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公开(公告)号：EP0335394A2
公开(公告)日：1989-10-04
申请号：EP89105627.7
申请日：1989-03-30
发明人： Okada, Takayuki , Mitsuno, Tatsuyuki , Fujii, Takeshi , Yamaguchi, Kentaro , Okada, Mitsuyuki , Tsuji, Mitsuji , Nishio, Takeyoshi , Yokoi, Toshio , Nomura, Takao
CPC分类号： C08L23/10 , C08K7/14 , C08L23/0884 , C08L23/12 , C08L23/16 , C08L51/06 , C08L53/00 , C08L63/00 , C08L67/00 , C08L67/02 , C08L2205/03 , C08L2205/035 , C08L2666/24 , C08L2666/18 , C08L2666/06 , C08L2666/02
摘要： There is disclosed a thermoplastic resin composition comprising a blend of
100 parts by weight of a resin composition composed of 1 to 99% by weight of a polypropylene type resin (C) selected from the group consisting of a modified polypropylene (A) obtained by graft copolymerizing an unsaturated carboxylic acid or a derivative thereof and an unsaturated aroamtic monomer onto polypropylene, and a composition composed of the modified polypropylene (A) and a polypropylene (B), and 99 to 1% by weight of at least one sturated polyester resin (D),
0.1 to 300 parts by weiht of an epoxy group containing copolymer (E),
0.1 to 300 parts by weight of a modified ethylenic copolymer ruber (F) obtained by graft copolymerizing and an unsaturated carboxylic acid or a derivative thereof and an unsaturated aromatic monomer onto ethylenic copolymer ruber, and
Up to 5 partsg by weight of a basic comdpound (G) optionally added as reaction accelerator, the content of the saturted polyester resin in the thermoplastic polyeste4r resin being less than 50% by weight.
The thermoplastic resin composition of the present invention has high heat resistance and high impact resistance. in particular, high low-temperatuer impact resistance and is advantgeously used in automobilde parts, electric and electronic parts, etc.摘要翻译： 公开了一种热塑性树脂组合物，其包含100重量份的由1至99重量％的聚丙烯类树脂（C）组成的树脂组合物的混合物，所述聚丙烯类树脂（C）选自由接枝获得的改性聚丙烯（A） 将不饱和羧酸或其衍生物和不饱和芳族单体共聚到聚丙烯上，以及由改性聚丙烯（A）和聚丙烯（B）组成的组合物和99至1重量％的至少一种饱和聚酯树脂（ D）0.1〜300份，含有环氧基共聚物（E）0.1〜300份，接枝共聚得到的改性乙烯类共聚物（F）0.1〜300重量份，不饱和羧酸或其衍生物和不饱和羧酸衍生物 芳族单体加入到乙烯共聚物中，最多加入5重量份作为反应促进剂的碱性化合物（G），饱和聚酯树脂的含量 塑性聚酯树脂小于50重量％。 本发明的热塑性树脂组合物具有高耐热性和高抗冲击性，特别是低耐温冲击性，并且有利地用于汽车零件，电气和电子零件等。
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公开(公告)号：EP1580230A2
公开(公告)日：2005-09-28
申请号：EP05005962.5
申请日：2005-03-18
发明人： Doi, Kazuhiro, Mitsui Chemicals, Inc. , Sakai, Ikunori, Mitsui Chemicals, Inc. , Nagai, Takayuki, Toyota Jidosha K.K. , Sekito, Takeshi, Toyota Jidosha K.K. , Kanzaki, Susumu , Tsuji, Mitsuji
IPC分类号： C08L23/10
CPC分类号： C08L53/00 , C08F110/06 , C08F210/06 , C08F255/02 , C08L23/0815 , C08L23/10 , C08L23/16 , C08L23/30 , C08L51/06 , C08L53/02 , C08L53/025 , C08L2666/24 , C08L2666/02 , C08L2666/06 , C08L2666/26 , C08L51/00 , C08F2500/15 , C08F2500/12 , C08F210/16
摘要： A polypropylene resin composition comprises (A) (a-1) a specific crystalline propylene/ethylene block copolymer or (a-3) a polymer mixture comprising the (a-1) and (a-2) a specific crystalline propylene homopolymer in specific ratio, in an amount of 5 to 56% by weight, (B) a hydroxyl group-containing polypropylene having an intrinsic viscosity [η] of 0.8 to 2.0 dl/g and a melting point of 150 to 168°C, in an amount of 10 to 45% by weight, (C) a copolymer rubber of ethylene and an α-olefin having a melt flow rate (ASTM D-1238, 230°C, load of 2160 g) of 0.5 to 15 g/10 min, in an amount of 18 to 25% by weight, (D) a hydrogenation product of a block copolymer containing a polymer block of a monovinyl-substituted aromatic hydrocarbon compound and a polymer block of a conjugated diene compound, in an amount of 1 to 10% by weight, and (E) an inorganic filler in an amount of 15 to 25% by weight, the total amount of said components (A), (B), (C), (D) and (E) being 100% by weight, hydroxyl group-containing monomer units derived from the hydroxyl group-containing polypropylene (B) being contained in amounts of 1.3 to 4.0% by weight in 100% by weight of the polypropylene resin composition. The polypropylene resin composition exhibits excellent coating adhesion properties and has excellent processability and mechanical strength with a good balance.
摘要翻译： 一种聚丙烯树脂组合物，包含（a）（a-1）特定结晶丙烯/乙烯嵌段共聚物或（a-3）包含（a-1）和（a-2）特定结晶丙烯均聚物的聚合物混合物 （B）特性粘度[η]为0.8〜2.0dl / g，熔点为150〜168℃的含羟基聚丙烯，其含量为5〜56重量％ 为10〜45重量％的（C）乙烯与α-烯烃的共聚物橡胶，其熔体流动速率（ASTM D-1238,230℃，2160g负荷）为0.5〜15g / 10分钟， （D）含有1〜10重量份的单乙烯基取代芳香族烃化合物的聚合物嵌段和共轭二烯化合物的聚合物嵌段的嵌段共聚物的氢化物，其含量为18〜25重量％ （E）无机填充剂15〜25重量％，上述成分（A），（B），（C），（D）和（E）的总量为100重量％ 羟基g 在100重量％聚丙烯树脂组合物中，含羟基聚丙烯（B）的含有单体单元的含量为1.3〜4.0重量％。 该聚丙烯树脂组合物表现出优异的涂层粘合性能，并具有优良的加工性和机械强度以及良好的平衡。
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公开(公告)号：EP1580230B1
公开(公告)日：2008-04-23
申请号：EP05005962.5
申请日：2005-03-18
发明人： Doi, Kazuhiro, Mitsui Chemicals, Inc. , Sakai, Ikunori, Mitsui Chemicals, Inc. , Nagai, Takayuki, Toyota Jidosha K.K. , Sekito, Takeshi, Toyota Jidosha K.K. , Kanzaki, Susumu , Tsuji, Mitsuji
IPC分类号： C08L51/06
CPC分类号： C08L53/00 , C08F110/06 , C08F210/06 , C08F255/02 , C08L23/0815 , C08L23/10 , C08L23/16 , C08L23/30 , C08L51/06 , C08L53/02 , C08L53/025 , C08L2666/24 , C08L2666/02 , C08L2666/06 , C08L2666/26 , C08L51/00 , C08F2500/15 , C08F2500/12 , C08F210/16
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公开(公告)号：EP0335394B1
公开(公告)日：1993-11-10
申请号：EP89105627.7
申请日：1989-03-30
发明人： Okada, Takayuki , Mitsuno, Tatsuyuki , Fujii, Takeshi , Yamaguchi, Kentaro , Okada, Mitsuyuki , Tsuji, Mitsuji , Nishio, Takeyoshi , Yokoi, Toshio , Nomura, Takao
CPC分类号： C08L23/10 , C08K7/14 , C08L23/0884 , C08L23/12 , C08L23/16 , C08L51/06 , C08L53/00 , C08L63/00 , C08L67/00 , C08L67/02 , C08L2205/03 , C08L2205/035 , C08L2666/24 , C08L2666/18 , C08L2666/06 , C08L2666/02
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公开(公告)号：EP1580230A3
公开(公告)日：2005-11-16
申请号：EP05005962.5
申请日：2005-03-18
发明人： Doi, Kazuhiro, Mitsui Chemicals, Inc. , Sakai, Ikunori, Mitsui Chemicals, Inc. , Nagai, Takayuki, Toyota Jidosha K.K. , Sekito, Takeshi, Toyota Jidosha K.K. , Kanzaki, Susumu , Tsuji, Mitsuji
IPC分类号： C08L51/06
CPC分类号： C08L53/00 , C08F110/06 , C08F210/06 , C08F255/02 , C08L23/0815 , C08L23/10 , C08L23/16 , C08L23/30 , C08L51/06 , C08L53/02 , C08L53/025 , C08L2666/24 , C08L2666/02 , C08L2666/06 , C08L2666/26 , C08L51/00 , C08F2500/15 , C08F2500/12 , C08F210/16
摘要： A polypropylene resin composition comprises (A) (a-1) a specific crystalline propylene/ethylene block copolymer or (a-3) a polymer mixture comprising the (a-1) and (a-2) a specific crystalline propylene homopolymer in specific ratio, in an amount of 5 to 56% by weight, (B) a hydroxyl group-containing polypropylene having an intrinsic viscosity [η] of 0.8 to 2.0 dl/g and a melting point of 150 to 168°C, in an amount of 10 to 45% by weight, (C) a copolymer rubber of ethylene and an α-olefin having a melt flow rate (ASTM D-1238, 230°C, load of 2160 g) of 0.5 to 15 g/10 min, in an amount of 18 to 25% by weight, (D) a hydrogenation product of a block copolymer containing a polymer block of a monovinyl-substituted aromatic hydrocarbon compound and a polymer block of a conjugated diene compound, in an amount of 1 to 10% by weight, and (E) an inorganic filler in an amount of 15 to 25% by weight, the total amount of said components (A), (B), (C), (D) and (E) being 100% by weight, hydroxyl group-containing monomer units derived from the hydroxyl group-containing polypropylene (B) being contained in amounts of 1.3 to 4.0% by weight in 100% by weight of the polypropylene resin composition. The polypropylene resin composition exhibits excellent coating adhesion properties and has excellent processability and mechanical strength with a good balance.
摘要翻译： 聚丙烯树脂组合物包含（A）（a-1）特定结晶丙烯/乙烯嵌段共聚物或（a-3）包含（a-1）和（a-2）特定结晶丙烯均聚物的聚合物混合物 的比例为5〜56重量％，（B）特性粘度Äeta为0.8〜2.0dl / g，熔点为150〜168℃的含羟基的聚丙烯，其量为 为10〜45重量％，（C）乙烯和熔体流动速率（ASTM D-1238,230℃，2160g载荷）为α-烯烃的共聚物橡胶为0.5〜15g / 10分钟， （D）含有单乙烯基取代的芳族烃化合物的聚合物嵌段和共轭二烯化合物的聚合物嵌段的嵌段共聚物的加氢产物的量为1至10重量％ （A），（B），（C），（D）和（E）的总量为100重量％，（E）无机填料的量为15〜25重量％ 由wei 含有羟基的聚丙烯（B）的含羟基的单体单元的含量为聚丙烯树脂组合物100重量％中的1.3〜4.0重量％。 聚丙烯树脂组合物表现出优异的涂料粘合性能，并且具有优异的加工性能和机械强度，并具有良好的平衡。
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公开(公告)号：EP0335394A3
公开(公告)日：1990-12-05
申请号：EP89105627.7
申请日：1989-03-30
发明人： Okada, Takayuki , Mitsuno, Tatsuyuki , Fujii, Takeshi , Yamaguchi, Kentaro , Okada, Mitsuyuki , Tsuji, Mitsuji , Nishio, Takeyoshi , Yokoi, Toshio , Nomura, Takao
CPC分类号： C08L23/10 , C08K7/14 , C08L23/0884 , C08L23/12 , C08L23/16 , C08L51/06 , C08L53/00 , C08L63/00 , C08L67/00 , C08L67/02 , C08L2205/03 , C08L2205/035 , C08L2666/24 , C08L2666/18 , C08L2666/06 , C08L2666/02
摘要： There is disclosed a thermoplastic resin composition comprising a blend of
100 parts by weight of a resin composition composed of 1 to 99% by weight of a polypropylene type resin (C) selected from the group consisting of a modified polypropylene (A) obtained by graft copolymerizing an unsaturated carboxylic acid or a derivative thereof and an unsaturated aroamtic monomer onto polypropylene, and a composition composed of the modified polypropylene (A) and a polypropylene (B), and 99 to 1% by weight of at least one sturated polyester resin (D), 0.1 to 300 parts by weiht of an epoxy group containing copolymer (E), 0.1 to 300 parts by weight of a modified ethylenic copolymer ruber (F) obtained by graft copolymerizing and an unsaturated carboxylic acid or a derivative thereof and an unsaturated aromatic monomer onto ethylenic copolymer ruber, and Up to 5 partsg by weight of a basic comdpound (G) optionally added as reaction accelerator, the content of the saturted polyester resin in the thermoplastic polyeste4r resin being less than 50% by weight. The thermoplastic resin composition of the present invention has high heat resistance and high impact resistance. in particular, high low-temperatuer impact resistance and is advantgeously used in automobilde parts, electric and electronic parts, etc.摘要翻译： 公开了一种热塑性树脂组合物，其包含100重量份的树脂组合物和100重量份的树脂组合物，所述树脂组合物由1至99重量％的选自由改性聚丙烯（A）通过接枝获得的聚丙烯类树脂（C） 将不饱和羧酸或其衍生物与不饱和芳香族单体共聚到聚丙烯上，以及由该改性聚丙烯（A）和聚丙烯（B）构成的组合物和99-1重量％的至少一种研磨的聚酯树脂（ D），0.1〜300重量份的含环氧基的共聚物（E），0.1〜300重量份的通过接枝共聚而得到的改性乙烯类共聚物橡胶（F）和不饱和羧酸或其衍生物以及不饱和羧酸 芳族单体加入烯属共聚物橡胶中，以及至多5重量份的作为反应促进剂任选加入的碱性化合物（G），饱和聚酯树脂在 rmoplastic聚酯树脂小于50重量％。 本发明的热塑性树脂组合物具有高耐热性和高耐冲击性。 特别是耐低温冲击性高，适用于汽车部件，电气电子部件等。
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公开(公告)号：EP0435173B1
公开(公告)日：1996-07-03
申请号：EP90124955.7
申请日：1990-12-20
发明人： Imai, Akio , Tsuji, Mitsuji , Sanada, Takashi , Yamamoto, Keisaku
IPC分类号： C08F255/06 , C08F291/02 , C08F285/00
CPC分类号： C08F255/04 , C08F255/06 , C08F279/02
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公开(公告)号：EP0270071B1
公开(公告)日：1994-03-02
申请号：EP87117741.6
申请日：1987-12-01
发明人： Takao, Hiroyoshi , Imai, Akio , Seki, Tomoaki , Tsuji, Mitsuji
IPC分类号： C08C19/42
CPC分类号： C08C19/42
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公开(公告)号：EP0336744A3
公开(公告)日：1991-10-09
申请号：EP89303383.7
申请日：1989-04-05
IPC分类号： C09J151/06 , C08L51/06 , C08J5/06
CPC分类号： C08F8/32 , C09J151/06
摘要： An adhesive composition comprising a modified, ethylene/ a-olefin copolymer rubber or a modified, ethylene/a-olefin/non-conjugated diene copolymer rubber containing 0.1 - 100/o by weight of at least one member selected from the group consisting of an acid anhydride and a dicarboxylic acid, and, if necessary, as an amine compound,
(i) 0.2 - 2 moles of a dialkylamine per mole of the acid anhydride in said modified copolymer rubber when said modified copolymer rubber contains no dicarboxylic acid; (ii) 0.2 - 2 moles of a polyamine compound per mole of the total amount of the acid anhydride and the dicarboxylic acid in said modified copolymer rubber; or (iii) 0.2 - 2 moles of a dialkylamine per mole of the acid anhydride in said modified copolymer rubber and 0.2 - 2 moles of a polyamine compound per mole of the acid anhydride in said modified copolymer rubber when said modified copolymer rubber contains no dicarboxylic acid. The above adhesive composition exhibits good adhesion for rubber compositions, particularly low saturated, non-polar rubber compositions and fibers, and is excellent in storage stability.摘要翻译： 一种粘合剂组合物，它含有改性的乙烯/α-烯烃共聚物橡胶或改性的乙烯/α-烯烃/非共轭二烯共聚物橡胶，该橡胶含有0.1-100％（重量）的至少一种选自 （ii）所述改性共聚物橡胶不含二羧酸时，所述改性共聚物橡胶中每摩尔酸酐0.2-2摩尔二烷基胺;以及（如果需要）作为胺化合物， （ii）每摩尔所述改性共聚物橡胶中酸酐和二羧酸总量为0.2-2摩尔多胺化合物; 或（iii）当所述改性共聚物橡胶不含二羧酸时，所述改性共聚物橡胶中每摩尔酸酐0.2-2摩尔二烷基胺和每摩尔酸酐0.2-2摩尔多胺化合物 酸。 上述粘合剂组合物对橡胶组合物，特别是低饱和非极性橡胶组合物和纤维表现出良好的粘合性，并且具有优异的储存稳定性。
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公开(公告)号：EP0408255A1
公开(公告)日：1991-01-16
申请号：EP90307369.0
申请日：1990-07-05
发明人： Furuta, Motonobu , Tsuji, Mitsuji
CPC分类号： C08L51/06 , C08L59/00 , C08L61/06 , C08L63/00 , C08L67/00 , C08L69/00 , C08L71/126 , C08L77/00 , C08L81/02 , C08L81/06 , C08L83/00 , Y10S525/905 , Y10T428/1397 , C08L2666/14 , C08L2666/02
摘要： A thermoplastic resin composition is disclosed which comprises
(a) a modified polyphenylene ether or a composition containing it, and
(b) (i) a modified propylene polymer comprising propylene polymer which is graft-copolymerized with a styrene based monomer or with a mixture of a styrene based monomer and a monomer copolymerizable therewith, or (ii) a composition containing the modified propylene polymer in (b)-(i) and propylene polymer. The resin composition may contain (c) a rubber-like substance containing at least one rubber-like substance having a polar group and/or (d) a melt flow characteristics improving agent.摘要翻译： 公开了一种热塑性树脂组合物，其包含（a）改性聚苯醚或含有它的组合物，以及（b）（i）包含丙烯聚合物的改性丙烯聚合物，所述丙烯聚合物与苯乙烯基单体接枝共聚或与 苯乙烯类单体和可与其共聚的单体，或（ii）含有（b） - （i）中的改性丙烯聚合物和丙烯聚合物的组合物。 树脂组合物可以含有（c）含有至少一种具有极性基团的橡胶状物质和/或（d）熔体流动性改进剂的橡胶状物质。
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