2205/03 , C08L2666/18 , C08L2666/02 , C08L2666/24
Abstract: Thermoplastic moulding compositions comprising: A) from 40 to 96% by weight of a partly aromatic polyamide, B) from 2 to 30% by weight of a copolymer of B1) from 35 to 89.9% by weight of ethylene, B2) from 10 to 60% by weight of 1-octene or 1-butene or propylene or a mixture thereof and B3) from 0.05 to 5% by weight of functional monomers selected from the group consisting of carboxylic acid, carboxylic anhydride, carboxylic ester, carboxamide, carboximide, amino, hydroxyl, epoxide, urethane and oxazoline groups and mixtures thereof, C) from 1 to 50% by weight of fibrous or particulate fillers or mixtures thereof, D) from 0.1 to 10% by weight of D1) at least one highly branched or hyperbranched polycarbonate having an OH number of from 1 to 600 mg of KOH/g of polycarbonate (in accordance with DIN 53240, Part 2) or D2) at least one highly branched or hyperbranched polyester of the AxBy type where x is at least 1.1 and y is at least 2.1 or a mixture thereof, E) from 0 to 15% by weight of an electrically conductive additive, F) from 0 to 30% by weight of further additives, where the sum of the percentages by weight of the components A) to F) is 100%.
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公开(公告)号：EP2049597A2
公开(公告)日：2009-04-22
申请号：EP07787618.3
申请日：2007-07-17
Applicant: BASF SE
Inventor： WEBER, Martin , HOPFENSPIRGER, Xaver , FUNKHAUSER, Steffen , HECKMANN, Walter , SCHNORR, Jörg , FERNANDEZ RODILES, Raquel , KLENZ, Rainer , STAWITZKI, Hagen
CPC classification number: C08L77/00 , C08L51/06 , C08L77/06 , C08L2666/24
Abstract: Thermoplastic moulding compositions comprising A) from 40 to 96.2% by weight of a semiaromatic polyamide, B) from 2 to 30% by weight of an impact-modifying polymer which contains functional groups, C) from 1 to 50% by weight of fibrous or particulate fillers or a mixture of these, D) from 0.2 to 5% by weight of a lubricant, E) from 0.5 to 15% by weight of an electrically conductive additive, F) from 0 to 30% by weight of other additives, where the total of the percentages by weight of components A) to F) is 100%.
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公开(公告)号：EP2121843B1
公开(公告)日：2010-08-25
申请号：EP07857359.9
申请日：2007-12-11
Applicant: BASF SE
Inventor： WEBER, Martin , HOPFENSPIRGER, Xaver , FUNKHAUSER, Steffen , HECKMANN, Walter , SCHNORR, Jörg , FERNANDEZ RODILES, Raquel , KLENZ, Rainer , STAWITZKI, Hagen , BRUCHMANN, Bernd
CPC classification number: C08L77/06 , C08L51/06 , C08L67/00 , C08L69/00 , C08L77/00 , C08L2205/03 , C08L2666/18 , C08L2666/02 , C08L2666/24
Abstract: Thermoplastic moulding compositions comprising: A) from 40 to 96% by weight of a partly aromatic polyamide, B) from 2 to 30% by weight of a copolymer of B1) from 35 to 89.9% by weight of ethylene, B2) from 10 to 60% by weight of 1-octene or 1-butene or propylene or a mixture thereof and B3) from 0.05 to 5% by weight of functional monomers selected from the group consisting of carboxylic acid, carboxylic anhydride, carboxylic ester, carboxamide, carboximide, amino, hydroxyl, epoxide, urethane and oxazoline groups and mixtures thereof, C) from 1 to 50% by weight of fibrous or particulate fillers or mixtures thereof, D) from 0.1 to 10% by weight of D1) at least one highly branched or hyperbranched polycarbonate having an OH number of from 1 to 600 mg of KOH/g of polycarbonate (in accordance with DIN 53240, Part 2) or D2) at least one highly branched or hyperbranched polyester of the AxBy type where x is at least 1.1 and y is at least 2.1 or a mixture thereof, E) from 0 to 15% by weight of an electrically conductive additive, F) from 0 to 30% by weight of further additives, where the sum of the percentages by weight of the components A) to F) is 100%.
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Patent Agency Ranking
公开(公告)号：EP2049597B1
公开(公告)日：2010-02-24
申请号：EP07787618.3
申请日：2007-07-17
Applicant: BASF SE
Inventor： WEBER, Martin , HOPFENSPIRGER, Xaver , FUNKHAUSER, Steffen , HECKMANN, Walter , SCHNORR, Jörg , FERNANDEZ RODILES, Raquel , KLENZ, Rainer , STAWITZKI, Hagen
CPC classification number: C08L77/00 , C08L51/06 , C08L77/06 , C08L2666/24
Abstract: Thermoplastic moulding compositions comprising A) from 40 to 96.2% by weight of a semiaromatic polyamide, B) from 2 to 30% by weight of an impact-modifying polymer which contains functional groups, C) from 1 to 50% by weight of fibrous or particulate fillers or a mixture of these, D) from 0.2 to 5% by weight of a lubricant, E) from 0.5 to 15% by weight of an electrically conductive additive, F) from 0 to 30% by weight of other additives, where the total of the percentages by weight of components A) to F) is 100%.
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公开(公告)号：EP2160431B1
公开(公告)日：2011-07-13
申请号：EP08760827.9
申请日：2008-06-11
Applicant: BASF SE
Inventor： DESBOIS, Philippe , KOPIETZ, Michael , NEUHAUS, Ralf , STAWITZKI, Hagen , WEIS, Hans-Joachim , ENGELMANN, Jochen
CPC classification number: C08G69/265 , B29C47/822 , C08G69/30
Abstract: The invention relates to a method for the production of a polyamide based on dicarboxylic acids and diamines, wherein a solid mixture is heated in an extruder, the mixture containing a monomer mixture of 50 mol-% of a dicarboxylic acid mixture of 60 to 88 wt.-% of terephthalic acid and 12 to 40 wt.-% isophthalic acid, in which up to 20 wt.-% of the dicarboxylic acid mixture may also be replaced by other dicarboxylic acids, and 50 mol-% of hexamethylene diamine, up to 20 wt.-% of which may be replaced by other C2-30 diamines, using a synchronized twin screw extruder for a dwell time of 10 seconds to 30 minutes to a temperature in the range from 150 to 400°C while removing water vapor, and possibly diamines, through degassing openings.
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公开(公告)号：EP2160432A1
公开(公告)日：2010-03-10
申请号：EP08760905.3
申请日：2008-06-12
Applicant: BASF SE
Inventor： DESBOIS, Philippe , STAWITZKI, Hagen , NEUHAUS, Ralf , WEIS, Hans-Joachim , WEICHMANN, Jürgen , FERNANDEZ RODILES, Raquel , VOGEL, Gunter
CPC classification number: C08G69/26 , C08G69/265 , C08G69/28
Abstract: The invention relates to a method for producing polyamides based on dicarboxylic acids and diamines, comprising the following steps: 1) preparing an aqueous monomer mixture of dicarboxylic acids and diamines, the molar ratio of dicarboxylic acids to diamines being adjusted such that a molar deficit of dicarboxylic acids or diamines of 1 to 10 mol %, relative to the other component, is present at the end of step 3), 2) transferring the aqueous mixture from step 1) into a continuously operated vaporization reactor, in which diamines and dicarboxylic acids are converted at a temperature in the range from 100 to 370 °C and a pressure in the range from 1 to 50 bar, 3) transferring the mixture from step 2) into a precipitator operated at a temperature in the range from 100 to 370 °C under separation of gaseous components, 4) transferring the mixture from step 3), together with diamine or dicarboxylic acid at a quantity suitable to make up for the molar deficit, into an extruder operating at a temperature in the range from 150 to 400°C for a dwell period in the range from 10 seconds to 30 minutes, while removing gaseous components through degassing openings.
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公开(公告)号：EP2160431A1
公开(公告)日：2010-03-10
申请号：EP08760827.9
申请日：2008-06-11
Applicant: BASF SE
Inventor： DESBOIS, Philippe , KOPIETZ, Michael , NEUHAUS, Ralf , STAWITZKI, Hagen , WEIS, Hans-Joachim , ENGELMANN, Jochen
CPC classification number: C08G69/265 , B29C47/822 , C08G69/30
Abstract: The invention relates to a method for the production of a polyamide based on dicarboxylic acids and diamines, wherein a solid mixture is heated in an extruder, the mixture containing a monomer mixture of 50 mol-% of a dicarboxylic acid mixture of 60 to 88 wt.-% of terephthalic acid and 12 to 40 wt.-% isophthalic acid, in which up to 20 wt.-% of the dicarboxylic acid mixture may also be replaced by other dicarboxylic acids, and 50 mol-% of hexamethylene diamine, up to 20 wt.-% of which may be replaced by other C2-30 diamines, using a synchronized twin screw extruder for a dwell time of 10 seconds to 30 minutes to a temperature in the range from 150 to 400°C while removing water vapor, and possibly diamines, through degassing openings.
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公开(公告)号：EP1994075B1
公开(公告)日：2009-09-02
申请号：EP07712354.5
申请日：2007-02-28
Applicant: BASF SE
Inventor： DESBOIS, Philippe , BLINNE, Gerd , NEUHAUS, Ralf , STAWITZKI, Hagen , WEIS, Hans-Joachim
IPC: C08G69/26
CPC classification number: C08G69/265 , C08K7/02 , C08L23/00 , C08L23/16 , C08L77/06 , C08L2666/06
Abstract: The invention relates to partially aromatic, partially crystalline thermoplastic polyamide moulding compounds containing: A) between 40 and 100 wt. % of a copolyamide consisting of a1) between 30 and 44 mol % of units derived from terephthalic acid, a2) between 6 and 20 mol % of units derived from isophthalic acid, a3) between 42 and 49.5 mol % of units derived from hexamethylene diamine, and a4) between 0.5 and 8 mol % of units derived from aromatic diamines having between 6 and 30 C atoms, the mol percentage of constituents a1) to a4) amounting to 100; B) between 0 and 50 wt % of a fibrous and particulate filler; C) between 0 and 30 wt. % of a rubber-elastic polymer; and D) between 0 and 30 % of other additives and auxiliary products, the weight percentage of constituents A) to D) amounting to 100.
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