摘要:
A catalyst for purification of exhaust gas, comprising: a material (A) which can release a noble metal at a high temperature; and a material (B) which contains a composite oxide of zirconia and/or alumina and at least one element selected from the group consisting of alkaline earth metal elements, rare earth elements and group 3A elements, and which receives the noble metal released from the material (A) at the high temperature.
摘要:
An exhaust gas cleaning catalyst is provided in an exhaust passage of an internal combustion engine to convert NOx in exhaust gas. The exhaust gas cleaning catalyst includes a carrier; a plurality of kinds of metal catalysts which are supported on the carrier; and an NOx absorbent which is supported on the carrier and has an NOx storage capacity. The exhaust gas cleaning catalyst includes at least platinum and rhodium as the metal catalysts. A Pt/Rh mass ratio in an upstream portion (65 a) including an exhaust gas inlet side end is different from the Pt/Rh mass ratio in a downstream portion (65 b) including an exhaust gas outlet side end, and the Pt/Rh mass ratio in the upstream portion (65a) is higher than the Pt/Rh mass ratio in the downstream portion (65b). The Pt/Rh mass ratio is a mass ratio of platinum to rhodium.
摘要:
An exhaust gas purification system includes: a catalyst (3) provided in an exhaust gas passage of an internal combustion engiue (1) and having a carrier containing a basic oxide and platinum carried on the carrier; a catalyst (4) for purifying NOx; and oxygen supply means (2).
摘要:
A regeneration apparatus comprises a heater 2 which heats a catalyst 1 at the time of stopping fuel supply to an engine, a pump 4 which supplies an oxidizing gas or a reducing gas to the heated catalyst 1 and a switching valve 3. In the oxidizing step, catalytic poisons, for example hydrocarbon, which are absorbed on a noble metal are oxidized and removed. The particles of the noble metal become oxidized particles as pure oxide and the like. After the oxidizing step, the reducing step is carried out. In the reducing step, particles of the noble metal are reduced and re-dispersed on the support simultaneously and as a result, the particles of the noble metal become fine. Thus, a deteriorated catalyst can be regenerated without interrupting the use of catalyst and also without deteriorating the drivability.
摘要:
A metal oxide catalyst carrier particle has a center portion and an outer skin portion each containing a first metal oxide and a second metal oxide. The center portion and the outer skin portion are different in composition. The mole fraction of the metal of the first metal oxide is higher in the center portion than in the outer skin portion and the mole fraction of the metal of the second metal oxide is higher in the outer skin portion than in the center portion. The second metal oxide is selected from the group consisting of rare earth oxides, except for ceria, and alkali earth metal oxides. In addition, platinum is supported on the metal oxide catalyst carrier particle, thus forming an exhaust gas purification catalyst.
摘要:
An exhaust gas cleaning catalyst is provided in an exhaust passage of an internal combustion engine to convert NOx in exhaust gas. The exhaust gas cleaning catalyst includes a carrier; a plurality of kinds of metal catalysts which are supported on the carrier; and an NOx absorbent which is supported on the carrier and has an NOx storage capacity. The exhaust gas cleaning catalyst includes at least platinum and rhodium as the metal catalysts. A Pt/Rh mass ratio in an upstream portion (65 a) including an exhaust gas inlet side end is different from the Pt/Rh mass ratio in a downstream portion (65 b) including an exhaust gas outlet side end, and the Pt/Rh mass ratio in the upstream portion (65a) is higher than the Pt/Rh mass ratio in the downstream portion (65b). The Pt/Rh mass ratio is a mass ratio of platinum to rhodium.
摘要:
The oxidation catalyst for exhaust gas purification provided by the present invention includes a support supporting a noble metal that catalyzes the oxidation of carbon monoxide (CO). The support is mainly constituted by a composite metal oxide including, in terms of oxides, Al and Zr, or Al, Zr and Ti at the following mass ratios: Al 2 O 3 40 to 99% by mass, ZrO 2 1 to 45% by mass, and TiO 2 0 to 15% by mass.
摘要翻译:本发明提供的废气净化用氧化催化剂含有负载催化氧化一氧化碳(CO)的贵金属的载体。 该载体主要由以氧化物Al和Zr或Al,Zr和Ti以以下质量比组成的复合金属氧化物构成:Al 2 O 3为40〜99质量%,ZrO 2为1〜45质量% ,TiO 2为0〜15质量%。
摘要:
Provided is an exhaust gas purification catalyst in which exhaust gas can be purified more effectively in regard to carbon monoxide, even when an engine is started up, or under other low-temperature conditions. This exhaust gas purification catalyst has a substrate (10), an oxidation catalyst layer (20) arranged on the substrate, and an adsorption layer (30) arranged on the oxidation catalyst layer. The oxidation catalyst layer has support particles and a noble metal supported by the support particles, the density of the noble metal supported in the oxidation catalyst layer being greater than the density of the noble metal supported in the adsorption layer. The adsorption layer has hydrocarbon adsorbent particles, the hydrocarbon adsorbent particle content of the adsorption layer being higher than the hydrocarbon adsorbent particle content of the oxidation catalyst layer.
摘要:
The present invention provides an exhaust gas purification catalyst which has a structure which prevents competitive adsorption of HC, CO, and NO X and enables effective utilization of an NO X storage reduction type catalyst. The exhaust gas purification catalyst of the present invention is characterized by having an NO X storage reduction type catalyst layer which contains at least one type of NO X storage material which is selected from an alkali metal or an alkali earth metal and Pt and/or Rh on a substrate and having an oxidation catalyst layer which carries Pt and/or Pd on the NO X storage reduction type catalyst layer.
摘要:
An exhaust gas purification system includes: a catalyst (3) provided in an exhaust gas passage of an internal combustion engiue (1) and having a carrier containing a basic oxide and platinum carried on the carrier; a catalyst (4) for purifying NOx; and oxygen supply means (2).