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    Thermoplastic resin composition and injection molded article thereof
    11.
    发明公开
    Thermoplastic resin composition and injection molded article thereof 失效
    Thermoplastische Harzzusammensetzung und Spritzgussformteil daraus

    公开(公告)号：EP0739943A1

    公开(公告)日：1996-10-30

    申请号：EP96106781.6

    申请日：1996-04-29

    申请人： SUMITOMO CHEMICAL COMPANY LIMITED ,  TOYOTA JIDOSHA KABUSHIKI KAISHA

    发明人： Sadatoshi, Hajime ,  Ohkawa, Kenichi ,  Doi, Teruhiko ,  Miyake, Yuichi ,  Nomura, Takao ,  Nishio, Takeyoshi

    IPC分类号： C08L53/00 ,  C08K7/08 ,  C08K3/34

    CPC分类号： C08L53/00 ,  C08L2666/04

    摘要： A thermoplastic resin composition which has a melt flow rate of 20 to 30 g/10 min and a flexural modulus at 23°C of 30,000 kg/cm 2 or more and which comprises (A) 60 to 75% by weight of a specific crystalline polypropylene in which the propylene homopolymer portion has a Q value of 3.0 to 5.0, an isotactic pentad fraction of 0.975 or more and an intrinsic viscosity [η] of 0.95 to 1.15 dl/g as measured at 135°C in tetralin, (B) 2 to 8% by weight of an ethylene-butene-1 copolymer rubber, (C) 2 to 8% by weight of an ethylene-propylene copolymer rubber, (D) 10 to 20% by weight of talc having an average particle diameter of 4 µm or less, and (E) 5 to 20% by weight of fibrous magnesium oxysulfate, and an injection molded article of the thermoplastic resin composition, said thermoplastic resin composition satisfying the impact strength and rigidity required as a material for an instrumental panel and having a short molding cycle and good surface quality.

    摘要翻译： 一种热塑性树脂组合物，其熔体流动速率为20至30g / 10min，在23℃下的挠曲模量为30,000kg / cm 2或更高，并且包含（A）60至75重量％的 其中丙烯均聚物部分的Q值为3.0〜5.0，在135℃下在四氢化萘中测定的0.975以上的特性粘度ÄetaÜ等于或等于0.95〜1.15dl / g， B）2-8重量％的乙烯 - 丁烯-1共聚物橡胶，（C）2-8重量％的乙烯 - 丙烯共聚物橡胶，（D）10至20重量％的具有平均颗粒的滑石 直径为4μm以下，（E）为5〜20重量％的纤维状氧硫酸镁，以及热塑性树脂组合物的注射成型品，所述热塑性树脂组合物满足冲击强度和刚性所需的刚性 仪器面板，成型周期短，表面质量好。

    Thermoplastic resin composition and injection molded article thereof
    12.
    发明公开
    Thermoplastic resin composition and injection molded article thereof 失效
    Thermoplastische Harzmasse und daraus hergestellter Spritzgussartikel

    公开(公告)号：EP0739940A2

    公开(公告)日：1996-10-30

    申请号：EP96106783.2

    申请日：1996-04-29

    申请人： SUMITOMO CHEMICAL COMPANY LIMITED ,  TOYOTA JIDOSHA KABUSHIKI KAISHA

    发明人： Sadatoshi, Hajime ,  Ohkawa, Kenichi ,  Doi, Teruhiko ,  Miyake, Yuichi ,  Nomura, Takao ,  Nishio, Takeyoshi

    IPC分类号： C08L23/12

    CPC分类号： C08L23/12 ,  C08K3/34 ,  C08L23/0815 ,  C08L23/10 ,  C08L23/16 ,  C08L53/00 ,  C08L53/02 ,  C08L2205/03 ,  C08L2205/035 ,  C08L2666/02 ,  C08L2666/04

    摘要： A thermoplastic resin composition which has a melt flow rate of 25 to 30 g/10 min and a flexural modulus at 23°C of 20,000 kg/cm 2 or more and which comprises (1) 78 to 87% by weight of a specific crystalline polypropylene [referred to hereinafter as (A)] in which the propylene homopolymer portion has a Q value of 3.0 to 5.0, an isotactic pentad fraction of 0.975 or more and an intrinsic viscosity [η] of 1.00 to 1.10 dl/g as measured at 135°C in tetralin, (2) 3 to 10% by weight of at least two specific rubber components selected from the group consisting of (B) 1 to 9% by weight of an ethylene-butene-1 copolymer rubber, (C) 1 to 9% by weight of an ethylene-propylene copolymer rubber and (D) 1 to 9% by weight of an alkenyl aromatic compound-containing rubber; and (3) 10 to 12% by weight of talc having an average particle diameter of 4 µm or less, and an injection molded article of the thermoplastic resin composition, said thermoplastic resin composition satisfying the impact strength and rigidity required as a material for an interior automotive trim and having a short molding cycle and good surface quality.

    摘要翻译： 一种热塑性树脂组合物，其熔体流动速率为25〜30g / 10min，在23℃下的弯曲弹性模量为20,000kg / cm 2以上，其中，（1）78〜87重量％ 其中丙烯均聚物部分的Q值为3.0〜5.0，全同立构五单元组分数为0.975以上，特性粘度ÄetaÜ为1.00〜1.10dl / g，测定时为（A）Ü （2）3至10重量％的至少两种选自（B）1至9重量％的乙烯 - 丁烯-1共聚物橡胶的特定橡胶组分，（C ）1〜9重量％的乙烯 - 丙烯共聚物橡胶和（D）1〜9重量％的含烯基芳香族化合物的橡胶; 和（3）10〜12重量％的平均粒径为4μm以下的滑石和热塑性树脂组合物的注射成型品，所述热塑性树脂组合物满足作为材料的材料所需的冲击强度和刚性 内部汽车装饰件，具有短的成型周期和良好的表面质量。

    Thermoplastic polymer composition
    14.
    发明公开
    Thermoplastic polymer composition 失效
    热塑性聚合物组合物

    公开(公告)号：EP0496625A3

    公开(公告)日：1993-02-17

    申请号：EP92300596.1

    申请日：1992-01-23

    申请人： MITSUBISHI CHEMICAL CORPORATION ,  TOYOTA JIDOSHA KABUSHIKI KAISHA

    发明人： Nishio, Takeyoshi ,  Kawamura, Nobuya ,  Nomura, Takao ,  Sato, Hiroki, c/o Mitsubishi Petrochem. Co., Ltd. ,  Uchikawa, Akihiko, c/o Mitsubishi Petrochem. Co., ,  Tsutsumi, Ikuo, c/o Mitsubishi Petrochem. Co., ,  Goto, Yukitaka, c/o Mitsubishi Petrochem. Co.,

    IPC分类号： C08L23/10 ,  C08L23/16 ,  C08L23/08 ,  C08K3/34

    CPC分类号： C08L23/04 ,  C08K3/34 ,  C08L23/0815 ,  C08L23/10 ,  C08L23/142 ,  C08L23/16 ,  C08L2205/03 ,  C08L2666/04 ,  C08L2666/02

    摘要： A thermoplaslic polymer composition comprising:
    (i) 100 parts by weight of a thermoplastic polymer component which comprises an ethylene-propylene rubber, an ethylene copolymer and a propylene polymer (including an ethylene-propylene block copolymer), and (ii) 7 to 25 parts by weight of talc, the thermoplastic polymer component being composed of, according to fractionation using o-dichlorobenzene as a solvent, component (A) which is a component soluble in the solvent at 40°C, component (B) which is a component insoluble in the solvent at 40°C but soluble at 110°C, and component (C) which is a component insoluble in the solvent even at 110°C in such a proportion that the total amount of the components (A) and (B) is from 50 to 70 parts by weight, the weight ratio of the component (A) to the component (B) being from 0.5 to 1.5, and the amount of the component (C) is from 50 to 30 parts by weight; said composition having a flexural modulus of 10,000 to 20,000 kg/cm².

    摘要翻译： 一种热塑性聚合物组合物，其包含：（i）100重量份包含乙烯 - 丙烯橡胶，乙烯共聚物和丙烯聚合物（包括乙烯 - 丙烯嵌段共聚物）的热塑性聚合物组分，和（ii）7-25 重量份的滑石组成，热塑性聚合物组分由根据使用邻二氯苯作为溶剂进行分级分离而成的组分（A），所述组分（A）是可溶于40℃的溶剂中的组分，作为组分（B）的组分 在40℃下不溶于溶剂但在110℃可溶，作为不溶于溶剂的组分（C），即使在110℃下也不溶于组分（C），组分（A）和（B）的总量 ）为50至70重量份，组分（A）与组分（B）的重量比为0.5至1.5，组分（C）的量为50至30重量份; 所述组合物具有10,000至20,000kg / cm 2的挠曲模量。

    Thermoplastic resin composition
    15.
    发明公开
    Thermoplastic resin composition 失效
    Thermoplastische Harzzusammensetzung。

    公开(公告)号：EP0335394A2

    公开(公告)日：1989-10-04

    申请号：EP89105627.7

    申请日：1989-03-30

    申请人： SUMITOMO CHEMICAL COMPANY, LIMITED ,  TOYOTA JIDOSHA KABUSHIKI KAISHA

    发明人： Okada, Takayuki ,  Mitsuno, Tatsuyuki ,  Fujii, Takeshi ,  Yamaguchi, Kentaro ,  Okada, Mitsuyuki ,  Tsuji, Mitsuji ,  Nishio, Takeyoshi ,  Yokoi, Toshio ,  Nomura, Takao

    IPC分类号： C08L51/06 ,  C08L23/12 ,  C08L67/00 ,  C08L63/00 ,  C08L23/16 ,  C08L51/00

    CPC分类号： C08L23/10 ,  C08K7/14 ,  C08L23/0884 ,  C08L23/12 ,  C08L23/16 ,  C08L51/06 ,  C08L53/00 ,  C08L63/00 ,  C08L67/00 ,  C08L67/02 ,  C08L2205/03 ,  C08L2205/035 ,  C08L2666/24 ,  C08L2666/18 ,  C08L2666/06 ,  C08L2666/02

    摘要： There is disclosed a thermoplastic resin composition comprising a blend of

    100 parts by weight of a resin composition composed of 1 to 99% by weight of a polypropylene type resin (C) selected from the group consisting of a modified polypropylene (A) obtained by graft copolymerizing an unsaturated carboxylic acid or a derivative thereof and an unsaturated aroamtic monomer onto polypropylene, and a composition composed of the modified polypropylene (A) and a polypropylene (B), and 99 to 1% by weight of at least one sturated polyester resin (D),
    0.1 to 300 parts by weiht of an epoxy group containing copolymer (E),
    0.1 to 300 parts by weight of a modified ethylenic copolymer ruber (F) obtained by graft copolymerizing and an unsaturated carboxylic acid or a derivative thereof and an unsaturated aromatic monomer onto ethylenic copolymer ruber, and
    Up to 5 partsg by weight of a basic comdpound (G) optionally added as reaction accelerator, the content of the saturted polyester resin in the thermoplastic polyeste4r resin being less than 50% by weight.

    The thermoplastic resin composition of the present invention has high heat resistance and high impact resistance. in particular, high low-temperatuer impact resistance and is advantgeously used in automobilde parts, electric and electronic parts, etc.

    摘要翻译： 公开了一种热塑性树脂组合物，其包含100重量份的由1至99重量％的聚丙烯类树脂（C）组成的树脂组合物的混合物，所述聚丙烯类树脂（C）选自由接枝获得的改性聚丙烯（A） 将不饱和羧酸或其衍生物和不饱和芳族单体共聚到聚丙烯上，以及由改性聚丙烯（A）和聚丙烯（B）组成的组合物和99至1重量％的至少一种饱和聚酯树脂（ D）0.1〜300份，含有环氧基共聚物（E）0.1〜300份，接枝共聚得到的改性乙烯类共聚物（F）0.1〜300重量份，不饱和羧酸或其衍生物和不饱和羧酸衍生物 芳族单体加入到乙烯共聚物中，最多加入5重量份作为反应促进剂的碱性化合物（G），饱和聚酯树脂的含量 塑性聚酯树脂小于50重量％。 本发明的热塑性树脂组合物具有高耐热性和高抗冲击性，特别是低耐温冲击性，并且有利地用于汽车零件，电气和电子零件等。

    Polypropylene resin composition
    17.
    发明公开
    Polypropylene resin composition 审中-公开
    聚丙烯树脂组合物

    公开(公告)号：EP0926195A1

    公开(公告)日：1999-06-30

    申请号：EP98124590.5

    申请日：1998-12-23

    申请人： Japan Polychem Corporation ,  TOYOTA JIDOSHA KABUSHIKI KAISHA

    发明人： Iwanami, Kunio, c/o Japan Polychem Corp. ,  Kobayashi, Akira, c/o Japan Polychem Corp. ,  Murayama, Mitsuhiro, c/o Japan Polychem Corp. ,  Fujita, Yuji, c/o Japan Polychem Corp. ,  Nagai, Takayuki ,  Nomura, Takao ,  Matsuda, Masatoshi ,  Kito, Osamu ,  Iwai, Hisayuki

    IPC分类号： C08L53/02 ,  C08L53/00 ,  C08K3/34

    CPC分类号： C08L53/00 ,  C08L53/02 ,  C08L53/025 ,  C08L2666/24

    摘要： This invention provides polypropylene resin compositions exhibiting a strongly improved balance of physical properties in comparison to related polypropylene materials. The materials can be used in both interior and exterior parts of automobiles, have excellent thin-wall moldability and can effectively reduce generation of flow marks. Particularly, it provides a polypropylene resin composition which comprises specified amounts of (A) a specific ethylene-propylene block copolymer, (B) a specific thermoplastic elastomer and (C) talc, wherein it has specified values of physical properties measured by ASTM and has a degree of b-axis orientation of 720 or more which is calculated from the ratio of differential peak intensities measured by wide-angle X-ray diffraction of the central area of an ASTM No. 1 dumbbell prepared by injection molding.

    摘要翻译： 与有关的聚丙烯材料相比，本发明提供了聚丙烯树脂组合物，其物理性能的平衡显着改善。 该材料可用于汽车内外部件，具有优异的薄壁成型性，可有效减少流痕的产生。 特别是提供含有特定量的（A）特定的乙烯 - 丙烯嵌段共聚物，（B）特定的热塑性弹性体和（C）滑石的聚丙烯树脂组合物，其特征在于， 根据通过注射成型制备的ASTM 1号哑铃的中心区域的广角X射线衍射测量的差分峰值强度的比率计算720或更高的b轴取向度。