摘要:
An upstream catalyst (3) and a downstream catalyst (4) are disposed in an exhaust passage (2) of an engine (1). The downstream catalyst (4) contains in the same catalyst layer thereof Rh-doped CeZrNd mixed oxide particles on which Rh is supported and active alumina particles on which Pt is supported. The upstream catalyst (3) is a three-way catalyst containing an oxygen storage component having a lower oxygen storage capacity than the Rh-doped CeZrNd mixed oxide.
摘要:
An upstream catalyst (3) and a downstream catalyst (4) are disposed in an exhaust passage (2) of an engine (1). The downstream catalyst (4) contains in the same catalyst layer thereof Rh-doped CeZrNd mixed oxide particles on which Rh is supported and active alumina particles on which Pt is supported. The upstream catalyst (3) is a three-way catalyst containing an oxygen storage component having a lower oxygen storage capacity than the Rh-doped CeZrNd mixed oxide.
摘要:
In an exhaust gas purification catalyst, particles (12) of a catalytic metal-doped, Ce-Zr-based second mixed oxide are carried on the surfaces of particles (11) of a Ce-Zr-based first mixed oxide. The second mixed oxide contains Ce and Zr as metals forming its constituents. Catalytic metal atoms (13) are placed at least one of at and between crystal lattice points of the second mixed oxide. The first mixed oxide contains Ce and Zr as metals forming its constituents but no catalytic metal. Thus, the concentration of catalytic metal on the surfaces of catalyst particles is increased.
摘要:
An exhaust gas purifying system includes an exhaust gas purifying catalyst (14) having a nitrogen oxide absorbing material which is installed in an exhaust line (13) of an engine (1) and performs split fuel injection to inject fuel directly into each combustion chamber (5) partly during a suction stroke and partly during a compression stroke to provide and supply an increased amount of carbon monoxide to the nitrogen oxide absorbing material so as thereby to desorb sulfur oxides from the nitrogen oxide absorbing material.
摘要:
A catalyst layer (2) includes: a first mixed oxide particle component (4) which contains Ce and Rh (8) and in which Rh is partially exposed at particle surfaces; and a second mixed oxide particle component (5) containing Ce, Zr, and a rare earth metal except Ce. The particle size distribution of the first mixed oxide particle component (4) has a peak in the particle size range from 100 nm to 300 nm, both inclusive. The particle size distribution of the second mixed oxide particle component (5) has a peak in a particle size range larger than the particle size range in which the first mixed oxide particle component (4) has the peak. At least part of particles of the first mixed oxide particle component (4) is attached to at least part of particles of the second mixed oxide particle component (5).
摘要:
An exhaust gas purification catalyst includes a catalyst layer (2) formed on a support (1). The catalyst layer (2) contains Ce-containing oxide particles (3) having an oxygen storage/release capacity and a catalytic metal (5). The catalyst layer (2) further contains a large number of iron oxide particles (4) of 300 nm diameter or less that are dispersed therein and are in contact with the Ce-containing oxide particles (3). When observed by electron microscopy, the proportion of the area of iron oxide particles (4) of 300 nm diameter or less to the total area of all of iron oxide particles in the catalyst layer (2) is 30% or more.
摘要:
An exhaust gas purifying system and a catalyst (14,31) used for the system prevents NOx absorbent from being poisoned by a sulphur compound to keep NOx absorption performance. The catalyst has at least an inner (26) and an outer layer (28,29) on a support material (25), the inner layer having NOx absorbent capable of absorbing NOx and a sulphur compound in the exhaust gas produced from combustion of a lean fuel mixture, releasing the NOx into the exhaust gas and substantially stopping absorbing the sulphur compound when a rich mixture is burnt, and the outer layer having a sulphur compound absorbent capable of absorbing the sulphur compound in the exhaust gas produced from combustion of a lean fuel mixture and capable of discharging the sulphur compound into the exhaust gas when a rich fuel mixture is burnt while the engine operates in a lean-burn zone. NOx is absorbed by the NOx absorbent in the inner layer and the sulphur compound is absorbed in the sulphur compound absorbent in the outer layer. Therefore the NOx absorbent in the inner layer is protected from being poisoned by the sulphur compound.
摘要:
An exhaust gas purifying system includes an exhaust gas purifying catalyst (14) having a nitrogen oxide absorbing material which is installed in an exhaust line (13) of an engine (1) and performs split fuel injection to inject fuel directly into each combustion chamber (5) partly during a suction stroke and partly during a compression stroke to provide and supply an increased amount of carbon monoxide to the nitrogen oxide absorbing material so as thereby to desorb sulfur oxides from the nitrogen oxide absorbing material.