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    LIQUID-ORGANIC HYDROGEN CARRIER SYSTEMS BASED ON CATALYTIC PEPTIDE FORMATION AND HYDROGENATION
    11.
    发明公开
    LIQUID-ORGANIC HYDROGEN CARRIER SYSTEMS BASED ON CATALYTIC PEPTIDE FORMATION AND HYDROGENATION 审中-公开
    基于催化肽形成和氢化的液 - 有机氢载体体系

    公开(公告)号：EP3189006A1

    公开(公告)日：2017-07-12

    申请号：EP15790289.1

    申请日：2015-09-03

    申请人： Yeda Research and Development Co., Ltd.

    发明人： MILSTEIN, David ,  HU, Peng ,  FOGLER, Eran

    IPC分类号： C01B3/00 ,  C07C209/50 ,  C07C213/00 ,  C07C29/149 ,  C07C31/08

    CPC分类号： C01B3/0015 ,  C01B3/00 ,  C07C29/149 ,  C07C209/50 ,  C07C211/00 ,  C07C211/10 ,  C07C213/00 ,  C07C215/08 ,  C07C231/08 ,  C07C231/10 ,  C07C233/36 ,  C07C237/08 ,  C07C249/02 ,  C07C251/08 ,  C07D241/08 ,  Y02E60/327 ,  Y02E60/328 ,  C07C31/08

    摘要： The present invention provides a system and method of storing hydrogen (H2) and releasing it on demand, comprising and making use of diaminoalkanes and alcohols, or aminoalcohols as liquid-organic hydrogen carrier systems (LOHC). 2-amino-ethanol (AE) or its N-methyl derivative 2-(methylamino)ethanol undergo catalytic dehydrogenation to form a cyclic dipeptide (glycine anhydride—GA) or its N,N-dimethyl derivative (N,N-dimethyl GA) with release of hydrogen. Similarly, ethylenediamine (ED) and ethanol undergo catalytic dehydrogenation to form N,N′-diacetylethylenediamine (DAE) with release of hydrogen. Glycine anhydride (GA) or N,N-dimethyl-GA may be hydrogenated back to 2-aminoethanol (AE) or 2-(methylamino)ethanol, respectively, each of which functions as a hydrogen storage system. N,N′-diacetylethylenediamine (DAE) may be hydrogenated back to ED and ethanol, which functions as a hydrogen storage system. These reactions may be catalyzed by a variety of compounds or complexes, including Ruthenium complexes as described herein.

    摘要翻译： 本发明提供储存氢气（H 2）并根据需要释放它的系统和方法，其包括并且使用二氨基烷烃和醇或氨基醇作为液体 - 有机氢载体体系（LOHC）。 2-氨基乙醇（AE）或其N-甲基衍生物2-（甲基氨基）乙醇进行催化脱氢以形成环状二肽（甘氨酸酐-GA）或其N，N-二甲基衍生物（N，N-二甲基GA） 的氢气。 类似地，乙二胺（ED）和乙醇进行催化脱氢以形成N，N'-二乙酰基乙二胺（DAE）并释放氢。 甘氨酸酐（GA）或N，N-二甲基-GA可分别氢化回到2-氨基乙醇（AE）或2-（甲基氨基）乙醇，其中每一个都起到储氢体系的作用。 N，N'-二乙酰乙二胺（DAE）可以被氢化回ED和乙醇，其作为储氢体系起作用。 这些反应可以被多种化合物或复合物催化，包括如本文所述的钌复合物。

    NEW METHOD FOR THE PREPARATION OF METAL CARBENE COMPLEXES
    15.
    发明授权
    NEW METHOD FOR THE PREPARATION OF METAL CARBENE COMPLEXES 有权
    新工艺生产金属CARBEN复杂

    公开(公告)号：EP1381617B8

    公开(公告)日：2006-05-03

    申请号：EP02761958.4

    申请日：2002-04-15

    申请人： YEDA RESEARCH AND DEVELOPMENT CO., LTD.

    发明人： MILSTEIN, David ,  GANDELMAN, Mark ,  ASHKENAZI, Nissan ,  RYBTCHINSKI, Boris

    IPC分类号： C07F15/00 ,  C07C381/00

    CPC分类号： C07F15/0046 ,  C07C381/00 ,  C07F15/002

    摘要： The present invention provides a process for preparing a metal carbene complex of formula (I): wherein M is a transition metal atom selected from the group consisting of ruthenium, rhodium, iron , cobalt, osmium and iridium; L denotes neutral donor ligands ligated to said metal, such groups being the same or different; X is an anionic ligand; R1 and R2 are each independently selected from the group consisting of hydrogen, substituted or unsubstituted C1-C20 alkyl, substituted or unsubstituted C2-C20 alkenyl, substituted or unsubstituted cycloalkyl, substituted or unsubstituted heterocycloalkyl, substituted or unsubstituted aryl, substituted or unsubstituted heteroaryl, substituted or unsubstituted vinyl, a is 2 or 3 and b is 1 or 2, such process comprising reacting a sulfur ylide of the formula Ar>2 R or its precursor with an appropriate metal complex comprising a transition metal atom selected from the group consisting of ruthenium, rhodium, iron, cobalt, osmium and iridium, said metal complex being also in dimeric form, at a temperature between +80 DEG C and -80 DEG C, in an inert solvent and under inert atmosphere.