摘要:
The present invention is directed to a process for the preparation of crystalline Mg-Al-Si-containing clay-containing bodies from sources comprising an aluminium source, a magnesium source, and a silicon source, comprising the steps of: a) preparing a precursor mixture; b) shaping the precursor mixture to obtain shaped bodies; c) optionally thermally treating the shaped bodies; and d) aging to obtain crystalline Mg-Al-Si-containing clay-containing bodies. The quintessence of the present invention is that the bodies are shaped prior to the forming of the crystalline clay in said bodies. This results in very attrition resistant bodies, without the need to add a binder material. The crystalline clay is formed from an aluminium source, a magnesium source, and, a silicon source. If only an aluminium source and a magnesium source are present, hydrotalcite is formed. If an aluminium source, a magnesium source, and a silicon source are present, saponite or montmorillonite is formed.
摘要:
The present invention pertains to an improved process for the preparation of quasi-crystalline boehmite. In this improved process a quasi-crystalline boehmite precursor is aged at a pH below 7, preferably under hydrothermal conditions. It was found that when conducting the preparation processes for quasi-crystalline aluminas described in the prior art at a pH below 7 and under hydrothermal conditions instead of the high pH and thermal ageing used in the prior art, QCBs with higher crystallinity are obtained. In the process according to the invention additives may be added to the quasi-crystalline boehmite precursor. This results in a high quality QCB with additives in a homogeneously dispersed state. Suitable additives are compounds containing elements selected from the group of rare earth metals, alkaline earth metals, transition metals, actinides, silicon, gallium, boron, and phosphorus.
摘要:
The present invention is directed to a process for the preparation of crystalline Mg-Al-Si-containing clay-containing bodies from sources comprising an aluminium source, a magnesium source, and a silicon source, comprising the steps of: a) preparing a precursor mixture; b) shaping the precursor mixture to obtain shaped bodies; c) optionally thermally treating the shaped bodies; and d) aging to obtain crystalline Mg-Al-Si-containing clay-containing bodies. The quintessence of the present invention is that the bodies are shaped prior to the forming of the crystalline clay in said bodies. This results in very attrition resistant bodies, without the need to add a binder material. The crystalline clay is formed from an aluminium source, a magnesium source, and, a silicon source. If only an aluminium source and a magnesium source are present, hydrotalcite is formed. If an aluminium source, a magnesium source, and a silicon source are present, saponite or montmorillonite is formed.
摘要:
This patent describes an economical and environment-friendly continuous process for the synthesis of anionic clays with carbonate and/or hydroxide anions as the charge-balancing interlayer species. It involves reacting a slurry comprising aluminium trihydrate and/or its calcined form, with a magnesium source. There is no necessity to wash or filter the product. It can be spray dried directly to form microspheres or can be extruded to form shaped bodies. The product can be combined with other ingredients in the manufacture of catalysts, absorbents, pharmaceuticals, cosmetics, detergents, and other commodity products.
摘要:
This patent describes economical and environment-friendly processes for the synthesis of anionic clays and anionic clay-like materials with acetate anions as the charge-balancing interlayer species. It involves combining a slurry of a gibbsite or its thermally treated form with a slurry or solution of a magnesium source and magnesium acetate. The product is not washed, needs no filtration and exists in a close to neutral pH condition. It can be spray dried directly to form microspheres or can be extruded to form shaped bodies. Because of the absence of foreign salts the product can be combined with other ingredients in the manufacture of catalysts, absorbents, pharmaceuticals, cosmetics, detergents, and other commodity products that contain anionic clays.
摘要:
This invention relates to a process for the preparation of anionic clay and boehmite-containing compositions. These compositions may also contain unreacted trivalent metal source and/or divalent metal source. The process involves subjecting a precursor mixture comprising a divalent metal source and a trivalent metal source to at least two aging steps, wherein at least once between two aging steps an aluminium source is added. An advantage of the invention is that the crystallinity of the boehmite in the composition can be tuned.
摘要:
The present invention pertains to cheaper process for the preparation of quasi-crystalline boehmite containing additive in a homogeneously dispersed state. In this cheaper process an inexpensive quasi-crystalline boehmite precursor and an additive are combined and aged to form a quasi-crystalline boehmite containing additive in a homogeneously dispersed state. Suitable inexpensive quasi-crystalline boehmite precursors are aluminium trihydrate and thermally treated forms thereof and inorganic aluminium salts. Suitable additives are compounds containing elements selected from the group of rare earth metals, alkaline earth metals, transition metals, actinides, silicon, gallium, boron, and phosphorus.