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    WATER-RESISTANT/OIL-RESISTANT AGENT FOR PAPER
    12.
    发明公开
    WATER-RESISTANT/OIL-RESISTANT AGENT FOR PAPER 审中-公开
    用于纸张的耐水/耐油剂

    公开(公告)号：EP2826918A1

    公开(公告)日：2015-01-21

    申请号：EP13761072.1

    申请日：2013-03-14

    Applicant: Daikin Industries, Ltd.

    Inventor： UEHARA, Tetsuya ,  KUSUMI, Kayo ,  MATSUDA, Michio

    IPC: D21H21/16 ,  C08F220/22 ,  C08L33/16 ,  C08L71/02 ,  C09K3/18 ,  D21H19/20

    CPC classification number: D21H21/16 ,  C08F220/22 ,  C08F220/24 ,  C08L71/02 ,  D21H17/11 ,  D21H17/36 ,  D21H17/37 ,  D21H17/72 ,  D21H19/12 ,  D21H19/20 ,  C08F220/20 ,  C08F226/10 ,  C08F220/06 ,  C08L33/16

    Abstract: Provided is a water-resistant/oil-resistant agent for paper that exhibits little foam formation and excellent product stability. The water-resistant/oil-resistant agent for paper comprises: (I) (a) a fluorine-containing monomer that has a fluoroalkyl group and that is represented by general formula (1) (General formula (1): CH 2 =C(-X)-C(=O)-Y-Z-Rf [In the formula, X is a hydrogen atom, a linear or branched alkyl group having 1-21 carbon atoms, a fluorine atom, a chlorine atom, a bromine atom, an iodine atom, or the like. Y is -O- or -NH-. Z is an aliphatic group having 1-10 carbon atoms, an aromatic group having 6-10 carbon atoms, a cycloaliphatic group, or the like. Rf is a linear or branched fluoroalkyl group having 1-6 carbon atoms.]) and (b) a fluorine-containing copolymer that includes, as a necessary component, a repeating unit derived from a (meth)acrylate monomer containing no fluorine atoms; and (II) a polypropylene glycol compound.

    Abstract translation: 本发明提供一种纸的耐水/耐油剂，其显示出很少的泡沫形成和优异的产品稳定性。 （1）：通式（1）：通式（1）：具有氟代烷基的含氟单体：通式（1）：CH 2 = C -X）-C（= O）-YZ-Rf [式中，X为氢原子，碳原子数为1〜21的直链状或支链状的烷基，氟原子，氯原子，溴原子， 碘原子等，Y为-O-或-NH-，Z为碳原子数为1〜10的脂肪族基团，碳原子数为6〜10的芳香族基团，脂环族基团等，Rf为 （b）含有来自不含氟原子的（甲基）丙烯酸酯单体的重复单元作为必需成分的含氟共聚物，（b）具有1〜6个碳原子的直链或支链状的氟代烷基。 和（II）聚丙二醇化合物。

    RESIN COMPOSITION AND MOLDINGS THEREOF
    17.
    发明公开
    RESIN COMPOSITION AND MOLDINGS THEREOF 有权
    树脂组合物及成型THEREOF

    公开(公告)号：EP1767583A4

    公开(公告)日：2011-12-21

    申请号：EP05765131

    申请日：2005-06-23

    Applicant: DAIKIN IND LTD

    Inventor： MASUDA EIJI

    IPC: C08L101/00 ,  C08L33/16 ,  D04H1/42

    CPC classification number: C08L77/00 ,  C08L23/02 ,  C08L23/06 ,  C08L23/10 ,  C08L23/22 ,  C08L33/16 ,  C08L67/00 ,  C08L2205/03 ,  C08L2207/066 ,  D01F6/46 ,  Y10T442/637 ,  C08L2666/02 ,  C08L2666/04

    Abstract: A resin composition which comprises (A) a thermoplastic resin and (B) a fluoropolymer comprising structural units derived from an acrylate ester_represented by the general formula (I): [wherein X is hydrogen, methyl, fluoro, chloro, bromo, iodo, CFX 1 X 2 (wherein X 1 and X 2 are each hydrogen, fluoro, chloro, bromo, or iodo), cyano, straight-chain or branched fluoroalkyl having 1 to 21 carbon atoms, substituted or unsubstituted benzyl, or substituted or unsubstituted phenyl; Y is an aliphatic group having 1 to 10 carbon atoms or the like; and Rf is a straight-chain or branched fluoroalkyl or fluoroalkenyl group having 1 to 6 carbon atoms]. The composition can give moldings excellent in water repellency and oil repellency.

    STAIN-PROOFING AGENT COMPOSITION, METHOD FOR PRODUCING THE SAME, AND ARTICLE TREATED WITH THE SAME
    18.
    发明公开
    STAIN-PROOFING AGENT COMPOSITION, METHOD FOR PRODUCING THE SAME, AND ARTICLE TREATED WITH THE SAME 有权
    组成FOR A易去污，生产方法，因此处理过的制品

    公开(公告)号：EP2287267A1

    公开(公告)日：2011-02-23

    申请号：EP09754742.6

    申请日：2009-05-27

    Applicant: Asahi Glass Company, Limited

    Inventor： HARA, Hiroyuki ,  SUGIMOTO, Shuichiro ,  HIRONO, Takao

    IPC: C09K3/00 ,  C08L33/16 ,  C09K3/18 ,  C08F220/26 ,  D06M15/277

    CPC classification number: D06M15/277 ,  C08F214/06 ,  C08F220/22 ,  C08F220/58 ,  C08F222/14 ,  C08F2220/1891

    Abstract: To provide a process for efficiently producing a fluorine type antifouling composition employing a short chain R f group, which can be made in the form of an aqueous dispersion containing substantially no volatile organic solvent and has a good soil release property (SR property).
    A process for producing an antifouling composition, which comprises a step of subjecting monomer components (Z) comprising from 30 to 80 mass% of a monomer (a) having a polyfluoroalkyl group in which the number of carbon atoms to which fluorine atoms are bonded is from 4 to 6, and from 20 to 70 mass% of a monomer (b) having no polyfluoroalkyl group and having a hydrophilic group, to solution polymerization in a volatile organic solvent having a boiling point of at most 100°C in the presence of a surfactant (c) comprising an ethylene oxide adduct of 2,4,7,9-tetramethyl-5-decyne-4,7-diol to form a fluorocopolymer (A), and a step of volatilizing the volatile organic solvent after the solution polymerization and adding an aqueous medium to form an aqueous dispersion.

    Abstract translation: 要有效地生产的氟类防污剂组合物采用短链R f基，其可以以水分散体基本不含挥发性有机溶剂的形式来制成，并且具有良好的去污性（SR性）的方法。 一种用于在防污剂组合物，该方法包括使单体成分（Z）由单体的质量，其包括30〜80％的工序制备方法（a）具有其中碳原子为氟原子的数量相连接的多氟烷基 从4到6，以及从​​20％到70％由不具有多氟烷基但具有具有在存在至多100℃的沸点的挥发性有机溶剂中的亲水性基团，以溶液聚合用的单体（b）的质量 表面活性剂（c）含有2,4,7,9-四甲基-5-癸炔-4,7-二醇的环氧乙烷加合物，以形成含氟共聚物（A），并将该溶液后挥发所述挥发性有机溶剂的步骤 聚合并加入到wässrige介质中以形成在wässrige分散体。

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