摘要:
Disclosed is a lithium manganese (Mn)-based oxide including Mn as an essential transition metal and having a layered crystal structure, in which the amount of Mn is greater than that of other transition metal(s), the lithium manganese-based oxide exhibits flat level section characteristics in which release of oxygen occurs together with lithium deintercalation during first charging in a high voltage range of 4.4 V or higher, and at least one of a transition metal layer including Mn and an oxygen layer is substituted or doped with a pillar element.
摘要:
Disclosed are a cathode active material and a lithium secondary battery including the same, and a method of manufacturing the cathode active material, the method including: (a) manufacturing a lithium metal oxide according to formula 1 below:
Li 1+z Ni a Mn b Co 1-(a+b) O2 (1)
wherein 0≤z≤0.1, 0.1≤a≤0.8, 0.1≤b≤0.8 and a+b (b) dry mixing the lithium metal oxide, and a precursor including zirconium and fluorine; and (c) changing the precursor including zirconium and fluorine into ZrO 2 and substituting some of oxygen (O) anions with F by heat-treatment after dry mixing of step (b), wherein the cathode active material is coated with ZrO 2 and F.
摘要翻译:公开了一种正极活性物质和包含该正极活性物质的锂二次电池及其制造方法,所述方法包括:(a)制备下式1的锂金属氧化物:€ƒ€ƒ€ ƒ€ƒ€ƒ€ƒ€ƒLi1 + z Ni a Mn b Co 1-(a + b)O2€ƒ€ƒ€ƒ€ƒ(1)其中0‰¤‰¤0.1,0.1‰¤ a‰¤0.8,0.1‰¤b‰¤0.8和a + b <1; (b)将锂金属氧化物和包含锆和氟的前体干混; 和(c)通过步骤(b)的干混后,通过热处理将包含锆和氟的前体改变成ZrO 2并用F代替一些氧(O)阴离子,其中正极活性材料涂覆有ZrO 2和F 。
摘要:
Provided are a lithium secondary battery including a cathode, an anode, a separator, and a gel polymer electrolyte, wherein the gel polymer electrolyte includes an acrylate-based polymer and a charge voltage of the battery is in a range of 4.3 V to 5.0 V, and a method of preparing the lithium secondary battery. A high-voltage lithium secondary battery of the present invention has excellent capacity characteristics at a high voltage of 4.3 V or more.
摘要:
The present invention provides a LiCoO2-containing powder comprising LiCoO2 having a stoichiometric composition via heat treatment of a lithium cobalt oxide and a lithium buffer material to make equilibrium of a lithium chemical potential therebetween; a lithium buffer material which acts as a Li acceptor or a Li donor to remove or supplement Li-excess or Li-deficiency, coexisting with a stoichiometric lithium metal oxide; and a method for preparing a LiCoO2-containing powder. Further, provided is an electrode comprising the above-mentioned LiCoO2-containing powder as an active material, and a rechargeable battery comprising the same electrode. The present invention enables production of a LiCoO2electrode active material which has improved high-temperature storage properties and high-voltage cycling properties, and is robust in composition fluctuation in the production process. Therefore, the present invention provides advantages such as reduction of time and labor required for quality control and process management in the mass-production of the electrode active material, and decreased production costs of LiCoO2.
摘要:
The present invention relates to a positive electrode active material for a lithium secondary battery and a method of preparing the positive electrode active material.
摘要:
The present invention relates to a method of preparing a positive electrode active material precursor for a lithium secondary battery in which particle size uniformity and productivity may be improved by using three reactors, a method of preparing a positive electrode active material for a lithium secondary battery by using the above-prepared positive electrode active material precursor for a lithium secondary battery, and a positive electrode for a lithium secondary battery and a lithium secondary battery which include the above-prepared positive electrode active material for a lithium secondary battery.
摘要:
The present invention provides a positive electrode active material for a secondary battery including: a lithium complex transition metal oxide which contains nickel (Ni) and cobalt (Co), and contains at least one selected from the group consisting of manganese (Mn) and aluminum (Al); and a composite coating portion which is formed on a surface of the lithium complex transition metal oxide, wherein the lithium complex transition metal oxide has a nickel (Ni) content of 65 mol% or more with respect to the total transition metal content, and the composite coating portion contains cobalt (Co) and boron (B), and contains at least one selected from the group consisting of lanthanum (La), titanium (Ti), and aluminum (Al).
摘要:
Provided is a cathode active material including a complex coating layer, which includes M below, formed on a surface of the cathode active material through reaction of a lithium transition metal oxide represented by Formula 1 below with a coating precursor: €ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒLi x MO 2 €ƒ€ƒ€ƒ€ƒ€ƒ(1) wherein M is represented by Mn a M' 1-b , M' is at least one selected from the group consisting of Al, Mg, Ni, Co, Cr, V, Fe, Cu, Zn, Ti and B, 0.95‰¤x‰¤1.5, and 0.5‰¤a‰¤1. The lithium secondary battery including the cathode active material exhibits improved lifespan and rate characteristics due to superior stability.
摘要:
The present invention provides a positive electrode active material for a lithium secondary battery including a core including first lithium cobalt oxide, and a surface modifying layer positioned on a surface of the core. The surface modifying layer includes a lithium compound discontinuously distributed on the surface of the core, and second lithium cobalt oxide distributed while making a contact with or adjacent to the lithium compound, with a Li/Co molar ratio of less than 1. The lithium compound includes at least one lithium reactive element selected from the group consisting of Ti, W, Zr, Mn, Mg, P, Ni, Al, Sn, V, Cr, and Mo. The positive electrode active material according to the present invention forms a lithium deficient structure in the positive electrode active material of lithium cobalt oxide and changes two-dimensional lithium transport path into three-dimensional path. The transport rate of lithium ions may increase when applied to a battery, thereby illustrating improved capacity and rate characteristic without decreasing initial capacity. As a result, the positive electrode active material may be useful as a positive electrode active material of a battery for a high voltage with 4.4 V or more.