公开(公告)号：EP2440514B1

公开(公告)日：2018-08-22

申请号：EP10728495.2

申请日：2010-06-11

Applicant: Archer-Daniels-Midland Company

Inventor： BOUSSIE, Thomas, R. ,  DIAS, Eric, L. ,  FRESCO, Zachary, M. ,  MURPHY, Vincent, J. ,  SHOEMAKER, James ,  ARCHER, Raymond ,  JIANG, Hong

IPC: C07C209/00 ,  C07C253/00 ,  C07D223/10 ,  C08G63/16 ,  C08G69/26 ,  C07C51/377 ,  C07C55/14 ,  C07C51/41 ,  C07C211/12 ,  C07C255/04 ,  C07D309/30 ,  C07D201/08 ,  C07C51/235 ,  C08G69/14 ,  C08G69/36

CPC classification number: C07C209/00 ,  C07B2200/07 ,  C07C51/235 ,  C07C51/377 ,  C07C51/412 ,  C07C253/00 ,  C07D201/08 ,  C07D223/10 ,  C07D309/30 ,  C08G63/16 ,  C08G69/14 ,  C08G69/26 ,  C08G69/36 ,  C07C55/14 ,  C07C211/12 ,  C07C255/04 ,  C07C59/285

Abstract: The present invention relates to a process for preparing glucaric acid or lactone thereof, the process comprising: reacting glucose with oxygen in the presence of a heterogeneous oxidation catalyst comprising a metal selected from the group consisting of Pd, Pt, and a combination thereof to convert at least a portion of the glucose to glucaric acid or lactone thereof, wherein the pH of the reaction mixture is less than 7 and the reaction is conducted in the substantial absence of added base, and wherein at least about 50% of the glucose is converted to glucaric acid or lactone thereof.

公开(公告)号：EP3214072A4

公开(公告)日：2018-04-11

申请号：EP15854971

申请日：2015-10-27

Applicant: TORAY INDUSTRIES

Inventor： ITO MASATERU ,  TSUKAMOTO DAIJIRO ,  KAWAMURA KENJI ,  YAMASHITA KOHEI ,  AKAHIRA MASATO ,  YAMADA KATSUSHIGE ,  YAMAUCHI KOJI

IPC: C07D201/08 ,  B01J23/44 ,  C07B61/00 ,  C07D223/10 ,  C08G69/14

CPC classification number: C07D201/08 ,  B01J23/44 ,  C07B61/00 ,  C07D223/10 ,  C08G69/14

Abstract: A method for selective production of µ-caprolactam, wherein a substance inducible from a biomass resource is used as a material; the reaction process is short; ammonium sulfate is not produced as a by-product; and production of by-products is suppressed; is disclosed. The method for producing µ-caprolactam comprises the step of reacting a particular compound inducible from a biomass resource, such as ±-hydromuconic acid, 3-hydroxyadipic acid, or 3-hydroxyadipic acid-3,6-lactone, or a salt thereof with hydrogen or ammonia.

公开(公告)号：EP2817293A1

公开(公告)日：2014-12-31

申请号：EP13705896.2

申请日：2013-02-13

Applicant: Rennovia, Inc.

Inventor： DIAS, Eric L. ,  MURPHY, Vincent J. ,  LONGMIRE, James ,  JIANG, Hong

IPC: C07D223/10 ,  C07D201/08 ,  B01J21/06 ,  B01J23/36 ,  B01J23/46

CPC classification number: C07D223/10 ,  B01J23/40 ,  B01J23/6525 ,  B01J23/6567 ,  B01J23/8906 ,  B01J23/8913 ,  B01J23/892 ,  B01J23/8926 ,  B01J35/1014 ,  B01J35/1019 ,  B01J37/0201 ,  B01J37/18 ,  C07D201/08 ,  Y02P20/52

Abstract: Processes are disclosed for the conversion of adipic acid to caprolactam employing a chemocatalytic reaction in which an adipic acid substrate is reacted with ammonia and hydrogen, in the presence of particular heterogeneous catalysts and employing unique solvents. The present invention also enables the conversion of other adipic acid substrates, such as mono-esters of adipic acid, di-esters of adipic acid, mono-amides of adipic acid, di-amides of adipic acid, and salts thereof to caprolactam. Solvents useful in the process that do not react with ammonia are also disclosed. Catalyst supports are disclosed which catalyze the reaction of the substrate with ammonia in the absence of added metal. Metals on the catalyst supports comprise ruthenium (Ru), rhodium (Rh), palladium (Pd), osmium (Os), iridium (Ir), and/or platinum (Pt). Heterogeneous catalysts comprising ruthenium (Ru) and rhenium (Re) on titania and/or zirconia supports are also disclosed. Further, disclosed are products produced by such processes, as well as products producible from such products.

公开(公告)号：EP2582678A1

公开(公告)日：2013-04-24

申请号：EP11726029.9

申请日：2011-06-10

Applicant: BioAmber S.A.S.

Inventor： FRUCHEY, Olan, S. ,  MANZER, Leo, E. ,  DUNUWILA, Dilum ,  KEEN, Brian, T. ,  ALBIN, Brooke, A. ,  CLINTON, Nye, A. ,  DOMBEK, Bernard, D.

IPC: C07D223/10 ,  C12P7/44

CPC classification number: C07D201/08 ,  C07D223/10 ,  C12P7/44 ,  C12P17/10

Abstract: Processes for producing caprolactam (CL) and derivatives thereof from adipic acid (AA) obtained from fermentation broths containing diammonium adipate (DAA) or monoammonium adipate (MAA).

公开(公告)号：EP2148856A2

公开(公告)日：2010-02-03

申请号：EP08725798.6

申请日：2008-02-20

Applicant: Board of Trustees of Michigan State University

Inventor： FROST, John W.

IPC: C07D201/00 ,  C07D201/02 ,  C07D201/08

CPC classification number: C07D201/00 ,  C07D201/02 ,  C07D201/08 ,  Y02P20/52

Abstract: Catalytic processes for preparing caprolactam, pipecolinic acid, and their derivatives, from lysine or alpha-amino-epsilon-caprolactam starting materials, and products produced thereby. A process for preparing caprolactam or a derivative thereof, the process comprising contacting a reactant comprising lysine or alpha aminocaprolactam with a catalyst and a gas comprising hydrogen gas, in the presence of a solvent. The catalyst may be provided on a support material, such as a transition metal.

公开(公告)号：EP1062203B2

公开(公告)日：2009-10-21

申请号：EP99910871.5

申请日：1999-03-17

Applicant: DSM IP Assets B.V. ,  E.I. DU PONT DE NEMOURS AND COMPANY

Inventor： AGTERBERG, Frank, Petrus, Willibrord ,  GUIT, Rudolf, Philippus, Maria ,  HAASEN, Nicolaas, Franciscus

IPC: C07D201/16 ,  C07D201/08

CPC classification number: C07D201/08 ,  C07D201/16

Abstract: The invention relates to a process for the purification of crude ε-caprolactam, wherein crude ε-caprolactam prepared by cyclization of alkyl 6-aminocaproate, 6-aminocapronitrile, 6-aminocaproic acid, 6 aminocaproic amide and/or oligomers thereof, is subjected to a crystallization process.

公开(公告)号：EP1975155A1

公开(公告)日：2008-10-01

申请号：EP06832839.2

申请日：2006-11-17

Applicant: Ube Industries, Ltd.

Inventor： KUGIMOTO, Junichi

IPC: C07D201/08 ,  C07D225/02 ,  C07B61/00

CPC classification number: C07D201/08 ,  C07D225/02

Abstract: Disclosed is a process for production of a lactam (particularly, an industrially useful lactam, e.g., laurolactam) with high selectivity, comprising hydrogenating a cyclic dicarboxylic acid imide having a large of ring members (particularly, a 8-membered or more cyclic dicarboxylic acid imide) to produce a corresponding. The process is characterized by hydrogenating a 8-membered or more cyclic dicarboxylic acid imide in the presence of ruthenium of platinum. In the process, the ruthenium or platinum may be supported on activated charcoal and an alcohol may be used as a reaction solvent.

Abstract translation: 公开了一种制备具有高选择性的内酰胺（特别是工业上可用的内酰胺）的方法，包括使具有大环成员的环状二羧酸酰亚胺（特别是8元以上的环状二羧酸 酰亚胺）生成相应的。 该方法的特征在于在铂的钌的存在下氢化8元或更多的环状二羧酸酰亚胺。 在此过程中，钌或铂可以负载在活性炭上，醇可用作反应溶剂。

公开(公告)号：EP1606252A4

公开(公告)日：2008-08-06

申请号：EP04758111

申请日：2004-03-23

Applicant: DU PONT

Inventor： MANZER LEO ERNEST

IPC: C07D207/267 ,  C07D201/08 ,  C07D207/26

CPC classification number: C07D201/08 ,  C07D207/267 ,  C10L1/224 ,  C10L1/232 ,  C10L10/18

公开(公告)号：EP1858843A1

公开(公告)日：2007-11-28

申请号：EP06738306.7

申请日：2006-03-15

Applicant: Invista Technologies S.a.r.l.

Inventor： SENGUPTA, Sourav, K. ,  OSTERMAIER, John, J. ,  KIRBY, Gregory, S.

IPC: C07D201/08 ,  C07D223/10

CPC classification number: C07D201/08

Abstract: Lactams, in particular ϵ-caprolactam, are produced by the hydrolytic cyclization of aminonitriles, in particular 6-aminocapronitrile, in the vapor phase in a plurality of adiabatic fixed bed reaction zones arranged in succession wherein at least a portion of the heat of the exothermic reaction is removed between each of the successive reaction zones. Conducting the reaction in such a manner requires less capital for the reactor itself. It has also been found that the product exiting such a reaction system can be directly fed to a distillation unit without the need of additional cooling or storing.

公开(公告)号：EP0891327B2

公开(公告)日：2007-06-27

申请号：EP97902722.4

申请日：1997-02-05

Applicant: INVISTA Technologies S.à.r.l.

Inventor： GUIT, Rudolf, Philuppus, Maria ,  FRENTZEN, Yvonne, Helene

IPC: C07D201/00 ,  C07D201/16

CPC classification number: C07D201/08 ,  C07D201/16

Abstract: Process to separate ε-caprolactam from an aqueous mixture containing ε-caprolactam and at least 0.5 wt.% oligomers, wherein the separation is performed by extraction using an organic extraction agent. The aqueous mixture may be obtained in a process to prepare ε-caprolactam starting from 6-aminocapronitrile or in a process to prepare ε-caprolactam starting from 6-aminocaproic acid.