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公开(公告)号:EP3168917A1
公开(公告)日:2017-05-17
申请号:EP15819618.8
申请日:2015-07-07
IPC分类号: H01M10/0567 , H01G9/035 , H01G11/64 , H01M10/0568 , H01M10/0569
CPC分类号: H01M10/0567 , C07F9/091 , H01G11/60 , H01G11/62 , H01G11/64 , H01M10/052 , H01M10/0525 , H01M10/0568 , H01M10/0569 , H01M2300/0025 , Y02E60/13
摘要: The present invention provides a novel electrolyte solution capable of providing electrochemical devices whose internal resistance is less likely to increase even after repeated charge and discharge and whose cycle capacity retention ratio is high. The electrolyte solution of the present invention contains a solvent, an electrolyte salt, and a phosphate in an amount of 0.001 to 15 mass% relative to the solvent and represented by the formula (1):
(R 11 O)(R 12 O)PO 2 M.摘要翻译: 本发明提供了一种新型电解质溶液,其能够提供即使在重复充放电之后其内阻也不太可能增加并且其循环容量保持率高的电化学装置。 本发明的电解质溶液含有溶剂,电解质盐和磷酸盐,其相对于溶剂为0.001至15质量%,并由式(1)表示:(R 11 O)(R 12 O)P O 2 M。
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公开(公告)号:EP4415079A1
公开(公告)日:2024-08-14
申请号:EP23882529.3
申请日:2023-10-19
IPC分类号: H01M4/62 , C08F214/22 , H01M4/131 , H01M10/054
CPC分类号: C08F214/22 , H01M4/131 , H01M4/505 , H01M4/525 , H01M4/62 , H01M10/054 , Y02E60/10
摘要: Provided are a binder that lowers interfacial resistance between a current collector and an electrode material layer in a positive electrode of a sodium ion battery and has good battery characteristics, as well as an electrode mixture, an electrode, and a secondary battery using the binder. A binder for a positive electrode of a sodium ion battery, including a copolymer that has a vinylidene fluoride unit (A) and a constituent unit (B) derived from at least one monomer selected from the group consisting of trifluoroethylene, hexafluoropropylene, chlorotrifluoroethylene, a monomer represented by formula (1), a monomer represented by formula (2), and a monomer represented by formula (3), and that is free of a tetrafluoroethylene unit:
wherein Rf1 is a linear or branched fluorinated alkyl group or fluorinated alkoxy group having from 1 to 12 carbon atoms, and the fluorinated alkyl group and the fluorinated alkoxy group optionally contain an oxygen atom (-O-) between carbon-carbon atoms in the case of having 2 or more carbon atoms,
wherein Rf2 is a linear or branched fluorinated alkyl group or fluorinated alkoxy group having from 1 to 12 carbon atoms, and the fluorinated alkyl group and the fluorinated alkoxy group optionally contain an oxygen atom (-O-) between carbon-carbon atoms in the case of having 2 or more carbon atoms, and
wherein R1, R2, and R3 are each independently a hydrogen atom, a chlorine atom or an alkyl group having from 1 to 5 carbon atoms; X is a single bond or an atomic group having a main chain composed of from 1 to 20 atoms and having a molecular weight of 500 or less; and Y represents an inorganic cation and/or an organic cation.-
公开(公告)号:EP4411898A1
公开(公告)日:2024-08-07
申请号:EP23880891.9
申请日:2023-10-26
IPC分类号: H01M4/62 , C08F214/22 , C08F214/24 , C08F214/26 , H01M4/131 , H01M4/485 , H01M4/505 , H01M4/525 , H01M4/1391 , H01M10/054
CPC分类号: C08F214/22 , C08F214/24 , C08F214/26 , H01M4/131 , H01M4/1391 , H01M4/485 , H01M4/505 , H01M4/525 , H01M4/62 , H01M10/054 , Y02E60/10
摘要: Provided are a binder that lowers interfacial resistance between a current collector and an electrode material layer in a positive electrode of a sodium ion battery, as well as an electrode mixture, an electrode, and a secondary battery using the binder. A binder for a positive electrode of a sodium ion battery includes a copolymer (A) having a vinylidene fluoride unit and a tetrafluoroethylene unit, wherein a content of the vinylidene fluoride unit is from 30 to 99.5 mol% with respect to all monomer units in the copolymer (A).
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24.
公开(公告)号:EP3982452A1
公开(公告)日:2022-04-13
申请号:EP20819113.0
申请日:2020-06-05
IPC分类号: H01M10/0569 , H01M4/13 , H01M4/131 , H01M4/133 , H01M4/134 , H01M4/136 , H01M4/505 , H01M4/525 , H01M4/58 , H01M4/587 , H01M10/052 , H01M10/054 , H01M10/0567
摘要: The present disclosure provides an electrolytic solution that can improve cycle characteristics and rate characteristics. An alkali metal ion secondary battery including the electrolytic solution of the present disclosure will provide favorable battery output.
An electrolytic solution for an alkali metal ion secondary battery comprising a positive electrode and a negative electrode, wherein
the positive electrode comprises at least one selected from the group consisting of an alkali metal-containing transition metal composite oxide and an alkali metal-containing transition metal phosphate compound,
the negative electrode comprises at least one selected from the group consisting of graphite, a silicon-based material, a tin-based material, and an alkali metal-containing metal composite oxide material, and
the electrolytic solution comprises a compound represented by the following formula (1) and/or a compound represented by the following formula (2):-
公开(公告)号:EP3982442A1
公开(公告)日:2022-04-13
申请号:EP20818122.2
申请日:2020-06-05
IPC分类号: H01M4/134 , H01M4/38 , H01M10/052 , H01M10/0568 , H01M10/0569
摘要: There are provided an electrolytic solution capable of improving the output characteristics and the capacity retention, a lithium-sulfur secondary battery having the electrolytic solution, as well as a module. The electrolytic solution to be used for a battery having a positive electrode or a negative electrode containing a sulfur-containing electrode active material containing at least one selected from the group consisting of simple sulfur, lithium polysulfides (Li 2 S n : 1 ≤ n ≤ 8) and organosulfur compounds contains: a fluorinated ether represented by the formula (1): Rf-(OR 1 ) n -O-R 2 wherein Rf is an alkyl group having a fluorine atom and optionally forming a branch or a ring having 1 to 5 carbon atoms, R 1 is an alkyl group optionally having a fluorine atom, R 2 is an alkyl group having no fluorine atom, having 1 to 9 carbon atoms and optionally forming a branch or a ring, n is 0, 1 or 2, and the number of carbon atoms in one molecule is 5 or more; an ether compound represented by the formula (2): R 4 -(OCHR 3 CH 2 ) x -OR 5 wherein R 4 and R 5 are each independently selected from the group consisting of alkyl groups having 1 to 9 carbon atoms and having no fluorine atom, a phenyl group optionally substituted by a halogen atom and a cyclohexyl group optionally substituted by a halogen atom, and optionally together form a ring, R 3 each independently represent H or CH 3 , and x represents 0 to 10; and an alkali metal salt.
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26.
公开(公告)号:EP3933999A1
公开(公告)日:2022-01-05
申请号:EP20762616.9
申请日:2020-02-26
IPC分类号: H01M10/0567 , C07D233/58 , C07F5/02 , H01G9/20 , H01G11/62 , H01M6/16 , H01M8/02
摘要: Provided are an electrolyte solution and the like that allow an electrochemical device to have low resistance and improved cycle characteristics. The disclosure relates to an electrolyte solution containing at least one compound (1) selected from the group consisting of a compound represented by the following formula (1A) and a compound represented by the following formula (1B):
the formula (1A) being:
wherein R 101 and R 102 , each independently, are a C5-C10 organic group, optionally contain at least one selected from the group consisting of a hetero atom and an unsaturated bond, and optionally contain a ring,
the formula (1B) being:
wherein R 103 to R 105 , each independently, are a C1-C10 organic group, optionally contain at least one selected from the group consisting of a hetero atom and an unsaturated bond, and optionally contain a ring.-
公开(公告)号:EP3780231A1
公开(公告)日:2021-02-17
申请号:EP19803680.8
申请日:2019-03-18
发明人: KUWAJIMA, Yoshiko , HIDAKA, Tomoya , KINOSHITA, Masakazu , SUZUKI, Yuuki , SHIMOOKA, Toshiharu , NAKAMURA, Hisako , YAMADA, Takaya , YAMAZAKI, Shigeaki , YAMAUCHI, Akiyoshi , HAYASHI, Kotaro , YAMAMOTO, Yoshihiro , TAKAHASHI, Kenzou
IPC分类号: H01M10/0567 , H01G11/64 , H01M10/052
摘要: The disclosure provides an electrolyte solution capable of improving the output characteristics of an electrochemical device at initial stage and after high-temperature storage as well as the high-temperature cycle characteristics of the device. The electrolyte solution contains a compound (1) represented by the formula (1) (wherein M 101 is P or P=O; R 101 is a group such as a C1-C11 alkylsilyloxy group; n101 is an oxidation number of M 101 minus 1 or an oxidation number of M 101 minus 3; and R 102 to R 104 are each individually a group such as a C1-C11 alkyl group) and a compound (11) represented by, for example, the formula (11-1) (wherein R 111 and R 112 are the same as or different from each other and are each an atom or group such as a hydrogen atom; and R 113 is a group such as an alkyl group free from a fluorine atom).
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公开(公告)号:EP3731329A1
公开(公告)日:2020-10-28
申请号:EP19747870.4
申请日:2019-01-09
发明人: KUWAJIMA, Yoshiko , YAMAUCHI, Akiyoshi , SUZUKI, Yuuki , HAYASHI, Kotaro , NAKAMURA, Hisako , YAMADA, Takaya , SHIMOOKA, Toshiharu , YAMAMOTO, Yoshihiro , YAMAZAKI, Shigeaki , TAKAHASHI, Kenzou
IPC分类号: H01M10/0567 , C07C69/533 , C07C233/09 , C07C233/13 , C07D295/185 , H01G11/64 , H01M10/052
摘要: The disclosure provides an electrolyte solution capable of improving the high-temperature storage characteristics and cycle characteristics of an electrochemical device. The electrolyte solution contains at least one selected from the group consisting of a compound represented by the following formula (1-1) (wherein R 101 is a group such as an optionally fluorinated C1-C7 alkyl group and optionally contains a substance such as O in the structure) and a compound represented by the following formula (1-2) (wherein R 102 and R 103 are (i) each individually H, F, or a group such as an optionally fluorinated C1-C7 alkyl group, or (ii) hydrocarbon groups binding to each other to form a 5-membered or 6-membered hetero ring with a nitrogen atom; and R 102 and R 103 each optionally contain a substance such as O in the structure).
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29.
公开(公告)号:EP3694041A1
公开(公告)日:2020-08-12
申请号:EP18876381.7
申请日:2018-10-26
发明人: KUWAJIMA, Yoshiko , HAYASHI, Kotaro , NAKAMURA, Hisako , YAMADA, Takaya , SUZUKI, Yuuki , YAMAZAKI, Shigeaki , YAMAUCHI, Akiyoshi , TAKAHASHI, Kenzou
IPC分类号: H01M10/0567 , C07C69/36 , H01G11/64 , H01M10/052
摘要: The invention provides an electrolyte solution capable of improving the high-temperature storage characteristics and cycle characteristics of an electrochemical device. The electrolyte solution contains at least one selected from the group consisting of a compound represented by the following formula (1-1) (wherein Rf 111 s are the same as or different from each other and are each a C2-C4 fluorinated alkenyl group), a compound represented by the following formula (1-2) (wherein R 121 is a C1-C4 alkyl group; and Rf 121 is a C2-C4 fluorinated alkenyl group), and a compound represented by the following formula (1-3) (wherein Rf 131 is a C1-C3 fluorinated alkyl group; and R 131 is a C6-C12 aryl group).
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30.
公开(公告)号:EP3691016A1
公开(公告)日:2020-08-05
申请号:EP18869721.3
申请日:2018-09-13
IPC分类号: H01M10/0567 , H01G11/64 , H01M10/052 , H01M10/0568
摘要: The invention provides an electrolyte solution capable of providing an electrochemical device that has a low internal resistance and excellent cycle characteristics and that is less likely to generate gas. The electrolyte solution contains lithium ethyl sulfate and ethyl sulfate. The lithium ethyl sulfate is present in an amount of 0.1 to 2.0% by mass relative to the electrolyte solution. The lithium ethyl sulfate and the ethyl sulfate give a mass ratio of the lithium ethyl sulfate to the ethyl sulfate of 80 to 1500.
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