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1.发明公开HYDROCARBOXYLATION OF FORMALDEHYDE IN THE PRESENCE OF A HIGHER ORDER CARBOXYLIC ACID AND A HOMOGENEOUS CATALYST 审中-公开Hydrocarboxylating甲醛炭酸和高阶均相催化剂A存在
公开(公告)号：EP2831026A1
公开(公告)日：2015-02-04
申请号：EP13715093.4
申请日：2013-03-22
发明人： BARNICKI, Scott, Donald , HEMBRE, Robert, Thomas , FALLING, Stephen, Neal , VETTER, Andrew, James
IPC分类号： C07C51/12 , C07C51/10 , C07C59/06 , C07C59/305 , C07C69/24 , C07C67/297
CPC分类号： C07C67/58 , C07C51/09 , C07C51/493 , C07C67/00 , C07C67/36 , C07C59/06 , C07C69/675 , C07C69/24
摘要： Disclosed is a process for the production and purification of glycolic acid or glycolic acid derivatives by the carbonylation of formaldehyde in the presence of a homogeneous acid catalyst and a carboxylic acid. This invention discloses hydrocarboxylations and corresponding homogeneous acid catalyst and glycolic acid separations. The homogeneous acid catalyst is readily separated from the hydrocarboxylation reaction effluent and recycled and the carboxylic acid is readily removed from the glycolic acid and the carboxylic acid is recycled.
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公开(公告)号：EP2618903A2
公开(公告)日：2013-07-31
申请号：EP11761210.1
申请日：2011-09-14
发明人： BARNICKI, Scott, Donald , FALLING, Stephen, Neal , KANEL, Jeffrey, Scott , KLINE, Robert, Sterling , MACKENZIE, Peter, Borden
CPC分类号： B01D11/0492 , B01J31/0225 , B01J31/0227 , B01J31/4092 , C07C51/48 , C07C303/44 , C07C315/06 , Y02P20/584 , C07C59/06 , C07C309/06 , C07C309/05 , C07C317/04
摘要： Disclosed is a process for the extractive recovery of an acid catalyst from an aqueous mixture of glycolic acid with an extraction solvent comprising a tertiary amine or an onium carboxylate compound, a modifier, and a diluent. The acid catalyst, which can comprise strong acids such as sulfuric acid, alkyl sulfonic acids, and fluoroalkyl sulfonic acids, can be recovered by back extraction with aqueous formaldehyde and recycled to a process for the preparation of glycolic acid by the acid-catalyzed carbonylation of formaldehyde.
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公开(公告)号：EP0951359A1
公开(公告)日：1999-10-27
申请号：EP97938408.0
申请日：1997-08-19
CPC分类号： B01J31/122 , B01J27/08 , B01J31/4015 , B01J2231/52 , B01J2531/42 , C07D307/28 , C07F7/2216 , Y02P20/584
摘要： Disclosed is a process for converting an iodine-free organotin (IV) compound resulting from the decomposition of an organotin (IV) iodide during the catalytic isomerization of η, δ-epoxyalkenes to 2,5-dihydrofurans to the corresponding, catalytically active organotin (IV) iodide by intimately contacting a catalyst mixture comprising (i) an organotin (IV) iodide, (ii) an iodine-free organotin (IV) compound resulting from the decomposition of the organotin (IV) iodide of component (i), and (iii) a solvent selected from hydrocarbons and chlorocarbons with aqueous hydrogen iodide.
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4.发明授权PROCESS FOR THE PREPARATION OF 3,4-DIHALO-1,2-EPOXYBUTANES FROM 3,4-EPOXY-1-BUTENE 失效工艺用于生产3,4-环氧-1-丁烯-3,4-二卤代-1,2- EPOXYBUTANEN BASIS
公开(公告)号：EP0693063B1
公开(公告)日：1997-07-30
申请号：EP94912831.8
申请日：1994-03-23
IPC分类号： C07D303/08 , C07D301/00
CPC分类号： C07D303/08
摘要： Disclosed is a process for the preparation of 3,4-dichloro- and 3,4-dibromo-1,2-epoxybutane by the reaction of 3,4-epoxy-1-butene with chlorine or bromine in the presence of a catalytic amount of a tertiary amine or a hydrohalide of a primary, secondary or tertiary amine. The reaction preferably is carried out by the addition of 3,4-epoxy-1-butene and chlorine or bromine to an organic, halogenation solvent containing chlorine or bromine and tertiary amine or amine hydrohalide catalyst.
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5.发明授权CONTINUOUS PROCESS FOR THE MANUFACTURE OF 2,5-DIHYDROFURANS FROM GAMMA,DELTA-EPOXYBUTENES 失效连续方法-2,5-二氢呋喃γ，δepoxybutenes的制备
公开(公告)号：EP0624157B1
公开(公告)日：1997-03-05
申请号：EP92925142.9
申请日：1992-11-09
发明人： PHILLIPS, Gerald, Wayne , FALLING, Stephen, Neal , GODLESKI, Stephen, Allen , MONNIER, John, Robert
IPC分类号： C07D307/28 , C07D303/04 , B01J31/02 , B01J31/12
CPC分类号： C07D307/28 , B01J27/08 , B01J31/0239 , B01J31/0268 , B01J31/122 , B01J2231/52
摘要： Disclosed is a continuous process for the manufacture of 2,5-dihydrofurans by the isomerization of η,δ-epoxyalkenes in the liquid phase in the presence of a catalyst system comprising an onium iodide compound and a Lewis acid and a process solvent comprising a mixture of the 2,5-dihydrofuran product of the process and an oligomer of the η,δ-epoxyalkenes reactant.
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6.发明公开HYDROCARBOXYLATION OF METHYLENE DIPROPIONATE IN THE PRESENCE OF PROPIONIC ACID AND A HETEROGENEOUS CATALYST 审中-公开Hydrocarboxylating METHYLENDIPROPIONAT在丙酸的存在和非均相催化剂
公开(公告)号：EP2831031A1
公开(公告)日：2015-02-04
申请号：EP13716568.4
申请日：2013-03-22
发明人： BARNICKI, Scott, Donald , HEMBRE, Robert, Thomas , FALLING, Stephen, Neal , JANKA, Mesfin, Ejerssa , MORAN, Kelley, Margaret
IPC分类号： C07C67/37 , C07C51/09 , C07C59/06 , C07C69/24 , C07C69/675
CPC分类号： C07C51/09 , C07C67/00 , C07C67/36 , C07C59/06 , C07C53/122 , C07C69/675 , C07C69/24
摘要： Disclosed is a process for the production and purification of glycolic acid glycolic acid derivatives by the carbonylation of methylene dipropionate in the presence of a solid acid catalyst and propionic acid. This invention discloses hydrocarboxylations and corresponding glycolic acid separations wherein the propionic acid stream is readily removed from the glycolic acid and the propion acid is recycled.
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7.发明公开
公开(公告)号：EP1212372A1
公开(公告)日：2002-06-12
申请号：EP00952644.3
申请日：2000-08-08
发明人： CYR, Michael, John , CLAUBERG, Horst , STEWART, Mark, Edward , ROGERS, Martin, Emerson , FALLING, Stephen, Neal
CPC分类号： C08L71/02 , C08G63/672 , C08K5/098 , C08K2201/012 , C08L67/02
摘要： The present invention relates to oxygen scavenging compositions comprising an oxidation catalyst and at least one polyether selected from the group consisting of unsubstituted poly(alkylene glycol)s having alkylene chains of 1 to 3 carbon atoms, substituted or unsubstituted poly(alkylene glycol)s having alkylene chains of at least 4 carbon atoms, copolymers of poly(alkylene glycol)s, blends containing poly(alkylene glycol)s and mixtures thereof. The invention further relates to polymers containing said oxygen scavenging compounds and articles made therefrom.
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8.发明公开CONTINUOUS PROCESS FOR THE CONVERSION OF 2,5-DIHYDROFURAN TO 2,3-DIHYDROFURAN 失效将2,5,5-二氢呋喃转化为2,3-二氢呋喃的连续方法
公开(公告)号：EP0902784A1
公开(公告)日：1999-03-24
申请号：EP97921447.0
申请日：1997-04-29
发明人： NOLEN, Timothy, Richard , FALLING, Stephen, Neal , HITCH, David, Martin , MILLER, Jerry, Lynn , TERRILL, Daniel, Latham
CPC分类号： C07D307/28
摘要： Disclosed is a process for the continuous production and recovery of 2,3-dihydrofuran (2,3-DHF) by the isomerization of 2,5-dihydrofuran (2,5-DHF) which contains certain impurities to 2,3-dihydrofuran in yields exceeding 95 %. The process utilizes, in order, an isomerization zone containing one or more beds of a supported, palladium or platinum catalyst, a product recovery zone comprising a distillation column, a high boiler removal zone and means for feeding the 2,5-DHF component of the bottoms stream from the product recovery zone to the isomerization zone.
摘要翻译： 本发明公开了一种通过将含有某些杂质的2,5-二氢呋喃（2,5-二氢呋喃）异构化为2,3-二氢呋喃来连续生产和回收2,3-二氢呋喃（2,3-DHF）的方法， 收益率超过95％。 该方法依次使用含有一个或多个负载的钯或铂催化剂床的异构化区，包含蒸馏塔的产物回收区，高沸点物移除区和用于将以下物质的2,5-DHF组分 从产物回收区到异构化区的底部物流。
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公开(公告)号：EP0883594A1
公开(公告)日：1998-12-16
申请号：EP97908766.0
申请日：1997-02-27
CPC分类号： C07C67/26 , Y02P20/582 , C07C69/16
摘要： A process for the preparation of a 1,2-diacetoxy ester comprises acetylation of an epoxide with an acetic anhydride in the presence of a quaternary phosphonium acetate catalyst or its complex with acetic acid.
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10.发明授权ISOMERIZATION OF EPOXYALKENES TO 2,5-DIHYDROFURANS AND CATALYSTS COMPOSITIONS USEFUL THEREFOR 失效环氧烯烃的异构化2.5用于此用途二氢呋喃和催化剂组合物。
公开(公告)号：EP0518973B1
公开(公告)日：1995-01-11
申请号：EP91906010.3
申请日：1991-03-07
发明人： MONNIER, John, Robert , LOW, Howard, Milburn , McCULLOUGH, Laughlin, Gerard , GODLESKI, Stephen, Allen , McGARRY, Lynda, Woedy , WEBSTER, Frank, Glenn , FALLING, Stephen, Neal , LOPEZ-MALDONADO, Patricia , PHILLIPS, Gerald Wayne
IPC分类号： C07D307/28 , B01J31/02
CPC分类号： C07D307/28 , B01J21/08 , B01J23/06 , B01J31/0239 , B01J31/0268 , B01J31/122 , B01J31/26 , B01J2231/52
摘要： Disclosed are processes for the isomerization of epoxyalkenes to dihydrofurans by contacting an epoxyalkene with a catalyst comprising a quaternary organic onium iodide compounds, optionally deposited on a non-acidic support and/or in combination with a Lewis acid co-catalyst. The catalyst may comprise a supported catalyst, an unsupported catalyst or a solution of the catalytically-active components in an inert, organic solvent.
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