摘要:
A novel class of lanthanide metal phenoxyimine complexes can be used as an ingredient of a catalyst system. The catalyst system can be used in polymerizations of ethylenically unsaturated hydrocarbon monomers.
摘要:
Provided is a method for producing an anionic polymer in an industrially advantageous manner, whereby at the time of anionically polymerizing monomers using a solvent whose boiling point at atmospheric pressure is higher than the polymerization temperature, temperature control can be achieved by quickly removing the heat of the polymerization reaction using a simple device. The method for producing an anionic polymer includes anionically polymerizing a conjugated diene, an aromatic vinyl compound, or a mixture thereof under a condition where the amount of an inert gas present with respect to 1 kg of a solvent whose boiling point at atmospheric pressure is higher than the polymerization temperature is 20 mmol or less.
摘要:
Provided is a rubber composition including a rubber component. The rubber component contains at least a polymer that is a synthesized polyisoprene or an isoprene copolymer and that has 20 % or less gel fraction.
摘要:
Provided are a catalyst for a conjugated diene polymerization capable of producing a conjugated diene polymer having a high content of cis-1,4-structures with a high activity, a conjugated diene polymer and a modified conjugated diene polymer using the same, production methods thereof, a rubber composition for a tire, and a rubber composition for a rubber belt. Described are a catalyst for a conjugated diene polymerization including: a non-metallocene type gadolinium compound (A) represented by the general formula (1); an ionic compound (B) formed of a non-coordinating anion and a cation; and an organic metal compound (C) of an element selected from the group consisting of a group 2, a group 12, and a group 13 of the periodic table, a conjugated diene polymer and a modified conjugated diene polymer obtained using the same, production methods thereof, a rubber composition for a tire, and a rubber composition for a rubber belt.
摘要:
FIELD: chemistry.SUBSTANCE: invention relates to the production of a rubber composition characterized by high transparency, toughness and heat resistance. Composition contains a neodymium catalyzed isoprene rubber (IR) component in an amount of from 5 to 95 mass parts and a rubber (RB) polymer component selected from the group: butadiene rubber (BR), 1,2-polybutadiene rubber, styrene-butadiene rubber (SBR), provided that the total amount of IR and RB polymers is 100 parts by weight. Composition is free from silicon dioxide and is characterized by turbidity, less than 20 % in relation to a sheet with a thickness of 2 mm, and a hardness of Durometer type A (0 sec), amounting to approximately 30 or more. Neodymium-catalyzed isoprene rubber has a cis isomer content of 95 % or more and includes approximately 10,000 ppm or less of iron or lithium.EFFECT: composition provides excellent transparency, durability and heat resistance.15 cl, 5 tbl, 9 ex