公开(公告)号：EP2571838A1

公开(公告)日：2013-03-27

申请号：EP11717410.2

申请日：2011-04-15

申请人： Bioamber, S.A.S.

发明人： FRUCHEY, Olan, S. ,  MANZER, Leo, E. ,  DUNUWILA, Dilum ,  KEEN, Brian, T. ,  ALBIN, Brooke, A. ,  CLINTON, Nye, A. ,  DOMBEK, Bernard, D.

IPC分类号： C07C51/02 ,  C07C51/41 ,  C07C51/43 ,  C07C51/44 ,  C07C55/02 ,  C07C55/08 ,  C07C55/21 ,  C07C57/13 ,  C07C57/15

CPC分类号： C07C51/46 ,  C07C51/02 ,  C07C51/41 ,  C07C51/43 ,  C07C51/44 ,  C07C55/02 ,  C07C57/13 ,  C07C55/08 ,  C07C55/21 ,  C07C57/15

摘要： A process for making HOOC-R-COOH compound acid from a clarified NH
4
+ - OOC- R-COO
- NH
4
+ compound-containing fermentation broth including distilling the broth under super atmospheric pressure at a temperature of >I00°C to about 250°C to form an overhead that comprises water and ammonia, and a liquid bottoms that Includes HOOC-R-COOH compound acid, and at least about 20 wt%. water; cooling the. bottoms to a temperature sufficient to cause the bottoms to separate into a liquid portion in contact with a solid portion that is substantially pure HOOC-R-COOH compound acid; separating the solid portion from the liquid portion; and recovering the solid portion.

摘要翻译： 由澄清的含NH 4 + -OOC-R-COO-NH 4 +化合物的发酵液制备HOOC-R-COOH化合物酸的方法，包括在超过大气压下在≥100℃的温度下蒸馏该液体培养基至约 250℃以形成包含水和氨的塔顶馏出物和包含HOOC-R-COOH化合物酸和至少约20重量％的液体塔底物。 水; 冷却。 底部至足以使底部分离成与实质上纯的HOOC-R-COOH化合物酸的固体部分接触的液体部分的温度; 将固体部分与液体部分分离; 并回收固体部分。

公开(公告)号：EP2582678A1

公开(公告)日：2013-04-24

申请号：EP11726029.9

申请日：2011-06-10

申请人： BioAmber S.A.S.

发明人： FRUCHEY, Olan, S. ,  MANZER, Leo, E. ,  DUNUWILA, Dilum ,  KEEN, Brian, T. ,  ALBIN, Brooke, A. ,  CLINTON, Nye, A. ,  DOMBEK, Bernard, D.

IPC分类号： C07D223/10 ,  C12P7/44

CPC分类号： C07D201/08 ,  C07D223/10 ,  C12P7/44 ,  C12P17/10

摘要： Processes for producing caprolactam (CL) and derivatives thereof from adipic acid (AA) obtained from fermentation broths containing diammonium adipate (DAA) or monoammonium adipate (MAA).

公开(公告)号：EP2582677A1

公开(公告)日：2013-04-24

申请号：EP11726028.1

申请日：2011-06-10

申请人： BioAmber S.A.S.

发明人： FRUCHEY, Olan, S. ,  MANZER, Leo, E. ,  DUNUWILA, Dilum ,  KEEN, Brian, T. ,  ALBIN, Brook, A. ,  CLINTON, Nye, A. ,  DOMBEK, Bernard, D.

IPC分类号： C07D223/10 ,  C07D313/04 ,  C07C29/149 ,  C12P7/44

CPC分类号： C07D223/10 ,  C07C29/149 ,  C07C51/412 ,  C07C51/43 ,  C07D313/04 ,  C12P7/18 ,  C12P7/44 ,  C12P17/08 ,  C12P17/10 ,  C07C31/20 ,  C07C55/14

摘要： Processes for making hydrogenated products including caprolactame (CL) caprolactone (CLO) or 1,6-hexanediol (HDO) and derivative thereof from monoammonium adipate (MAA) and/or adipic acid (AA) obtained from a clarified diammonium adipate-containing (DAA-containing) fermentation broth or monoammonium adipate-containing (MAA-containing) fermentation broth.

公开(公告)号：EP2571850A1

公开(公告)日：2013-03-27

申请号：EP11722252.1

申请日：2011-05-17

申请人： BioAmber S.A.S.

发明人： FRUCHEY, Olan, S. ,  MANZER, Leo, E. ,  DUNUWILA, Dilum ,  KEEN, Brian, T. ,  CLINTON, Nye, A. ,  ALBIN, Brooke, A. ,  DOMBEK, Bernard, D.

IPC分类号： C07D207/27 ,  C07D207/267

CPC分类号： C07D207/27 ,  C07D207/267

摘要： Processes for making pyrrolidones include providing a clarified diammonium succinate (DAS)-containing and/or monoammonium succinate (MAS)-containing fermentation broth; distilling the broth under super atmospheric pressure at a temperature of greater than 100°C to about 300°C to form an overhead that includes water and ammonia, and a liquid bottoms that includes SA, and at least about 20 wt% water; cooling and/or evaporating the bottoms to attain a temperature and composition sufficient to cause the bottoms to separate into a liquid portion and a solid portion that is substantially pure SA; separating the solid portion from the liquid portion; and converting the solid SA portion to pyrrolidones.