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1.发明公开NOVEL RUTHENIUM COMPLEXES AND THEIR USES IN PROCESSES FOR FORMATION AND/OR HYDROGENATION OF ESTERS, AMIDES AND DERIVATIVES THEREOF 审中-公开新钌和它们在程序对教育和/或加氢酯，酰胺及其衍生物的
公开(公告)号：EP2629889A2
公开(公告)日：2013-08-28
申请号：EP11788587.1
申请日：2011-10-11
发明人： MILSTEIN, David , BALARAMAN, Ekambaram , GUNANATHAN, Chidambaram , GNANAPRAKASAM, Boopathy , ZHANG, Jing
IPC分类号： B01J31/18
CPC分类号： C07K5/12 , B01J31/18 , B01J31/189 , B01J31/2404 , B01J31/2409 , B01J31/248 , B01J31/2485 , B01J2231/40 , B01J2231/49 , B01J2231/643 , B01J2231/763 , B01J2531/0244 , B01J2531/821 , C07B41/02 , C07B41/08 , C07B41/12 , C07B43/04 , C07B43/06 , C07C29/136 , C07C29/149 , C07C29/177 , C07C41/16 , C07C41/26 , C07C45/002 , C07C45/006 , C07C51/00 , C07C51/02 , C07C51/23 , C07C51/295 , C07C67/00 , C07C67/03 , C07C67/297 , C07C209/00 , C07C209/62 , C07C213/00 , C07C213/02 , C07C231/02 , C07C231/10 , C07C2601/08 , C07C2601/10 , C07C2601/14 , C07D207/06 , C07D207/08 , C07D211/12 , C07D213/38 , C07D241/08 , C07D241/12 , C07D295/023 , C07D295/027 , C07D295/185 , C07D305/06 , C07D307/14 , C07D307/33 , C07D307/44 , C07D307/52 , C07D307/83 , C07D309/30 , C07D487/14 , C07F9/58 , C07F9/65583 , C07F15/0046 , C07F15/0053 , C07K1/00 , C08G69/00 , Y02P20/52 , C07C233/05 , C07C235/06 , C07C233/07 , C07C235/16 , C07C235/14 , C07C235/10 , C07C211/27 , C07C211/07 , C07C211/35 , C07C211/46 , C07C211/10 , C07C215/28 , C07C217/58 , C07C69/14 , C07C69/24 , C07C31/125 , C07C31/12 , C07C49/78 , C07C49/04 , C07C49/10 , C07C49/08 , C07C49/403 , C07C31/205 , C07C31/202 , C07C31/04 , C07C31/08 , C07C33/20 , C07C33/22 , C07C31/1355 , C07C31/10 , C07C43/13 , C07C69/78 , C07C69/75 , C07C53/124 , C07C53/126 , C07C59/125 , C07C57/32 , C07C61/08 , C07C57/30 , C07C65/21 , C07C63/08 , C07C63/06
摘要： The present invention relates to novel Ruthenium catalysts and related borohydride complexes, and the use of such catalysts, inter alia, for (1) hydrogenation of amides (including polyamides) to alcohols and amines; (2) preparing amides from alcohols with amines (including the preparation of polyamides (e.g., polypeptides) by reacting dialcohols and diamines and/or by polymerization of amino alcohols); (3) hydrogenation of esters to alcohols (including hydrogenation of cyclic esters (lactones) or cyclic di-esters (di-lactones) or polyesters); (4) hydrogenation of organic carbonates (including polycarbonates) to alcohols and hydrogenation of carbamates (including polycarbamates) or urea derivatives to alcohols and amines; (5) dehydrogenative coupling of alcohols to esters; (6) hydrogenation of secondary alcohols to ketones; (7) amidation of esters (i.e., synthesis of amides from esters and amines); (8) acylation of alcohols using esters; (9) coupling of alcohols with water to form carboxylic acids; and (10) dehydrogenation of beta-amino alcohols to form pyrazines. The present invention further relates to the novel uses of certain pyridine Ruthenium catalysts.
摘要翻译： 本发明涉及新的钌络合物和相关的硼氢化物，及对（1）酰胺（包括聚酰胺），以醇和cardamines的氢化使用; （2）制备的酰胺从醇与cardamines（包括通过使二元醇与二胺或由氨基醇的聚合制备聚酰胺（例如，多肽））; （3）酯的氢化，以醇（包括环状酯的氢化（内酯），环状二酯（二 - 内酯）或聚酯）; （4）的有机碳酸酯（包括聚碳酸酯）醇类和氨基甲酸酯类（包括聚氨基甲酸酯）或尿素衍生物为醇和cardamines的加氢; （5）的醇脱氢以酯的耦合; （6）仲醇到酮的加氢; （7）酯的酰胺化（从酯和cardamines酰胺的合成）; （8）使用酯醇的酰化; （9）与水的醇的偶联以形成羧酸; 和（10）的β-氨基醇的脱氢以形成吡嗪。 本发明还涉及某些吡啶钌配合物的新颖用途。
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公开(公告)号：EP2629889B1
公开(公告)日：2019-04-03
申请号：EP11788587.1
申请日：2011-10-11
发明人： MILSTEIN, David , BALARAMAN, Ekambaram , GUNANATHAN, Chidambaram , GNANAPRAKASAM, Boopathy , ZHANG, Jing
IPC分类号： C07D487/14 , C07C29/136 , C07C29/149 , C07C29/17 , C07C67/00 , C07C67/03 , C07D309/30 , C07C41/16 , C07C45/00 , C07F15/00 , C07C209/62 , C07C213/00 , C07D241/08 , C07D241/12 , C07C231/02 , C07C231/10 , C07D207/08 , C07D295/023 , C07D213/38 , C07C51/23
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公开(公告)号：EP2307431B1
公开(公告)日：2012-12-26
申请号：EP09787521.5
申请日：2009-08-10
IPC分类号： C07F15/00 , C07F9/60 , C07F9/64 , C07C209/00
CPC分类号： C07C209/16 , B01J31/146 , C07B43/04 , C07C213/02 , C07C2601/14 , C07D213/38 , C07D305/06 , C07D307/52 , C07F9/60 , C07F9/64 , C07F15/0046 , C07C211/07 , C07C211/17 , C07C211/27 , C07C217/08 , C07C217/58
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4.发明公开PROCESS FOR PREPARING AMINES FROM ALCOHOLS AND AMMONIA 有权VERFAHREN ZUR HERSTELLUNG冯AMINEN AUS ALKOHOLEN UND AMMONIAK
公开(公告)号：EP2307431A1
公开(公告)日：2011-04-13
申请号：EP09787521.5
申请日：2009-08-10
IPC分类号： C07F15/00 , C07F9/60 , C07F9/64 , C07C209/00
CPC分类号： C07C209/16 , B01J31/146 , C07B43/04 , C07C213/02 , C07C2601/14 , C07D213/38 , C07D305/06 , C07D307/52 , C07F9/60 , C07F9/64 , C07F15/0046 , C07C211/07 , C07C211/17 , C07C211/27 , C07C217/08 , C07C217/58
摘要： The present invention provides novel ruthenium based catalysts, and a process for preparing amines, by reacting a primary alcohol and ammonia in the presence of such catalysts, to generate the amine and water. According to the process of the invention, primary alcohols react directly with ammonia to produce primary amines and water in high yields and high turnover numbers. This reaction is catalyzed by novel ruthenium complexes, which are preferably composed of quinolinyl or acridinyl based pincer ligands.
摘要翻译： 本发明提供了新的钌基催化剂，以及通过在这种催化剂存在下使伯醇和氨反应制备胺的方法，以产生胺和水。 根据本发明的方法，伯醇与氨直接反应，以高产率和高周转数产生伯胺和水。 该反应由新的钌络合物催化，其优选由喹啉基或吖啶基类钳制配体组成。
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