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21.发明授权PROCESS FOR THE PRODUCTION OF MIXTURES OF 2-HYDROXYTETRAHYDROFURAN AND 4-HYDROXYBUTANAL 无效工艺制备2-羟基四氢呋喃和4-羟混合工
公开(公告)号：EP0586522B1
公开(公告)日：1997-07-23
申请号：EP92912218.2
申请日：1992-05-14
IPC分类号： C07D307/20 , C07D307/28 , C07C45/59 , C07C47/19
CPC分类号： C07D307/28 , C07C45/59 , C07D307/20 , C07C47/19
摘要： Disclosed is a process for the production of an equilibrium mixture of 2-hydroxytetrahydrofuran and 4-hydroxybutanal by a two-step process comprising (1) heating 2,5-dihydrofuran in the presence of a catalyst system comprising a phosphine, ruthenium or rhodium to convert the 2,5-dihydrofuran to 2,3-dihydrofuran; and (2) contacting 2,3-dihydrofuran with water in the presence of an acidic catalyst to convert the 2,3-dihydrofuran to a mixture of 2-hydroxytetrahydrofuran and 4-hydroxybutanal. Also disclosed is a process for the continuous production of an aqueous solution of 2-hydroxytetrahydrofuran and 4-hydroxybutanal. The mixture of 2-hydroxytetrahydrofuran and 4-hydroxybutanal may be catalytically hydrogenated to produce 1,4-butanediol.
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公开(公告)号：EP0740676A1
公开(公告)日：1996-11-06
申请号：EP95908072.0
申请日：1995-01-17
发明人： FALLING, Stephen, Neal , GODLESKI, Stephen, Allen , LOPEZ-MALDONADO, Patricia , MACKENZIE, Peter, Borden , McCULLOUGH, Laughlin, Gerard , MATAYABAS, James, Christopher, Jr.
IPC分类号： C08G65
CPC分类号： C08G65/269 , C08G65/12 , C08G65/14
摘要： Disclosed are novel polyether compounds obtained by the reaction or polymerization of 3,4-epoxy-1-butene in the presence of an onium iodide compound such as an ammonium or phosphonium iodide, an organotin compound such as a trihydrocarbyltin iodide, and a nucleophilic initiator compound. The polyether compounds comprise n units of residue (1) and m units of residue (2), wherein the total value of n + m is 2 to 70, m/(n + m) is greater than 0.75 and up to 0.98, and residues (1) and (2) have the structures (1) and (2).
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23.发明公开HYDROCARBOXYLATION OF FORMALDEHYDE IN THE PRESENCE OF A HIGHER ORDER CARBOXYLIC ACID AND A HETEROGENEOUS CATALYST 审中-公开Hydrocarboxylating甲醛炭酸高阶的存在和非均相催化剂
公开(公告)号：EP2831030A1
公开(公告)日：2015-02-04
申请号：EP13714484.6
申请日：2013-03-22
发明人： BARNICKI, Scott, Donald , HEMBRE, Robert, Thomas , FALLING, Stephen, Neal , JANKA, Mesfin, Ejerssa , MORAN, Kelley, Margaret
CPC分类号： C07C51/12 , C07C29/149 , C07C51/09 , C07C51/48 , C07C51/493 , C07C67/08 , C07C67/36 , C07C67/58 , Y02P20/52 , C07C59/06 , C07C31/202 , C07C69/675 , C07C69/67
摘要： Disclosed is a process for the production and purification of glycolic acid or glycolic acid derivatives by the carbonylation of formaldehyde in the presence of a solid acid catalyst and a carboxylic acid. This invention discloses hydrocarboxylations and corresponding glycolic acid separations wherein the glycolic acid stream is readily removed from the carboxylic acid and the carboxylic acid is recycled.
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24.发明授权PROCESS FOR THE PREPARATION OF 3-FUROATE ESTERS AND NOVEL INTERMEDIATE COMPOUNDS 有权用于生产ALKYL呋喃-3-羧酸和新中间体
公开(公告)号：EP1250330B1
公开(公告)日：2004-01-07
申请号：EP01902078.3
申请日：2001-01-16
IPC分类号： C07D307/46
CPC分类号： C07D307/68
摘要： Disclosed is a two-step process wherein a 4-acyl-2,3-dihydrofuranis converted to a 2-alkoxy-3-acyl-3-halotetrahydorfuran which then is contacted with a strong base to produce an alkyl 3-furoate.Also disclosed are novel 2-alkoxy-3-acyl-3-halotetrahydrofuran intermediates.
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25.发明授权
公开(公告)号：EP0653963B1
公开(公告)日：1996-12-11
申请号：EP93918547.6
申请日：1993-07-30
发明人： FALLING, Stephen, Neal , GODLESKI, Stephen, Allen , MCGARRY, Linda, Woedy , NOLEN, Timothy, Richard , KANEL, Jeffrey, Scott
IPC分类号： B01J31/40 , C07D307/28
CPC分类号： B01J31/0268 , B01J31/0239 , B01J31/122 , B01J31/4015 , B01J31/4053 , B01J2231/52 , C07D307/28 , Y02P20/584
摘要： Disclosed is a process for the recovery of catalyst values from mixtures of catalyst compounds and oligomeric materials. The process provides for the separation of (i) an onium iodide compound, (ii) an organotin iodide compound, or (iii) a mixture thereof from a mixture thereof in an oligomer of a η,δ-epoxyalkene by the steps of (1) intimately contacting the mixture with an extraction solvent selected from hydrocarbons having 5 to 12 carbon carbon atoms; (2) allowing the mixture of step (1) to separate into two phases; and (3) recovering the extraction solvent phase containing iodide compounds (i) and (ii). The oligomer mixture of compounds (i) and/or (ii) is formed during the manufacture of 2,5-dihydrofurans by the isomerization of η,δ-epoxyalkenes.
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26.发明公开PROCESS FOR THE PREPARATION OF 3,4-DIHALO-1,2-EPOXYBUTANES FROM 3,4-EPOXY-1-BUTENE 失效工艺用于生产3,4-环氧-1-丁烯-3,4-二卤代-1,2- EPOXYBUTANEN BASIS
公开(公告)号：EP0693063A1
公开(公告)日：1996-01-24
申请号：EP94912831.0
申请日：1994-03-23
CPC分类号： C07D303/08
摘要： Disclosed is a process for the preparation of 3,4-dichloro- and 3,4-dibromo-1,2-epoxybutane by the reaction of 3,4-epoxy-1-butene with chlorine or bromine in the presence of a catalytic amount of a tertiary amine or a hydrohalide of a primary, secondary or tertiary amine. The reaction preferably is carried out by the addition of 3,4-epoxy-1-butene and chlorine or bromine to an organic, halogenation solvent containing chlorine or bromine and tertiary amine or amine hydrohalide catalyst.
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27.发明授权
公开(公告)号：EP0605508B1
公开(公告)日：1995-12-06
申请号：EP92919624.4
申请日：1992-09-03
IPC分类号： C07D303/08
CPC分类号： C07D303/08
摘要： Disclosed is a process for the preparation of 3,4-dichloro- and 3,4-dibromo-1,2-epoxybutane by the reaction of 3,4-epoxy-1-butane with chlorine or bromine in the presence of a quaternary ammonium or phosphonium halide compound. The reaction preferably is carried out by the addition of 3,4-epoxy-1-butane and chlorine or bromine to an organic, halogenation solvent containing chlorine or bromine and the quaternary compound.
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28.发明公开PROCESS FOR THE SEPARATION OF OLIGOMERIC MATERIALS FROM A CATALYST MIXTURE 失效PROCESS寡聚体材料从催化剂混合物分离。
公开(公告)号：EP0653963A1
公开(公告)日：1995-05-24
申请号：EP93918547.0
申请日：1993-07-30
发明人： FALLING, Stephen, Neal , GODLESKI, Stephen, Allen , MCGARRY, Linda, Woedy , NOLEN, Timothy, Richard , KANEL, Jeffrey, Scott
CPC分类号： B01J31/0268 , B01J31/0239 , B01J31/122 , B01J31/4015 , B01J31/4053 , B01J2231/52 , C07D307/28 , Y02P20/584
摘要： Disclosed is a process for the recovery of catalyst values from mixtures of catalyst compounds and oligomeric materials. The process provides for the separation of (i) an onium iodide compound, (ii) an organotin iodide compound, or (iii) a mixture thereof from a mixture thereof in an oligomer of a η,δ-epoxyalkene by the steps of (1) intimately contacting the mixture with an extraction solvent selected from hydrocarbons having 5 to 12 carbon carbon atoms; (2) allowing the mixture of step (1) to separate into two phases; and (3) recovering the extraction solvent phase containing iodide compounds (i) and (ii). The oligomer mixture of compounds (i) and/or (ii) is formed during the manufacture of 2,5-dihydrofurans by the isomerization of η,δ-epoxyalkenes.
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29.发明公开PROCESS FOR THE SELECTIVE HYDROGENATION OF $g(g),$g(d)-EPOXYALKYLENES TO EPOXYALKANES 失效PROCESS FOR GAMMA的选择性加氢，DELTA IN环氧烯烃环氧烷烃。
公开(公告)号：EP0639185A1
公开(公告)日：1995-02-22
申请号：EP92907378.0
申请日：1991-12-17
CPC分类号： C07D303/04 , C07C45/58 , C07D301/00
摘要： Disclosed is a novel process for the preparation of epoxyalkanes and epoxycycloalkanes which comprises hydrogenating η,δ-epoxyalkenes or η,δ-epoxycycloalkenes in the presence of a rhodium catalyst. The process is especially useful for the preparation of 1,2-epoxybutane from 3,4-epoxy-1-butene.
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