ION EXCHANGE STATIONARY PHASES FOR ANALYZING POLYVALENT IONS

    公开(公告)号:EP3479900A1

    公开(公告)日:2019-05-08

    申请号:EP18204155.8

    申请日:2018-11-02

    摘要: Ion exchange stationary phases are prepared with diprimary diamines for applications such as separating samples that contain polyvalent anions. The ion exchange stationary phase includes a series of condensation polymer reaction products bound to a substrate. The condensation polymer products are formed with diprimary diamines and polyepoxide compounds. The ion exchange stationary phases described herein are capable of separating monovalent and highly polyvalent anions relatively quickly with relatively low eluent concentrations in one chromatographic run.

    AGGLOMERATED ION EXCHANGE PARTICLE BED AND METHOD

    公开(公告)号:EP1924358B1

    公开(公告)日:2018-10-24

    申请号:EP06814704.0

    申请日:2006-09-14

    IPC分类号: B01J47/00 B01D15/36

    摘要: A liquid chromatography agglomerated bed comprising component A comprising (a) substrate particles and polymer chains (e.g. a condensation polymer) bound to the substrate particles and projecting therefrom, and (b) component B comprising substrate particles having external surfaces of opposite charge to that of the charged polymer chains, components A and B being bound at least in part by electrostatic forces between the component A charged polymer chains and the component B external surfaces to form in composite an agglomerated bed of ion exchange particles packed in a chromatography column.

    DISPOSABLE WORKING ELECTRODE FOR AN ELECTROCHEMICAL CELL
    16.
    发明授权
    DISPOSABLE WORKING ELECTRODE FOR AN ELECTROCHEMICAL CELL 有权
    一次性工作电极用于电化学电池

    公开(公告)号:EP1602138B1

    公开(公告)日:2018-01-24

    申请号:EP02792413.3

    申请日:2002-12-16

    IPC分类号: H01M4/00

    CPC分类号: G01N27/307 Y10T29/49002

    摘要: A flow-through electrochemical cell assembly with a disposable working electrode structure, including (a) a perimeter wall defining a sample flow channel including an inlet and an outlet, (b) a sample inlet line in fluid communication with the sample flow channel inlet, (c) a sample outlet line providing fluid communication between the sample flow channel outlet and a remote reference electrode, and (d) a disposable working electrode structure comprising an electrically conductive and electrochemically active working electrode region bound as a layer, directly or indirectly, to an electrically insulating substrate surface. The substrate surface is in fluid-sealing relationship with the sample flow channel, and the working electrode region is in fluid communication with said sample flow channel. The working electrode is vapor deposited, directly or indirectly, onto the organic polymer substrate through a mask, and a fluid seal is formed between said working electrode region and perimeter wall.

    A METHOD FOR REDUCING SUPPRESSOR NOISE
    18.
    发明公开
    A METHOD FOR REDUCING SUPPRESSOR NOISE 审中-公开
    一种降低抑制噪声的方法

    公开(公告)号:EP3177915A1

    公开(公告)日:2017-06-14

    申请号:EP15753557.6

    申请日:2015-08-07

    IPC分类号: G01N30/96

    摘要: An electrolytic method for suppressing liquid eluent containing previously separated sample analyte anions, counterions to the sample anions, and non-sample anions suppressible to weak acids in an electrolytic device comprising a housing defining at least a sample stream flow channel and an ion receiving flow-through channel separated by an ion exchange bather. The sample stream flow channel includes an upstream channel portion and a downstream channel portion. A first current is applied across the upstream channel portion for substantially completely suppression. A second current is applied across the downstream channel portion at a magnitude of less than 10% of the magnitude of the first current.

    摘要翻译: 一种用于在电解装置中抑制含有预先分离的样品分析物阴离子,对样品阴离子的抗衡离子和对于弱酸可被抑制的非样品阴离子的液体洗脱液的电解方法,该电解装置包括限定至少一个样品流流动通道和离子接收流动通道的壳体, 通过由离子交换浴室隔开的通道。 样品流流动通道包括上游通道部分和下游通道部分。 第一电流被施加在上游通道部分上以用于基本完全抑制。 第二电流以小于第一电流的大小的10%的量值施加在下游通道部分上。

    METHOD OF PACKING CHROMATOGRAPHIC COLUMNS, PACKED CHROMATOGRAPHIC COLUMNS FOR USE AT HIGH PRESSURES AND USES THEREOF
    19.
    发明公开
    METHOD OF PACKING CHROMATOGRAPHIC COLUMNS, PACKED CHROMATOGRAPHIC COLUMNS FOR USE AT HIGH PRESSURES AND USES THEREOF 审中-公开
    包装层析柱法,色谱柱包装以关于在高PRESS及其用途

    公开(公告)号:EP3151004A1

    公开(公告)日:2017-04-05

    申请号:EP16182362.0

    申请日:2016-08-02

    IPC分类号: G01N30/56 B01D15/20

    摘要: A method of packing a chromatography column, including: dispersing chromatographic media particles in a slurry solution to form a slurry, filling a chromatography column with the chromatographic media particles by introducing the slurry to the column and applying a pressure to pack the chromatographic media particles in the chromatography column. The slurry solution is preferably aqueous based slurry solution. The pressure is preferably applied and held substantially constant for a first period at a first pressure and is applied and held substantially constant for a second period, following the first period, at a second pressure higher than the first pressure.

    摘要翻译: 在淤浆溶液的色谱介质粒子分散以形成浆料,通过引入浆料到柱填充与层析介质颗粒的层析柱和施加压力来包装色谱介质粒子:包装色谱柱,的方法,包括 色谱柱。 将该浆料溶液优选wässrige基于浆料溶液。 压力优选应用和英雄基本恒定为一个第一时间段在第一压力和施加和英雄基本恒定为一个第二时间段,接着所述第一周期,在第二压力比第一压力高。